ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU

Year 2015, Volume: 16 Issue: 2, 283 - 292, 11.11.2015

Deniz Uzunoğlu , Ayla Özer Ercan Tuncay Ercan Tuncay Abdullah Küntaş

https://doi.org/10.18038/btd-a.25614

Abstract

Bu çalışmada, AB 324’ün levrek balığı pulu (LBP)’na adsorbsiyonu kesikli bir sistemde araştırılmış; optimum ortam koşulları; başlangıç pH’sı 2.0, sıcaklık 25 oC, başlangıç AB 324 derişimi 200 mg/L ve adsorbent derişimi 1.0 g/L olarak belirlenmiştir. Çalışılan balık pulunun izoelektrik pH’sı 7.25 olarak belirlenmiş; izoelektrik pH değerinden daha düşük pH değerlerinde yüksek giderimler elde edilmiştir. Adsorpsiyon dengesinin Langmuir izoterm modeline, kinetik verilerin ise yalancı ikinci mertebe kinetik modeline çok iyi uyduğu saptanmıştır.  AB 324’ün levrek balığı pulu (LBP)’na adsorbsiyonunda tanecik içi ve dışı difüzyonun etkili olduğu sonucuna varılmıştır. Termodinamik çalışmalar AB 324’ün LBP’na adsorbsiyonunun ekzotermik ve istemli olduğunu göstermiştir. LBP’nun adsorpsiyon öncesi ve sonrası karakterizasyonu FTIR, SEM ve EDX analizleri ile gerçekleştirilmiştir. 

Keywords

Acid Blue 324, Adsorption, Wastewater treatment, Fish scale, Dyestuff

ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU

Abstract

Bu çalışmada, AB 324’ün levrek balığı pulu (LBP)’na adsorbsiyonu kesikli bir sistemde
araştırılmış; optimum ortam koşulları; başlangıç pH’sı 2.0, sıcaklık 25 oC, başlangıç AB 324 derişimi
200 mg/L ve adsorbent derişimi 1.0 g/L olarak belirlenmiştir. Çalışılan balık pulunun izoelektrik pH’sı
7.25 olarak belirlenmiş; izoelektrik pH değerinden daha düşük pH değerlerinde yüksek giderimler elde
edilmiştir. Adsorpsiyon dengesinin Langmuir izoterm modeline, kinetik verilerin ise yalancı ikinci
mertebe kinetik modeline çok iyi uyduğu saptanmıştır. AB 324’ün levrek balığı pulu (LBP)’na
adsorbsiyonunda tanecik içi ve dışı difüzyonun etkili olduğu sonucuna varılmıştır. Termodinamik
çalışmalar AB 324’ün LBP’na adsorbsiyonunun ekzotermik ve istemli olduğunu göstermiştir. LBP’nun
adsorpsiyon öncesi ve sonrası karakterizasyonu FTIR, SEM ve EDX analizleri ile gerçekleştirilmiştir.

Keywords

Acid Blue 324, Adsorpsiyon, Atık su arıtımı, Balık pulu, Boyarmadde

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