İnsan Saçı Örneklerinde Talyumun Katı Örneklemeli Atomik Absorpsiyon Yöntemi İle Tayini
Year 2015,
Volume: 1 Issue: 1, 51 - 66, 16.10.2015
Asli Baysal
Süleyman Akman
Abstract
Bu çalışmada insan saçında talyum için doğrudan katı örneklemeli atomik absorpsiyon spektrometresi ile tayini için yöntem geliştirilmiştir. İnsan saçı örnekleri aseton, destile deiyonize su ve tekrar aseton ile yıkanmış ve 75 oC’de kurutulmuştur. Saç örnekleri doğrudan katı örneklemeli oto-örnekleyiciye yüklenmiştir. Katı örnekleme tekniği ile talyum tayini için piroliz/atomlaşma sıcaklığı, madde miktarı ve bunlara modifier (Pd/Mg) ve/veya yardımcı reaktiflerin etkisi incelenmiştir. Aletsel ve deneysel parametreler optimize edildikten sonra iki farklı sertifikalı referans maddesi ile geri kazanım çalışmaları yapılmıştır. Talyum için ortalama geri kazanım % 94’tir. Talyum için tayin sınırı (3σ, N=10) sırasıyla 0.0067 μg/g’dır.
References
- [1] International Atomic Energy Agency, Activation analysis of hair
as an indicator of contamination of man by environmental trace
element pollutants, Report IAEA/RL/50, Vienna. 1978.
[2] Jenkins, D.W., Biological Monitoring of Toxic Trace Metals,
E.P.A. (Pub. No. 600/3-8-089) Washington. D.C. 1980.
[3] Baumgartner, W.A., Hill, V.A., Blahd, W.H., Hair Analysis for
Drugs of Abuse, Journal of Forensic Sciences,
1989; 34, 1433-1453.
[4] Assarian, G.S., Oberleas, D., Effect of washing procedures on
trace-element content of hair, Clinical Chemistry,
1977; 23, 1771-1772.
[5] Esteban, E., Rubin, C., Jones, R., Noonan, G., Hair and blood
as substrates for screening children for lead poisoning, Archives of
Environmental Health, 1999; 54, 436-440.
[6] Saiki, M., Alves, E.R., Jaluul, O., Sumita, N.M., Jacob Filho, W.,
Determination of trace elements in scalp hair of an elderly
population by neutron activation analysis, Journal of Radioanalytical
and Nuclear Chemistry, 2008; 276, 53-57.
[7] Kolmogorov, Y., Kovaleva, V., Gonchar, A., Analysis of trace
elements in scalp hair of healthy people, hyperplasia and breast
cancer patients with XRF method, Nuclear Instruments and
Methods in Physics Research, Sect. A, 2000; 448, 457-460.
[8] Forte, G., Alimonti, A., Violante, N., Di Gregorio, M., Senofonte,
O., Petrucci, F., Sancesario, G., Bocca, B., Calcium, copper, iron,
magnesium, silicon and zinc content of hair in Parkinson’s disease,
Journal of Trace Elements in Medicine & Biology,
2005; 19, 195-201.
[9] Steely, S., Amarasiriwardena, D., Jones, J., Yanez, J., A rapid
approach for assessment of arsenic exposure by elemental analysis
of single strand of hair using laser ablation-inductively coupled
plasma-mass spectrometry, Microchemical Journal,
2007; 86, 235-240.
[10] Lafleur, J.P., Lam, R., Chan, H.M., Salin, E.D., Induction heatingelectrothermal
vaporization for direct mercury analysis of a single
human hair strand by inductively coupled plasma mass spectrometry,
Journal of Analytical Atomic Spectrometry, 2005; 20, 1315-1317.
[11] Paschal, D.C., DiPietro, R.S., Phillips, D.L., Gunter, E.W., Age
dependence of metals in hair in a selected U.S. population,
Environmental Research, 1989; 48, 17-28.
[12] Stephenson, J., X-ray analysis of hair reveals breast cancer, The
Journal of the American Medical Association,
1999; 281, 1578-1579.
[13] Sakamoto, T., Tanaka, A., Nakahara, Y., Hair Analysis for Drugs
of Abuse XII. Determination of PCP and Its Major Metabolites
PCHP and PPC in Rat Hair after Administration of PCP, Journal of
Analytical Toxicology, 1996; 20, 124-130.
[14] Asadoulahi T., Dadfarnia S., Shabani A. M. H., Determination
of Thallium Traces by ETAAS after On-Line Matrix Separation
and Preconcentration in a Flow Injection System, J. Braz. Chem.
Soc., 2007;18, 1353-1359.
[15] Welz, B., Sperling, M., Atomic Absorption Spectrometry, 3 rd Ed.,
Wiley-VCH. Weinheim, Newyork. 1999.
[16] Kurfürst, U., Solid Sample Analysis – Direct and Slurry Sampling
Using GF AAS and ETV-ICP, Springer, Berlin. 1998.
[17] Jablonska-Czapla M., Arsenic, Antimony, Chromium, and
Thallium Speciation in Water and Sediment Samples with the LC-
ICP-MS Technique, International Journal of Analytical Chemistry,
2015, Article ID 171478, 13 pages.
[18] Revanasıddappa H. D., Kıran Kumar T. N., A Novel Method for
the Spectrophotometric Determination of Thallium Using
Methiomeprazine Hydrochloride, Turk J Chem 2005; 29, 265-272.
Year 2015,
Volume: 1 Issue: 1, 51 - 66, 16.10.2015
Asli Baysal
Süleyman Akman
References
- [1] International Atomic Energy Agency, Activation analysis of hair
as an indicator of contamination of man by environmental trace
element pollutants, Report IAEA/RL/50, Vienna. 1978.
[2] Jenkins, D.W., Biological Monitoring of Toxic Trace Metals,
E.P.A. (Pub. No. 600/3-8-089) Washington. D.C. 1980.
[3] Baumgartner, W.A., Hill, V.A., Blahd, W.H., Hair Analysis for
Drugs of Abuse, Journal of Forensic Sciences,
1989; 34, 1433-1453.
[4] Assarian, G.S., Oberleas, D., Effect of washing procedures on
trace-element content of hair, Clinical Chemistry,
1977; 23, 1771-1772.
[5] Esteban, E., Rubin, C., Jones, R., Noonan, G., Hair and blood
as substrates for screening children for lead poisoning, Archives of
Environmental Health, 1999; 54, 436-440.
[6] Saiki, M., Alves, E.R., Jaluul, O., Sumita, N.M., Jacob Filho, W.,
Determination of trace elements in scalp hair of an elderly
population by neutron activation analysis, Journal of Radioanalytical
and Nuclear Chemistry, 2008; 276, 53-57.
[7] Kolmogorov, Y., Kovaleva, V., Gonchar, A., Analysis of trace
elements in scalp hair of healthy people, hyperplasia and breast
cancer patients with XRF method, Nuclear Instruments and
Methods in Physics Research, Sect. A, 2000; 448, 457-460.
[8] Forte, G., Alimonti, A., Violante, N., Di Gregorio, M., Senofonte,
O., Petrucci, F., Sancesario, G., Bocca, B., Calcium, copper, iron,
magnesium, silicon and zinc content of hair in Parkinson’s disease,
Journal of Trace Elements in Medicine & Biology,
2005; 19, 195-201.
[9] Steely, S., Amarasiriwardena, D., Jones, J., Yanez, J., A rapid
approach for assessment of arsenic exposure by elemental analysis
of single strand of hair using laser ablation-inductively coupled
plasma-mass spectrometry, Microchemical Journal,
2007; 86, 235-240.
[10] Lafleur, J.P., Lam, R., Chan, H.M., Salin, E.D., Induction heatingelectrothermal
vaporization for direct mercury analysis of a single
human hair strand by inductively coupled plasma mass spectrometry,
Journal of Analytical Atomic Spectrometry, 2005; 20, 1315-1317.
[11] Paschal, D.C., DiPietro, R.S., Phillips, D.L., Gunter, E.W., Age
dependence of metals in hair in a selected U.S. population,
Environmental Research, 1989; 48, 17-28.
[12] Stephenson, J., X-ray analysis of hair reveals breast cancer, The
Journal of the American Medical Association,
1999; 281, 1578-1579.
[13] Sakamoto, T., Tanaka, A., Nakahara, Y., Hair Analysis for Drugs
of Abuse XII. Determination of PCP and Its Major Metabolites
PCHP and PPC in Rat Hair after Administration of PCP, Journal of
Analytical Toxicology, 1996; 20, 124-130.
[14] Asadoulahi T., Dadfarnia S., Shabani A. M. H., Determination
of Thallium Traces by ETAAS after On-Line Matrix Separation
and Preconcentration in a Flow Injection System, J. Braz. Chem.
Soc., 2007;18, 1353-1359.
[15] Welz, B., Sperling, M., Atomic Absorption Spectrometry, 3 rd Ed.,
Wiley-VCH. Weinheim, Newyork. 1999.
[16] Kurfürst, U., Solid Sample Analysis – Direct and Slurry Sampling
Using GF AAS and ETV-ICP, Springer, Berlin. 1998.
[17] Jablonska-Czapla M., Arsenic, Antimony, Chromium, and
Thallium Speciation in Water and Sediment Samples with the LC-
ICP-MS Technique, International Journal of Analytical Chemistry,
2015, Article ID 171478, 13 pages.
[18] Revanasıddappa H. D., Kıran Kumar T. N., A Novel Method for
the Spectrophotometric Determination of Thallium Using
Methiomeprazine Hydrochloride, Turk J Chem 2005; 29, 265-272.