TY - JOUR T1 - Poly acrylamide-allyl glycidyl ether Cryogel as a Novel Stationary Phase for Chlorophenol Adsorption AU - Bayram, Engin AU - Uzun, Lokman AU - Türkmen, Deniz AU - Yılmaz, Erkut AU - Galaev, Igor Yu AU - Denizli, Adil AU - Bektaş, Sema PY - 2007 DA - August JF - Hacettepe Journal of Biology and Chemistry JO - HJBC PB - Hacettepe University WT - DergiPark SN - 2687-475X SP - 219 EP - 231 VL - 35 IS - 3 LA - en AB - Poly acrylamide-allyl glycidyl ether [poly AAm-AGE ] cryogel was prepared by bulk polymerization which proceedsin an aqueous solution of monomers frozen inside a glass column cryo-polymerization . After thawing, the monolithiccryogel contains a continuous polymeric matrix having interconnected pores of 10-100 µm size. Cibacron Blue F3GAwas immobilized by covalent binding onto poly AAm-AGE cryogel via epoxy groups. Poly AAm-AGE cryogel wascharacterized by swelling studies, FTIR, scanning electron microscopy SEM and elemental analysis. The equilibriumswelling degree of the poly AAm-AGE monolithic cryogel was 6.84 g HO/g cryogel. Poly AAm-AGE cryogelcontaining 68.9 µmol Cibacron Blue F3GA/g were used in the adsorption/desorption of chlorophenols i.e., phenol,m-chlorophenol, p-chlorophenol and 2,4,6-trichlorophenol from aqueous solutions. The maximum adsorptions ofchlorophenols onto the Cibacron Blue carrying cryogels were 128.5 µmol/g for phenol, 144.3 µmol/g for 2,4,6trichlorophenol, 155.8 µmol/g for p-chlorophenol and 164.7 µmol/g for m-chlorophenol. The affinity order was asfollows: m-chlorophenol > p-chlorophenol > 2,4,6-trichlorophenol > phenol. The adsorption of chlorophenols decreasedwith increasing pH. Desorption of chlorophenols was achieved using methanol solution 30%, v/v . The cibacron BlueF3GA-carrying cryogels are suitable for repeated use for more than ten cycles without noticeable loss of adsorptioncapacity KW - Dye-affinity adsorption KW - cryogels KW - chlorophenols KW - environmental pollution CR - 1. D.C. Greminger, G.P. Burns, S. Lynn, D.N. Hanson, C.J. King, Ind. Eng. Chem. Res., 21 (1982) 51. CR - 2. HEW Publication No. (N10SH), Center for Disease Control, N10SH, Washington, 1976. CR - 3. M.W. Slein, E.B. Sansone, Degradation of Chemical Carcinogens, Van Nostrand Reinhold, New York, 1980. CR - 4. E. Munaf, R. Zein, R. Kurniadi, I. Kurniadi, Environ. Technol., 18 (1997) 355. CR - 5. Z. Aksu, J. Yener, Process Biochem., 33 (1998) 649. CR - 6. G. Bülbül, Z. Aksu, Turkish J. Eng. Environ. Sci., 21 (1997) 175. CR - 7. S. Brandt, A. Zeng, W.D. Deckwer, Biotechnol. Bioeng., 55 (1997) 480. CR - 8. K.J. Kennedy, J. Lu, W.W. Mohn, Water Res., 26 (1992) 1085. CR - 9. J.K. Park, Y.B. Jin, H.N. Chang, Biotechnol. Bioeng., 63 (1999) 116. CR - 10. H. Volesky, Z.R. Holan, Biotechnol. Prog., 11 (1995) 239. CR - 11. M. Tsezos, Z. Georgousis, E. Remoudaki, Biotechnol. Bieng., 55 (1997) 16. CR - 12. N. Hafez, A.S. Abdel-Rarek, M.B. Hafez, J. Chem. Technol. Biotechnol., 68 (1997) 19. CR - 13. A. Kapoor, T. Viraraghavan, Biores. Technol., 61 (1997) 221. CR - 14. G.M. Gadd, C. White, Biotechnol. Bioeng., 33 (1989) 592. CR - 15. M. Streat, L.A. Sweetland, React. Functl. Polym., 35 (1997) 99. CR - 16. V.V. Azanova, J. Hradil, React. Functl. Polym., 41 (1999) 163. CR - 17. A. Denizli, G. Özkan, M. Uçar, Sep. Purif. Technol, 24 (2001) 255. CR - 18. A. Denizli, G. Özkan, M. Uçar, J. Appl. Polym. Sci, 83 (2002) 2411. CR - 20. R. Say, A. Denizli, J. Biomater. Sci. Polym. Ed., 12 (2001) 1059. CR - 21. E. Büyüktuncel, A. Tuncel, Ö. Genç, A. Denizli, Sep. Sci. Technol., 36 (2001) 3427. CR - 22. H. Yavuz, R. Say, N. Bayraktar, M. Andaç, A. Denizli, Biomag. Res. Technol., 2 (2004) 1. CR - 25. N. Demiryas, N. Tüzmen, I.Y. Galaev, E. Pişkin, A. Denizli, J. Appl. Polym. Sci., 105 (2007) 1808. CR - 26. M. McCoy, K. Kalghatgi, F.E. Regnier, N. Afeyan, J. Chromatogr. A., 743 (1996) 221. CR - 27. E.B. Altıntas, A. Denizli, J. Appl. Polym. Sci., 103 (2007) 975. CR - 28. S. Özkara, B. Garipcan, E. Pişkin, A. Denizli, J. Biomater. Sci. Polym. Ed., 14 (2003) 761. CR - 29. V.I. Lozinsky, I.Y. Galaev, F.M. Plieva, I.N. Savina, H. Jungvid, B. Mattiasson, Trends in Biotechnol., 21 (2003) 445. CR - 30. P. Arvidsson, F.M. Plieva, V.I. Lozinsky, I.Y. Galaev, B. Mattiasson, J. Chromatogr. A., 986 (2003) 275. CR - 31. V.I. Lozinsky, F.M. Plieva, I. Y. Galaev, B. Mattiasson, Bioseparation, 10 (2002) 163. CR - 32. P. Arvidsson, F.M. Plieva, I.N. Savina, V.I. Lozinsky, S. Fexby, L. Bülow, I.Y. Galaev, B. Mattiasson, J. Chromatogr. A., 977 (2002) 27. CR - 33. C. Babaç, H. Yavuz, I.Y. Galaev, E. Pişkin, A. Denizli, React. Functl. Polym., 66 (2006) 1263. CR - 34. M.B. Dainiak, I.Y. Galaev, B. Matiasson, J. Chromatogr. A., 1123 (2006) 145. CR - 35. A. Hanora, I. Savina, F.M. Plieva, V.A. Izumrudov, B. Mattiasson, I. Y. Galaev, J. Biotechnol., 123 (2006) 209. CR - 36. P. Arvidsson, F.M. Plieva, I.N. Savina, V.I. Lozinsky, S. Fexby, L. Bülow, I.Y. Galaev, B. Mattiasson, J. Chromatogr. A., 977 (2002) 27. CR - 37. D.K. Singh, A. Mishra, Sep. Sci. Technol., 28 (1993) 1923. CR - 38. V. P. Ravi, R.V. Jasra, R.S.G. Bhat, J. Chem. Technol. Biotechnol., 71 (1998) 173. CR - 39. E.G. Furuya, H.T. Chang, Y. Miura, K.E. Noll., Sep. Purif. Technol., 111 (1997) 69. CR - 40. T.R. Dargaville, M.G. Looney, H.D. Solomon, J. Colloid Interface Sci., 182 (1996) 17. CR - 41. H.T. Shu, D. Li, A.A. Scala, Y.H. Ma, Sep. Purif. Technol., 11 (1997) 27. CR - 42. M. Streat, L.A. Sweetland, React. Functl. Polym., 35 (1997) 99. CR - 43. V.K. Gupta, S. Sharma, D. Mohan, J. Chem. Technol. Biotechnol., 71 (1998) 180. CR - 44. S.H. Lin, M.J. Cheng, Environ. Technol., 21 (2000) 475. CR - 45. M. Ahmaruzzaman, D.K. Sharma, J. Coll. Interf. Sci., 287 (2005) 14. CR - 46. Y.S. Ho, G. McKay, Process Biochem., 34 (1999) 451. CR - 47. S.J. Allen, B. Koumanova, Z. Kircheva, S. Nenkova, Ind. Eng. Chem. Res., 44 (2005) 2281. CR - 48. E. Valdman, L. Erijman, F.L.P. Pessoa, S.G.F. Leite, Process Biochem., 36 (2001) 869. CR - 49. X. Zhu, S.D. Alexandratos, Ind. Eng. Chem. Res., 44 (2005) 8605. UR - https://dergipark.org.tr/en/pub/hjbc/issue//925900 L1 - https://dergipark.org.tr/en/download/article-file/1727508 ER -