TY  - JOUR
T1  - Monomer Fraction in Real Gases
AU  - Sedunov, Boris
PY  - 2008
DA  - March
JF  - International Journal of Thermodynamics
PB  - Uluslararası Uygulamalı Termodinamik Derneği İktisadi İşletmesi
WT  - DergiPark
SN  - 1301-9724
SP  - 1
EP  - 9
VL  - 11
IS  - 1
LA  - en
AB  - This work is aimed to attract attention to monomer fraction density (MFD), the variable that has not yet taken its place in the theory of real gases. The work shows that this variable can be calculated for monocomponent real gases from experimental isothermal dependences of their density on pressure and can be used for calculations of Gibbs energy, entropy and clusters equilibrium constants in real gases. The MFD-based joint series expansions method for density and pressure is suggested as an alternative to virial expansions. This method corresponds to the chemical equilibrium theory and provides new non-obvious results.
KW  - real gas
KW  - supercritical fluid
KW  - cluster
KW  - entropy
KW  - virial expansion
KW  - equilibrium constant
UR  - https://dergipark.org.tr/en/pub/ijot/article/76746
L1  - https://dergipark.org.tr/en/download/article-file/65720
ER  -