@article{article_926073, title={Vibrational Spectroscopic Study of 6-Aminouracil Tetracyanonickelate Complexes}, journal={Hacettepe Journal of Biology and Chemistry}, volume={40}, pages={419–426}, year={2012}, author={Bayrak, Celal}, keywords={6-aminouracil,far-IR,FT-IR,FT-Raman spectra,Hofmann type complexes}, abstract={The FT-IR, FT-Raman and far-IR spectra of two dimensional coordination polymer compounds, M 6AU 2Ni CN 4 where M = Mn, Co, Ni and Cd; 6AU = 6-aminouracil = 4-amino-2,6-dihydroxypyrimidine were reported for the first time. 6-aminouracil molecules are found to involve coordination through one of the pyrimidine ring nitrogen atoms. The spectral features suggest that the compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with Ni CN 42- ions bridged by M 6AU 22+ cations. Vibrational bands originated from both 6AU and Ni CN 4 group were assigned.}, number={4}, publisher={Hacettepe University}