TY - JOUR T1 - The Design, Synthesis and Spectroscopic/Photophysical Characterization of Phosphonate-substituted BODIPY AU - Işık Taşgın, Dilek PY - 2020 DA - April Y2 - 2020 DO - 10.15671/hjbc.650747 JF - Hacettepe Journal of Biology and Chemistry JO - HJBC PB - Hacettepe University WT - DergiPark SN - 2687-475X SP - 197 EP - 201 VL - 48 IS - 2 LA - en AB - BODIPY compounds continue to attract the attention ofscientists from multidisciplinary areas because of the wide range applicationsand excellent photophysical properties as fluorescent sensors or dyes. In thisstudy, a new phosphonate substituted BODIPY dye was synthesized by classicalcondensation-oxidation-complexation method of pyrrolic compounds and aldehyde.The structure and photophysical properties of the synthesized BODIPY compoundwere determined by 1H NMR, 13C NMR, 31P NMR, 19FNMR, UV-Vis absorption and fluorescence spectroscopic techniques.0000-0002-0316-4604 KW - BODIPY KW - fluorescent dyes KW - phosphonate CR - Referans 1 N. Boens, V. Leen, W. Dehaen, Fluorescent indicators based on BODIPY, Chem. Soc. Rev., 41 (2012) 1130-1172. https://pubs.rsc.org/en/content/articlelanding/2012/cs/c1cs15132kReferans 2 A. Loudet, K. Burgess, BODIPY Dyes and Their Derivatives: Syntheses and Spectroscopic Properties, Chem. Rev., 107 (2007) 4891-4932. https://pubs.acs.org/doi/pdf/10.1021/cr078381nReferans 3 G. Ulrich, R. Ziessel, A. Harriman, The Chemistry of Fluorescent Bodipy Dyes: Versatility Unsurpassed, Angew. Chem. Int. Ed., 47 (2008) 1184-1201. https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.200702070Referans 4 S. Banfi, G. Nasini, S. Zaza, E. Caruso, Synthesis and photo-physical properties of a series of BODIPY dyes, Tetrahedron 69 (2013) 4845-4856. https://www.sciencedirect.com/science/article/pii/S0040402013006029Referans 5 A. Treibs, F.-H. Kreuzer, Difluorboryl-Komplexe von Di- und Tripyrrylmethenen, Justus Liebigs Ann. Chem., 718 (1968) 208-223. https://onlinelibrary.wiley.com/doi/abs/10.1002/jlac.19687180119Referans 6 A. V. Solomonov, Y. S. Marfin, E. V. Rumyantsev, Design and applications of dipyrrin-based fluorescent dyes and related organic luminophores: From individual compounds to supramolecular self-assembled systems, Dyes and Pigments, 162 (2019) 517-542. https://www.sciencedirect.com/science/article/pii/S0143720818304698Referans 7 P. Kaur, K. Singh, Recent advances in the application of BODIPY in bioimaging and chemosensing, J. Mater. Chem. C, 7 (2019) 11361-11405. https://pubs.rsc.org/en/content/articlelanding/2019/tc/c9tc03719Referans 8 T. Bura, R. Ziessel, Water-Soluble Phosphonate-Substituted BODIPY Derivatives with Tunable Emission Channels, Org. Lett., 13 (2011) 3072-3075. https://pubs.acs.org/doi/10.1021/ol200969rReferans 9 A.-C. Schulz-Fincke, M. Blaut, A. Braune, M. Gütschow, A BODIPY-Tagged Phosphono Peptide as Activity-Based Probe for Human Leukocyte Elastase, ACS Med. Chem. Lett., 9 (2018) 345-350. https://pubs.acs.org/doi/abs/10.1021/acsmedchemlett.7b00533Referans 10 Z. Dost, S. Atilgan, E. U. Akkaya, Distyryl-boradiazaindacenes: facile synthesis of novelnear IR emitting fluorophores, Tetrahedron, 62 (2006) 8484–8488. https://www.sciencedirect.com/science/article/pii/S0040402006010258Referans 11 B. Brizet, C. Bernhard, Y. Volkova, Y. Roussselin, P. D. Harvey, C. Goze, F. Denat, Boron functionalization of BODIPY by various alcohols and phenols, Org. Biomol. Chem., 11 (2013) 7729-7737. https://pubs.rsc.org/en/content/articlelanding/2013/ob/c3ob41370 UR - https://doi.org/10.15671/hjbc.650747 L1 - https://dergipark.org.tr/en/download/article-file/1061642 ER -