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DEGREE OF CONVERSION OF NOVEL LOW-SHRINKING COMPOSITES AND METHACRYLATE-BASED RESIN COMPOSITE

Year 2014, Volume: 24 Issue: 1, 39 - 43, 11.02.2015
https://doi.org/10.17567/dfd.06689

Abstract

Purpose: The purpose of this in-vitro study was to determine the degree of conversion of three different composite materials. Material and Methods: In this study three composite materials were analyzed; a traditional methacylate-based composite (Premise, Kerr, Orange, CA, USA), a silorane-based composite (Filtek Silorane, 3M ESPE, St.Paul. MN, USA) and a novel low-shrinking composite (GC Kalore, GC Europe, Leuven, Belgium). Degree of conversion was measured on the composite with FTIR spectroscopy (Perkin Elmer Spectrum One, MA, USA). FTIR analyses were performed at the prepolymerization and post-polymerization stages of tested materials. Results: The silorane-based novel composite resin Filtek Silorane (58,60%) showed significantly higher conversion degree when compared to Premise (44,65%) and Kalore (44,53%). Conclusion: The conversion degree of resin composite might depend on monomer structure and siloranbased composite polymerized better than other tested composites

References

  • Tarle Z, Meniga A, Knezevic A, Sutalo J, Ristic M, Pichler G. Composite conversion and temperature rise using a conventional, plasma arc, and an experimental blue LED curing unit. J Oral Rehabil. 2002;29:662-7.
  • Caughman WF, Caughman GB, Shiflett RA, Rueggeberg F, Schuster GS. Correlation of cytotoxicity, filler loading and curing time of dental composites. Biomaterials. 1991;12:737-40.
  • Ferracane JL. Correlation between hardness and degree of conversion during the setting reaction of unfilled dental restorative resins. Dent Mater 1985;1:11-4.
  • Ferracane JL, Mitchem JC, Condon JR, Todd R. Wear and marginal breakdown of composites with various degrees of cure. J Dent Res. 1997;76:1508-16.
  • Inoue K, Hayashi I. Residual monomer (Bis-GMA) of composite resins. J Oral Rehabil. 1982;9:493-7.
  • Weinmann W, Thalacker C, Guggenberger R. Siloranes in dental composites. Dent Mater 2005;21:68-74.
  • Labella R, Lambrechts P, Van Meerbeek B, Vanherle G. Polymerization shrinkage and elasticity of flowable composites and filled adhesives. Dent Mater 1999;15:128-37.
  • Ilie N, Hickel R. Silorane-based dental composite: behavior and abilities. Dent Mater J 2006;25:445- 54.
  • Palin WM, Fleming GJ, Nathwani H, Burke FJ, Randall RC. In vitro cuspal deflection and microleakage of maxillary premolars restored with novel low-shrink dental composites. Dent Mater 2005;21:324-35.
  • Guggenberger R, Weinmann W. Exploring beyond methacrylates. Am J Dent 2000;13(Spec No):82D- 4D.
  • Gökçe K, Özel E. Kompozit restorasyonlarda son gelişmeler. Atatürk Üniv. Diş Hek. Fak. Dergisi 2005;15:52-60.
  • Naoum SJ, Ellakwa A, Morgan L, White K, Martin FE, Lee IB. Polymerization profile analysis of resin composite dental restorative materials in real time. J Dent. 2012;40:64-70.
  • Imazato S, McCabe JF, Tarumi H, Ehara A, Ebisu S. Degree of conversion of composites measured by DTA and FTIR. Dent Mater 2001;17:178-83.
  • Michelsen VB, Lygre H, Skalevik R, Tveit AB, Solheim E. Identification of organic eluates from four polymer-based dental filling materials. Eur J Oral Sci 2003;111:263-71.
  • Wendl B, Droschl H, Kern W. A comparative study of polymerization lamps to determine the degree of cure of composites using infrared spectroscopy. Eur J Orthodont. 2004;26:545-51.
  • Davidson CL, Degee AJ, Feilzer A. The Competition between the Composite-Dentin Bond Strength and the Polymerization Contraction Stress. J Dent Res 1984;63:1396-9.
  • Yoon TH, Lee YK, Lim BS, Kim CW. Degree of polymerization of resin composites by different light sources. J Oral Rehabil. 2002;29:1165-73.
  • Knezevic A, Tarle Z, Meniga A, Sutalo J, Pichler G, Ristic M. Degree of conversion and temperature rise during polymerization of composite resin samples with blue diodes. J Oral Rehabil. 2001;28:586-91.
  • Kusgoz A, Ulker M, Yesilyurt C, Yoldas OH, Ozil M, Tanriver M. Silorane-Based Composite: Depth of Cure, Surface Hardness, Degree of Conversion, and Cervical Microleakage in Class II Cavities. J Esthet Restor Dent. 2011;23:324-35.
  • Frauscher KE, Ilie N. Degree of conversion of nano-hybrid resin-based composites with novel and conventional matrix formulation. Clin Oral Invest. 2013;17:635-42.
  • Papadogiannis D, Kakaboura A, Palaghias G, Eliades G. Setting characteristics and cavity adaptation of low-shrinking resin composites. Dent Mater 2009;25:1509-16.
  • Silikas N, Eliades G, Watts DC. Light intensity effects on resin-composite degree of conversion and shrinkage strain. Dent Mater 2000;16:292-6.
  • Sakaguchi RL, Berge HX. Reduced light energy density decreases post-gel contraction while maintaining degree of conversion in composites. J Dent. 1998;26:695-700.

DÜŞÜK POLİMERİZASYON BÜZÜLMESİ GÖSTEREN MODERN KOMPOZİTLER İLE METAKRİLAT ESASLI REZİN KOMPOZİTİN KONVERSİYON ORANLARININ DEĞERLENDİRİLMESİ

Year 2014, Volume: 24 Issue: 1, 39 - 43, 11.02.2015
https://doi.org/10.17567/dfd.06689

Abstract

 Amaç: Bu in-vitro çalışmanın amacı üç farklı rezin kompozitin konversiyon oranlarının belirlenmesidir.

Gereç ve Yöntem: Bu çalışmada üç farklı rezin kompozit değerlendirildi; bir geleneksel metakrilat esaslı kompozit (Premise, Kerr, Orange, CA, ABD), bir siloran esaslı kompozit (Filtek Silorane, 3M ESPE, St.Paul. MN, ABD) ve yeni bir düşük polimerizasyon özelliğine sahip kompozit (GC Kalore, GC Europe, Leuven, Belçika). Kompozit örneklerinin konversiyon oranlarının ölçümleri bir FTIR spektroskopi (Perkin Elmer Spectrum One, MA, ABD) ile yapıldı. Tüm kompozit rezin örnekleri için FTIR ölçümleri, örnekler polimerize edilmeden önce ve örnekler polimerize edildikten sonra gerçekleştirildi.

Bulgular: Siloran esaslı kompozit Filtek Siloran (%58,60), istatistiksel olarak anlamlı bir şekilde Premise (%44,65) ve Kalore'den (%44,53) daha yüksek konversiyon oranı gösterdi.

Sonuç: Rezin kompozitlerin konversiyon oranı monomer yapılarına bağlı olarak değişebilmektedir ve siloran esaslı kompozitler daha iyi polimerize olabilmektedir.

References

  • Tarle Z, Meniga A, Knezevic A, Sutalo J, Ristic M, Pichler G. Composite conversion and temperature rise using a conventional, plasma arc, and an experimental blue LED curing unit. J Oral Rehabil. 2002;29:662-7.
  • Caughman WF, Caughman GB, Shiflett RA, Rueggeberg F, Schuster GS. Correlation of cytotoxicity, filler loading and curing time of dental composites. Biomaterials. 1991;12:737-40.
  • Ferracane JL. Correlation between hardness and degree of conversion during the setting reaction of unfilled dental restorative resins. Dent Mater 1985;1:11-4.
  • Ferracane JL, Mitchem JC, Condon JR, Todd R. Wear and marginal breakdown of composites with various degrees of cure. J Dent Res. 1997;76:1508-16.
  • Inoue K, Hayashi I. Residual monomer (Bis-GMA) of composite resins. J Oral Rehabil. 1982;9:493-7.
  • Weinmann W, Thalacker C, Guggenberger R. Siloranes in dental composites. Dent Mater 2005;21:68-74.
  • Labella R, Lambrechts P, Van Meerbeek B, Vanherle G. Polymerization shrinkage and elasticity of flowable composites and filled adhesives. Dent Mater 1999;15:128-37.
  • Ilie N, Hickel R. Silorane-based dental composite: behavior and abilities. Dent Mater J 2006;25:445- 54.
  • Palin WM, Fleming GJ, Nathwani H, Burke FJ, Randall RC. In vitro cuspal deflection and microleakage of maxillary premolars restored with novel low-shrink dental composites. Dent Mater 2005;21:324-35.
  • Guggenberger R, Weinmann W. Exploring beyond methacrylates. Am J Dent 2000;13(Spec No):82D- 4D.
  • Gökçe K, Özel E. Kompozit restorasyonlarda son gelişmeler. Atatürk Üniv. Diş Hek. Fak. Dergisi 2005;15:52-60.
  • Naoum SJ, Ellakwa A, Morgan L, White K, Martin FE, Lee IB. Polymerization profile analysis of resin composite dental restorative materials in real time. J Dent. 2012;40:64-70.
  • Imazato S, McCabe JF, Tarumi H, Ehara A, Ebisu S. Degree of conversion of composites measured by DTA and FTIR. Dent Mater 2001;17:178-83.
  • Michelsen VB, Lygre H, Skalevik R, Tveit AB, Solheim E. Identification of organic eluates from four polymer-based dental filling materials. Eur J Oral Sci 2003;111:263-71.
  • Wendl B, Droschl H, Kern W. A comparative study of polymerization lamps to determine the degree of cure of composites using infrared spectroscopy. Eur J Orthodont. 2004;26:545-51.
  • Davidson CL, Degee AJ, Feilzer A. The Competition between the Composite-Dentin Bond Strength and the Polymerization Contraction Stress. J Dent Res 1984;63:1396-9.
  • Yoon TH, Lee YK, Lim BS, Kim CW. Degree of polymerization of resin composites by different light sources. J Oral Rehabil. 2002;29:1165-73.
  • Knezevic A, Tarle Z, Meniga A, Sutalo J, Pichler G, Ristic M. Degree of conversion and temperature rise during polymerization of composite resin samples with blue diodes. J Oral Rehabil. 2001;28:586-91.
  • Kusgoz A, Ulker M, Yesilyurt C, Yoldas OH, Ozil M, Tanriver M. Silorane-Based Composite: Depth of Cure, Surface Hardness, Degree of Conversion, and Cervical Microleakage in Class II Cavities. J Esthet Restor Dent. 2011;23:324-35.
  • Frauscher KE, Ilie N. Degree of conversion of nano-hybrid resin-based composites with novel and conventional matrix formulation. Clin Oral Invest. 2013;17:635-42.
  • Papadogiannis D, Kakaboura A, Palaghias G, Eliades G. Setting characteristics and cavity adaptation of low-shrinking resin composites. Dent Mater 2009;25:1509-16.
  • Silikas N, Eliades G, Watts DC. Light intensity effects on resin-composite degree of conversion and shrinkage strain. Dent Mater 2000;16:292-6.
  • Sakaguchi RL, Berge HX. Reduced light energy density decreases post-gel contraction while maintaining degree of conversion in composites. J Dent. 1998;26:695-700.
There are 23 citations in total.

Details

Primary Language Turkish
Subjects Dentistry
Journal Section Articles
Authors

Çağatay Barutcugil This is me

Fuat Ahmetoğlu This is me

Hacer Turgut This is me

Burak Dayı This is me

Muhammet Yalçın This is me

Publication Date February 11, 2015
Published in Issue Year 2014 Volume: 24 Issue: 1

Cite

APA Barutcugil, Ç., Ahmetoğlu, F., Turgut, H., Dayı, B., et al. (2015). DÜŞÜK POLİMERİZASYON BÜZÜLMESİ GÖSTEREN MODERN KOMPOZİTLER İLE METAKRİLAT ESASLI REZİN KOMPOZİTİN KONVERSİYON ORANLARININ DEĞERLENDİRİLMESİ. Atatürk Üniversitesi Diş Hekimliği Fakültesi Dergisi, 24(1), 39-43. https://doi.org/10.17567/dfd.06689
AMA Barutcugil Ç, Ahmetoğlu F, Turgut H, Dayı B, Yalçın M. DÜŞÜK POLİMERİZASYON BÜZÜLMESİ GÖSTEREN MODERN KOMPOZİTLER İLE METAKRİLAT ESASLI REZİN KOMPOZİTİN KONVERSİYON ORANLARININ DEĞERLENDİRİLMESİ. Ata Diş Hek Fak Derg. February 2015;24(1):39-43. doi:10.17567/dfd.06689
Chicago Barutcugil, Çağatay, Fuat Ahmetoğlu, Hacer Turgut, Burak Dayı, and Muhammet Yalçın. “DÜŞÜK POLİMERİZASYON BÜZÜLMESİ GÖSTEREN MODERN KOMPOZİTLER İLE METAKRİLAT ESASLI REZİN KOMPOZİTİN KONVERSİYON ORANLARININ DEĞERLENDİRİLMESİ”. Atatürk Üniversitesi Diş Hekimliği Fakültesi Dergisi 24, no. 1 (February 2015): 39-43. https://doi.org/10.17567/dfd.06689.
EndNote Barutcugil Ç, Ahmetoğlu F, Turgut H, Dayı B, Yalçın M (February 1, 2015) DÜŞÜK POLİMERİZASYON BÜZÜLMESİ GÖSTEREN MODERN KOMPOZİTLER İLE METAKRİLAT ESASLI REZİN KOMPOZİTİN KONVERSİYON ORANLARININ DEĞERLENDİRİLMESİ. Atatürk Üniversitesi Diş Hekimliği Fakültesi Dergisi 24 1 39–43.
IEEE Ç. Barutcugil, F. Ahmetoğlu, H. Turgut, B. Dayı, and M. Yalçın, “DÜŞÜK POLİMERİZASYON BÜZÜLMESİ GÖSTEREN MODERN KOMPOZİTLER İLE METAKRİLAT ESASLI REZİN KOMPOZİTİN KONVERSİYON ORANLARININ DEĞERLENDİRİLMESİ”, Ata Diş Hek Fak Derg, vol. 24, no. 1, pp. 39–43, 2015, doi: 10.17567/dfd.06689.
ISNAD Barutcugil, Çağatay et al. “DÜŞÜK POLİMERİZASYON BÜZÜLMESİ GÖSTEREN MODERN KOMPOZİTLER İLE METAKRİLAT ESASLI REZİN KOMPOZİTİN KONVERSİYON ORANLARININ DEĞERLENDİRİLMESİ”. Atatürk Üniversitesi Diş Hekimliği Fakültesi Dergisi 24/1 (February 2015), 39-43. https://doi.org/10.17567/dfd.06689.
JAMA Barutcugil Ç, Ahmetoğlu F, Turgut H, Dayı B, Yalçın M. DÜŞÜK POLİMERİZASYON BÜZÜLMESİ GÖSTEREN MODERN KOMPOZİTLER İLE METAKRİLAT ESASLI REZİN KOMPOZİTİN KONVERSİYON ORANLARININ DEĞERLENDİRİLMESİ. Ata Diş Hek Fak Derg. 2015;24:39–43.
MLA Barutcugil, Çağatay et al. “DÜŞÜK POLİMERİZASYON BÜZÜLMESİ GÖSTEREN MODERN KOMPOZİTLER İLE METAKRİLAT ESASLI REZİN KOMPOZİTİN KONVERSİYON ORANLARININ DEĞERLENDİRİLMESİ”. Atatürk Üniversitesi Diş Hekimliği Fakültesi Dergisi, vol. 24, no. 1, 2015, pp. 39-43, doi:10.17567/dfd.06689.
Vancouver Barutcugil Ç, Ahmetoğlu F, Turgut H, Dayı B, Yalçın M. DÜŞÜK POLİMERİZASYON BÜZÜLMESİ GÖSTEREN MODERN KOMPOZİTLER İLE METAKRİLAT ESASLI REZİN KOMPOZİTİN KONVERSİYON ORANLARININ DEĞERLENDİRİLMESİ. Ata Diş Hek Fak Derg. 2015;24(1):39-43.

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