TY  - JOUR
T1  - THE WITTIG REACTION WITH 2,2-DIMETHYL-l,3-INDANDIONE
AU  - Uyar, Tahsin
PY  - 1899
DA  - January
DO  - 10.1501/Commub_0000000486
JF  - Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
JO  - Commun. Fac. Sci. Univ. Ank. Ser. B
PB  - Ankara University
WT  - DergiPark
SN  - 1303-6017
SP  - 48
EP  - 52
VL  - 34
IS  - 01.02
LA  - en
AB  - The reactions of 2,2-dimethyl-l,3-indandione (I) with several Wittig reagents have been studied. When I was reacted with one or two equimolar amounts of active phosphoranes, such as methylene and ethylidenetriphenylphosphorane, bismethylene- and bisethylidene deriva- tives of the indandione were obtained in fairly good yields. The reactions of I with resonance- stabilized phosphoranes such as ethoxycarbony!methylene-2—butylidene— and carboethoxy— 2-methyl-2-propylidenetriphenylphosphorane gave monoalkylideneindanones in moderate or in pocr yields at severe conditions. On the contrary, the reaction of I with carboethoxymethyle- netriphenylphosphorane in sealed tube gave the bisalkylidene derivative of the indandione at 160°C.
KW  - The reactions
KW  - When I was reacted
KW  - On the contrary
CR  - Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
UR  - https://doi.org/10.1501/Commub_0000000486
L1  - https://dergipark.org.tr/en/download/article-file/1991133
ER  -