TY - JOUR T1 - Microstructures and Phase Transformations of Melt-Spun Ti-V-Al High Temperature Shape Memory Alloys with Addition of Zr AU - Bağ, Öznur AU - Yılmaz, Fikret AU - Kölemen, Uğur AU - Ergen, Semra PY - 2021 DA - June Y2 - 2021 DO - 10.16984/saufenbilder.797337 JF - Sakarya University Journal of Science JO - SAUJS PB - Sakarya University WT - DergiPark SN - 2147-835X SP - 735 EP - 740 VL - 25 IS - 3 LA - en AB - In this study, the effects of Zr addition on phase transformation temperatures, microstructure of Ti-12V-4Al (wt. %) high temperature shape memory alloys (HTSMAs) manufactured using melt-spinning technique were investigated. During heating, differential scanning calorimetry (DSC) curves showed that austenite transformation temperature of Ti-12V-4Al (wt. %) melt-spun ribbon was single-stage transformation and Ti-12V-4Al-0.5Zr (wt. %) melt-spun ribbon was two-stage transformation. In the scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyzes, unveiled that the melt-spun ribbons consisted of martensite, austenite and R phases. Transmission electron microscopy (TEM) analysis showed that the thickness of martensite plates in ribbons was thinned by the addition of Zr. KW - High temperature KW - shape memory alloys KW - phase transition CR - [1] C. M. Wayman, K. Otsuka, “Shape Memory Materials,” Cambridge University Press, 1998. CR - [2] R. D. Noebe, T. Biles, S. A. Padula, “NiTibased high temperature shape-memory alloys: properties, prospects, and potential applications, in ‘Advanced structural materials: properties, design optimization, and applications,” (ed. W. O. Soboyejo and T. S. Srivatsan); New York, Taylor & Francis Group, 2007. CR - [3] Q. Li, J. Li, G. Ma, X. Liu, D. Pana, “Influence of ω phase precipitation on mechanical performance and corrosion resistance of Ti–Nb–Zr alloy,” Material and Design, 11C, pp. 421-428, 2016. CR - [4] J. Wang, Q. Li, C. Xiong, Y. Li, B. Sun, “Effect of Zr on the martensitic transformation and the shape memory effect in Ti-Zr-Nb-Ta high-temperature shape memory alloys,” Journal of Alloys and Compounds, 737, pp. 672-677, 2018. CR - [5] X. Yi, Y. Wang, B. Sun, B. Cui, J. Liu, X. Meng, Z. Gao, W. Cai, L. Zhao, “Crystallization process and microstructural evolution of as-spun Ti-Ni-Zr alloy ribbon,” Journal of Alloys and Compounds, 762, pp. 62-66, 2018. CR - [6] C. Xiong, L. Yaoa, B. Yuan, W. Qu,, Y. Li, “Strain induced martensite stabilization and shape memory effect of Ti-20Zr–10Nb–4Ta alloy,” Materials Science&Engineering A, 658, pp. 28–32, 2016. CR - [7] O. Uzun, T. Karaaslan, M. Keskin, “Production and structure of rapidly solidified Al–Si alloys,” Turk J. Phys., 25:455–66, 2001. CR - [8] O. Uzun, T. Karaaslan, M. Göğebakan, M. Keskin, “Hardness and microstructural characteristics of rapidly solidified Al–8–16 wt. % Si Alloys,” J. Alloys Compd., 376:149–57, 2004. CR - [9] Y. Kim, Y. Yun, T. Nam, “The effect of the melt spinning processing parameters on the solidification structures in Ti–30 at.% Ni–20 at.% Cu shape memory alloys,” Mater Sci Eng A., 438–440:545–8, 2006. CR - [10] H.Y. Kim, M. Mizutani, S. Miyazaki, “Crystallization process and shape memory properties of TieNieZr thin films,” Acta Mater., 57, 1920-1930, 2009. CR - [11] Y. Motemani, P. J. McCluskey, C. W. Zhao, M. J. Tan, “Analysis of Ti-Ni- Hf shape memory alloys by combinatorial nanocalorimetry,” Acta Mater. 59, 7602- 7614, 2011. CR - [12] Y. Y. Li, S. S. Cao, X. Ma, C. B. Ke, X. P. Zhang, “Influence of strongly textured microstructure on the all-round shape memory effect of rapidly solidified Ni51Ti49 alloy,” Materials Science & Engineering A., 705, 273–281, 2017. CR - [13] S. Ergen, O. Uzun, F. Yılmaz, F. Kiliçaslan, “Shape memory properties and microstructural evolution of rapidly solidified CuAlBe alloys,” Materials Characterization, 80, pp. 92-97, 2013. CR - [14] Ö. Bağ, F. Yılmaz, U. Kölemen, S. Ergen, C. Temiz and O. Uzun, “Transformational, microstructural and superelasticity characteristics of Ti–V–Al high temperature shape memory alloys with Zr addition,” Physica Scripta, Vol. 96, 8, 2021. UR - https://doi.org/10.16984/saufenbilder.797337 L1 - https://dergipark.org.tr/en/download/article-file/1299603 ER -