TY - JOUR T1 - An investigation based on removal of ibuprofen and its transformation products by a batch activated sludge process: A kinetic study AU - Özgüven, Ayşe AU - Öztürk, Dilara AU - Bayram, Tuba PY - 2021 DA - December Y2 - 2021 DO - 10.35208/ert.947460 JF - Environmental Research and Technology JO - ERT PB - Mehmet Sinan Bilgili WT - DergiPark SN - 2636-8498 SP - 329 EP - 341 VL - 4 IS - 4 LA - en AB - Ibuprofen metabolites can form in humans as a result of metabolic activities or can be produced by microorganisms in wastewater treatment plants and receiving environments, which increases their likelihood of being present in the environment. In this study, various experiments were conducted to determine the removal degree for ibuprofen, ibuprofen carboxylic acid (IBU-CBX), and 2-hydroxylated ibuprofen (IBU-2-OH) metabolites with an activated sludge reactor. Furthermore, the pseudo-first-order biodegradation rate constant (kbiol) (17.76 L/g SS day) was calculated to determine the decomposition degree of ibuprofen in the batch activated sludge system. The effects of different ibuprofen concentrations (8.2, 5.6, 3.2, 1.51 mg/L) at constant biomass concentration (3 g/L) on the biodegradation mechanism were investigated. In addition, IBU-2-OH and IBU-CBX were tested in a batch activated sludge reactor with a volume of 2 L individually at 100 μg/L with activated sludge containing 3 g/L biomass. It was observed that ibuprofen had a removal efficiency of more than 90%. IBU-CBX and IBU-2-OH were removed at approximately 27-91% and 18-82%, respectively. In abiotic conditions, the removal of ibuprofen was found to be 7.07%. It was confirmed that the removal of ibuprofen largely depended on biological degradation. This study enabled us to know which metabolites are involved in the biodegradation process of ibuprofen in batch experiments with the activated sludge process. KW - Activated sludge KW - ibuprofen KW - metabolite KW - removal CR - A. F. Streit, G. C. Collazzo, S. P. Druzian, R. S. Verdi, E. L. Foletto, L. F. Oliveira, and G. L. Dotto, “Adsorption of ibuprofen, ketoprofen, and paracetamol onto activated carbon prepared from effluent treatment plant sludge of the beverage industry,” Chemosphere, Vol.262, pp.128322, 2021. CR - T. Alvarino, S. Suarez, J.M. Lema, and F. Omil, “Understanding the removal mechanisms of PPCPs and the influence of main technological parameters in anaerobic UASB and aerobic CAS reactors,” Journal of Hazardous Materials, Vol.278, pp.506-513, 2014. UR - https://doi.org/10.35208/ert.947460 L1 - https://dergipark.org.tr/en/download/article-file/1805111 ER -