TY - JOUR T1 - Piezoelektrik Malzemelerin Lityum İyon Batarya Anotlarında Katkı Olarak Kullanılması AU - Doğrusöz, Mehbare AU - Demirkan, M. Taha PY - 2021 DA - December DO - 10.17780/ksujes.672828 JF - Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi JO - KSU J. Eng. Sci. PB - Kahramanmaras Sutcu Imam University WT - DergiPark SN - 1309-1751 SP - 258 EP - 270 VL - 24 IS - 4 LA - tr AB - ÖzetLityum iyon bataryalarında son günlerdeki en popüler malzeme olarak gösterilen silisyum (Si) içerikli malzemelerle ilgili önemli sorunlar, bunların ticari olarak yaygınlaşmasını engellemektedir. Si anot malzemelerinin şarj/deşarj esnasında yüksek hacim değişikliğine uğraması ve mekanik olarak dayanıksızlığı bu sorunların başında gelmektedir. Bu çalışmada PZT tabanlı piezoelektrik malzemelerin kullanılmasıyla bu sorunların çözümündeki katkısı üzerinde durulmuştur. Si ve karbon (C) karışımı anot malzemelerinde katkı olarak PZT parçacıkları kullanıldığında bu malzemelerin kapasite performansında artış olduğu görülmüştür. Bu artışın nedenleri tartışılmakla birlikte farklı türlerde PZT malzemeleri ile farklı oranlarda Si-C karışımları üzerine test yapılmış ve aralarındaki performans farkları incelenmiştir. PZT kullanımı olmadığı durumlarda ilk 50 çevrimde 50 mAh/g’in altında spesifik kapasite değerleri vererek bozulmaya uğrayan anot malzemelerinin, PZT katkısı kullanılmasıyla 100. çevrimde dahi 400 mAh/g üzerinde değerleri verdiği gözlemlenmiştir. KW - Silisyum Anot KW - Lityum İyon Batarya KW - Piezoelektrik CR - Aurbach, D., Markovsky, B., Salitra, G., Markevich, E., Talyossef, Y., Koltypin, M., Kovacheva, D. (2007). Review on electrode–electrolyte solution interactions, related to cathode materials for Li-ion batteries. Journal of Power Sources, 165(2), 491-499. doi:10.1016/j.jpowsour.2006.10.025 CR - B.A. Boukamp, G. C. L., R.A. Huggins. 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