ANALYSIS OF MAGNETIC FIELD EFFECTS ON Kα AND Kβ XRF SPECTRA OF SELENIDE COMPOUNDS

Year 2019, NSP2018 Special Issue, 52 - 58, 28.03.2019

Harun Çümen Merve Meltem Hatipoğulları Tuba Akkuş Sevil Porikli Durdağı

Abstract

In this work,
EDXRF are used to demonstrate the effect of an applied magnetic field, on the
determination of energy of X-ray line, full width at half maximum (FWHM),
asymmetry index (AI) and intensity ratio values. To this end, various initial
magnetic fields were induced on a selenide compounds, and for each level of
residual magnetic field, their corresponding Kα and Kβ
spectra were collected from a Si(Li) detector. The results showed a strong correlation between the residual sample
magnetic field and the atomic parameters such as energy shifts and asymmetry
indices. It was observed that the chemical shift values increases with
applying the sample magnetic field but FWHM values starts decreasing with
higher levels of initial residual magnetic fields. 

Keywords

EDXRF, External Magnetic Field, Intensity Ratio

References

• [1] K. Kawatsura, N. Takeshima, T. Imaoku, K. Takahiro, Y. Mokuno, Y. Horino, T. Sekioka, M. Terasawa, High-resolution X-ray spectroscopy for copper and copper oxides and a new WDX system using an ion microbeam, Nucl. Instr. Meth. Phys. B 193 (2002) 877–882.
• [2] Y. Mokuno, Y. Horino, T. Tadic, M. Terasawa, A. Kinomura, A. Chayahara, N. Tsubouchi, WDX-PIXE analysis of low energy X-rays using a microbeam, Nucl. Instr. Meth. Phys. B 150 (1999) 109–113.
• [3] S. Nishibu, S. Yonezawa, M. Takashima, Chemical state analysis of fluorine invarious compounds using X-ray fluorescence spectra, J. Fluor. Chem. 126 (7) (2005) 1048–1053.
• [4] E. Öz, E. Baydaş, Y. Şahin, Chemical shifts of Kα and Kβ1,3 x-ray emission spectra for oxygen compounds of Ti, Cr, Fe Co, Cu with WDXRF, J. Radioanal. Nucl. Chem. 279 (2) (2009) 529–537.
• [5] M.R. Kacal, I. Han, F. Akman, R. Durak, Measurement of L subshell fluorescence yields for high-Z elements excited by 22.6 keV photons, J. Quant. Spectrosc. Radiat. Transf. 113 (2012) 373-381.
• [6] V. Aylikci, A. Kahoul, N. KupAylikci, E. Tiraşoğlu, A. Abassi, IH Karahan, M. Dogan, Empirical and semi-empirical interpolation of L X-ray fluorescenceparameters for elements in the atomic range 50 ≤ Z ≤ 92, Radiat. Phys. Chem. 106 (2015) 99-125.
• [7] BG. Durdu, A. Kucukonder, Variation of the L X-ray fluorescence crosssections,intensity ratios and fluorescence yields of Sm and Eu in halogen compounds, Radiat. Phys. Chem. 81 (2012) 135-142.
• [8] S. Porikli, Chemical shift and intensity ratio values of dyspersium, holmiumand erbium L X-ray emission lines, Radiat. Phys. Chem. 81 (2012) 113-117.
• [9] A. Kumar, S. Puri, Li(i=1–3) sub-shell x-ray relative intensities for some compounds of 66Dy at 22.6 and 59.54 keV incident photon energies, Radiation Physics and Chemistry 81(7):735–739.
• [10] S. Krishnananda, M. Santosh, N. M. Badiger, M. K. Tiwari, Measurement of the radiative L 3-M vacancy transfer probabilities of some 4f elements and compounds using Indus-2 synchrotron radiation, Chemical Physics Letters, 658, 2016
• [11] S. Vasala, M. Karppinen, A2B′B″O6 perovskites: a review, Prog. Solid State Chem. 43 (2015) 1–36.
• [12] D. Demir, Y. Şahin, The effect of an external magnetic field on the L3 subshell fluorescence yields and level widths for Ta, W, Tl, Th and U at 59.54 keV photons, Eur. Phys. J. D. 44, (2006) 17.
• [13] S. Porikli, D. Demir, Y. Kurucu, Variation of Kβ/Kα X-ray intensity ratio and lineshape with the effect of external magnetic field and chemical combination, Eur. Phys. J. D 47, (2008) 315–323.