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ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU

Year 2015, Volume: 16 Issue: 2, 283 - 292, 11.11.2015
https://doi.org/10.18038/btd-a.25614

Abstract

Bu çalışmada, AB 324’ün levrek balığı pulu (LBP)’na adsorbsiyonu kesikli bir sistemde araştırılmış; optimum ortam koşulları; başlangıç pH’sı 2.0, sıcaklık 25 oC, başlangıç AB 324 derişimi 200 mg/L ve adsorbent derişimi 1.0 g/L olarak belirlenmiştir. Çalışılan balık pulunun izoelektrik pH’sı 7.25 olarak belirlenmiş; izoelektrik pH değerinden daha düşük pH değerlerinde yüksek giderimler elde edilmiştir. Adsorpsiyon dengesinin Langmuir izoterm modeline, kinetik verilerin ise yalancı ikinci mertebe kinetik modeline çok iyi uyduğu saptanmıştır.  AB 324’ün levrek balığı pulu (LBP)’na adsorbsiyonunda tanecik içi ve dışı difüzyonun etkili olduğu sonucuna varılmıştır. Termodinamik çalışmalar AB 324’ün LBP’na adsorbsiyonunun ekzotermik ve istemli olduğunu göstermiştir. LBP’nun adsorpsiyon öncesi ve sonrası karakterizasyonu FTIR, SEM ve EDX analizleri ile gerçekleştirilmiştir. 

References

  • Alok, M., Jhare, D. and Mittal, J. (2013). Adsorption of Hazardous Dye Eosin Yellow from Aqueous Solution onto Waste Material De-oiled Soya: Isotherm, Kinetics and Bulk Removal Journal of Molecular Liquids 179, 133-140.
  • Basu, A., Mustafiz, S., Islam, M.R., Bjorndalen, N., Rahaman, M.S. and Chaalal, O. (2006). A Comprehensive Approach for Modeling Sorption of Lead and Cobalt ions Through Fish Scales as an Adsorbent Chemical Engineering Communications 193.5, 580-605.
  • Boparai, H.K., Joseph, M. and O’Carroll, D.M. (2011). Kinetics and Thermodynamics of Cadmium ion Removal by Adsorption onto Nano Zerovalent Iron Particles Journal of Hazardous Materials 186.1, 458-465.
  • Chowdhury, S., Das Saha, P. and Ghosh, U. (2012). Fish (Labeo rohita) Scales as Potential Low-Cost Biosorbent for Removal of Malachite Green from Aqueous Solutions, Bioremediation Journal 16, 235-242.
  • Dong, Z., Wang, D., Liu, X., Pei, X., Chen, L. and Jin, J. (2014). Bio-inspired Surface-Functionalization of Graphene Oxide for The Adsorption Of Organic Dyes and Heavy Metal Ions with a Superhigh Capacity Journal of Materials Chemistry A 2.14, 5034-5040.
  • Du, L.N., Wang, B., Li, G., Wang, S., Crowley, D.E. and Zhao, Y.H. (2012). Biosorption of the Metal- complex Dye Acid Black 172 by Live and Heat-Treated Biomass of Pseudomonas Strain DY1: Kinetics and Sorption Mechanisms Journal of Hazardous Materials 205, 47-54.
  • El-Bindary, A.A., El-Sonbati, A.Z., Al-Sarawy, A.A., Mohamed, K.S. and Farid, M.A. (2014). Adsorption and Thermodynamic Studies of Hazardous Azocoumarin Dye from an Aqueous Solution onto Low Cost Rice Straw Based Carbons Journal of Molecular Liquids 199, 71-78.
  • Gupta, V.K., Bhushan, R., Nayak, A., Singh, P. and Bhushan, B. (2014). Biosorption and Reuse Potential of a Blue Green Alga for the Removal of Hazardous Reactive Dyes from Aqueous Solutions Bioremediation Journal 18.3, 179-191.
  • Hameed, B.H., Ahmad, A.A. and Aziz, N. (2007). Isotherms, Kinetics and Thermodynamics of Acid Dye Adsorption on Activated Palm Ash Chemical Engineering Journal 133.1, 195-203.
  • Hu, X.J., Wang, J.S., Liu, Y.G., Li, X., Zeng, G.M., Bao, Z.L. and Long, F. (2011). Adsorption of Chromium (VI) by Ethylenediamine-Modified Cross-Linked Magnetic Chitosan Resin: Isotherms, Kinetics and Thermodynamics Journal of Hazardous Materials 185.1, 306-314.
  • Iqbal, J., Wattoo, F.H., Wattoo, M.H.S., Malik, R., Tirmizi, S.A., Imran, M. and Ghangro, A.B. (2011). Adsorption of acid Yellow Dye on Flakes of Chitosan Prepared from Fishery Wastes Arabian Journal of Chemistry 4.4, 389-395.
  • Kaur, S., Rani, S., Mahajan, R.K., Asif, M. and Gupta, V.K. (2014). Synthesis and Adsorption Properties of Mesoporous Material for the Removal of Dye Safranin: Kinetics, Equilibrium, and Thermodynamics Journal of Industrial and Engineering Chemistry.
  • Kongsri, S., Janpradit, K., Buapa, K., Techawongstien, S. and Chanthai, S. (2013). Nanocrystalline Hydroxyapatite from Fish Scale Waste: Preparation, Characterization and Application for Selenium Adsorption in Aqueous Solution. Chemical Engineering Journal 215, 522-532.
  • Lorenc-Grabowska, E. and Gryglewicz, G. (2007). Adsorption Characteristics of Congo Red on Coal- Based Mesoporous Activated Carbon Dyes and Pigments 74.1, 34-40.
  • Mahmoodi, N.M., Hayati, B., Arami, M. and Lan, C. (2011). Adsorption of Textile Dyes on Pine Cone from Colored Wastewater: Kinetic, Equilibrium and Thermodynamic Studies. Desalination 268.1, 117-125.
  • Manjot, T. and Jin, B. (2012). Adsorption Characteristics, Isotherm, Kinetics, and Diffusion of Modified Natural Bentonite for Removing Diazo Dye. Chemical Engineering Journal 187, 79-88.
  • Moura, K.O., Vieira, E.F.S. and Cestari, A.R. (2012). The use of Solution microcalorimetry to Evaluate Chemically Modified Fish Scales as a Viable Adsorbent for Heavy Metals. Journal of Thermal Analysis and Calorimetry 107.3, 999-1005.
  • Moura, K.O., Vieira, E.F.S. and Cestari, A.R. (2012). Poly (Glutaraldehyde)‐Stabilized Fish Scale Fibrillar Collagen-Some Features of a New Material for Heavy Metal Sorption. Journal of Applied Polymer Science 124.4, 3208-3221.
  • Nadeem, R., Ansari, T.M. and Khalid, A.M. (2008). Fourier Transform Infrared Spectroscopic Characterization and Optimization of Pb (II) biosorption by Fish (Labeo rohita) Scales. Journal of Hazardous Materials 156.1, 64-73.
  • Öztürk, A. and Malkoc, E. (2014). Adsorptive Potential of Cationic Basic Yellow 2 (BY2) Dye onto Natural Untreated Clay (NUC) from Aqueous Phase: Mass Transfer Analysis, Kinetic and Equilibrium Profile. Applied Surface Science 299, 105-115.
  • Peng, X., Huang, D., Odoom-Wubah, T., Fu, D., Huang, J. and Qin, Q. (2014). Adsorption of Anionic and Cationic Dyes on Ferromagnetic Ordered Mesoporous Carbon from Aqueous Solution: Equilibrium, Thermodynamic and Kinetics. Journal of Colloid and Interface Science 430, 272- 282.
  • Semerjian, L. (2010). Equilibrium and Kinetics of Cadmium Adsorption from Aqueous Solutions using Untreated Pinushalepensis Sawdust. Journal of Hazardous Materials 173.1, 236-242.
  • Senthil, K.P., Sivaranjanee, R., Vinothini, U., Raghavi, M., Rajasekar, K. and Ramakrishnan, K. (2014). Adsorption of Dye Onto Raw and Surface Modified Tamarind Seeds: Isotherms, Process Design, Kinetics and Mechanism. Desalination and Water Treatment 52.13-15, 2620-2633.
  • Uddin, M.T., Islam, M.A., Mahmud, S. and Rukanuzzaman, M. (2009). Adsorptive Removal of Methylene Blue by Tea Waste. Journal of Hazardous Materials 164.1, 53-60.
  • Uzunoğlu, D. (2014). Levrek Balığı (Dicentrarchus labrax) Pulu ve Ticari Hidroksiapatit ile Acid Blue 121 Boyarmaddesinin Adsorbsiyonu. Mersin Üniversitesi, Fen Bilimleri Enstitüsü, Kimya Mühendisliği Ana Bilim Dalı, Yüksek Lisans Tezi.
  • Vieira, E.F., Cestari, A.R., Carvalho, W.A., Oliveira, C.D.S. and Chagas, R.A. (2012). The use of Freshwater Fish Scale of the Species Leporinus elongatus as Adsorbent for Anionic Dyes Journal of Thermal Analysis and Calorimetry 109.3, 1407-1412.
  • Villanueva-Espinosa, J.F., Hernandez-Esparza, M. and Ruiz-Trevino, F.A. (2001). Adsorptive Properties of Fish Scales of Oreochromis Niloticus (Mojarra Tilapia) for Metallic Ion Removal from Waste Water. Industrial and Engineering Chemistry Research 40.16, 3563-3569.
  • Zhang, R., Zhang, J., Zhang, X., Dou, C. and Han, R. (2014). Adsorption of Congo Red from Aqueous Solutions using Cationic Surfactant Modified Wheat Straw in Batch Mode: Kinetic and Equilibrium Study. Journal of the Taiwan Institute of Chemical Engineers 45.5, 2578-2583.
  • Zhang, Z., Moghaddam, L., O’Hara, I.M. and Doherty, W.O. (2011). Congo Red Adsorption by Ball- Milled Sugarcane Bagasse. Chemical Engineering Journal 178, 122-128.

ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU

Year 2015, Volume: 16 Issue: 2, 283 - 292, 11.11.2015
https://doi.org/10.18038/btd-a.25614

Abstract

Bu çalışmada, AB 324’ün levrek balığı pulu (LBP)’na adsorbsiyonu kesikli bir sistemde
araştırılmış; optimum ortam koşulları; başlangıç pH’sı 2.0, sıcaklık 25 oC, başlangıç AB 324 derişimi
200 mg/L ve adsorbent derişimi 1.0 g/L olarak belirlenmiştir. Çalışılan balık pulunun izoelektrik pH’sı
7.25 olarak belirlenmiş; izoelektrik pH değerinden daha düşük pH değerlerinde yüksek giderimler elde
edilmiştir. Adsorpsiyon dengesinin Langmuir izoterm modeline, kinetik verilerin ise yalancı ikinci
mertebe kinetik modeline çok iyi uyduğu saptanmıştır. AB 324’ün levrek balığı pulu (LBP)’na
adsorbsiyonunda tanecik içi ve dışı difüzyonun etkili olduğu sonucuna varılmıştır. Termodinamik
çalışmalar AB 324’ün LBP’na adsorbsiyonunun ekzotermik ve istemli olduğunu göstermiştir. LBP’nun
adsorpsiyon öncesi ve sonrası karakterizasyonu FTIR, SEM ve EDX analizleri ile gerçekleştirilmiştir.

References

  • Alok, M., Jhare, D. and Mittal, J. (2013). Adsorption of Hazardous Dye Eosin Yellow from Aqueous Solution onto Waste Material De-oiled Soya: Isotherm, Kinetics and Bulk Removal Journal of Molecular Liquids 179, 133-140.
  • Basu, A., Mustafiz, S., Islam, M.R., Bjorndalen, N., Rahaman, M.S. and Chaalal, O. (2006). A Comprehensive Approach for Modeling Sorption of Lead and Cobalt ions Through Fish Scales as an Adsorbent Chemical Engineering Communications 193.5, 580-605.
  • Boparai, H.K., Joseph, M. and O’Carroll, D.M. (2011). Kinetics and Thermodynamics of Cadmium ion Removal by Adsorption onto Nano Zerovalent Iron Particles Journal of Hazardous Materials 186.1, 458-465.
  • Chowdhury, S., Das Saha, P. and Ghosh, U. (2012). Fish (Labeo rohita) Scales as Potential Low-Cost Biosorbent for Removal of Malachite Green from Aqueous Solutions, Bioremediation Journal 16, 235-242.
  • Dong, Z., Wang, D., Liu, X., Pei, X., Chen, L. and Jin, J. (2014). Bio-inspired Surface-Functionalization of Graphene Oxide for The Adsorption Of Organic Dyes and Heavy Metal Ions with a Superhigh Capacity Journal of Materials Chemistry A 2.14, 5034-5040.
  • Du, L.N., Wang, B., Li, G., Wang, S., Crowley, D.E. and Zhao, Y.H. (2012). Biosorption of the Metal- complex Dye Acid Black 172 by Live and Heat-Treated Biomass of Pseudomonas Strain DY1: Kinetics and Sorption Mechanisms Journal of Hazardous Materials 205, 47-54.
  • El-Bindary, A.A., El-Sonbati, A.Z., Al-Sarawy, A.A., Mohamed, K.S. and Farid, M.A. (2014). Adsorption and Thermodynamic Studies of Hazardous Azocoumarin Dye from an Aqueous Solution onto Low Cost Rice Straw Based Carbons Journal of Molecular Liquids 199, 71-78.
  • Gupta, V.K., Bhushan, R., Nayak, A., Singh, P. and Bhushan, B. (2014). Biosorption and Reuse Potential of a Blue Green Alga for the Removal of Hazardous Reactive Dyes from Aqueous Solutions Bioremediation Journal 18.3, 179-191.
  • Hameed, B.H., Ahmad, A.A. and Aziz, N. (2007). Isotherms, Kinetics and Thermodynamics of Acid Dye Adsorption on Activated Palm Ash Chemical Engineering Journal 133.1, 195-203.
  • Hu, X.J., Wang, J.S., Liu, Y.G., Li, X., Zeng, G.M., Bao, Z.L. and Long, F. (2011). Adsorption of Chromium (VI) by Ethylenediamine-Modified Cross-Linked Magnetic Chitosan Resin: Isotherms, Kinetics and Thermodynamics Journal of Hazardous Materials 185.1, 306-314.
  • Iqbal, J., Wattoo, F.H., Wattoo, M.H.S., Malik, R., Tirmizi, S.A., Imran, M. and Ghangro, A.B. (2011). Adsorption of acid Yellow Dye on Flakes of Chitosan Prepared from Fishery Wastes Arabian Journal of Chemistry 4.4, 389-395.
  • Kaur, S., Rani, S., Mahajan, R.K., Asif, M. and Gupta, V.K. (2014). Synthesis and Adsorption Properties of Mesoporous Material for the Removal of Dye Safranin: Kinetics, Equilibrium, and Thermodynamics Journal of Industrial and Engineering Chemistry.
  • Kongsri, S., Janpradit, K., Buapa, K., Techawongstien, S. and Chanthai, S. (2013). Nanocrystalline Hydroxyapatite from Fish Scale Waste: Preparation, Characterization and Application for Selenium Adsorption in Aqueous Solution. Chemical Engineering Journal 215, 522-532.
  • Lorenc-Grabowska, E. and Gryglewicz, G. (2007). Adsorption Characteristics of Congo Red on Coal- Based Mesoporous Activated Carbon Dyes and Pigments 74.1, 34-40.
  • Mahmoodi, N.M., Hayati, B., Arami, M. and Lan, C. (2011). Adsorption of Textile Dyes on Pine Cone from Colored Wastewater: Kinetic, Equilibrium and Thermodynamic Studies. Desalination 268.1, 117-125.
  • Manjot, T. and Jin, B. (2012). Adsorption Characteristics, Isotherm, Kinetics, and Diffusion of Modified Natural Bentonite for Removing Diazo Dye. Chemical Engineering Journal 187, 79-88.
  • Moura, K.O., Vieira, E.F.S. and Cestari, A.R. (2012). The use of Solution microcalorimetry to Evaluate Chemically Modified Fish Scales as a Viable Adsorbent for Heavy Metals. Journal of Thermal Analysis and Calorimetry 107.3, 999-1005.
  • Moura, K.O., Vieira, E.F.S. and Cestari, A.R. (2012). Poly (Glutaraldehyde)‐Stabilized Fish Scale Fibrillar Collagen-Some Features of a New Material for Heavy Metal Sorption. Journal of Applied Polymer Science 124.4, 3208-3221.
  • Nadeem, R., Ansari, T.M. and Khalid, A.M. (2008). Fourier Transform Infrared Spectroscopic Characterization and Optimization of Pb (II) biosorption by Fish (Labeo rohita) Scales. Journal of Hazardous Materials 156.1, 64-73.
  • Öztürk, A. and Malkoc, E. (2014). Adsorptive Potential of Cationic Basic Yellow 2 (BY2) Dye onto Natural Untreated Clay (NUC) from Aqueous Phase: Mass Transfer Analysis, Kinetic and Equilibrium Profile. Applied Surface Science 299, 105-115.
  • Peng, X., Huang, D., Odoom-Wubah, T., Fu, D., Huang, J. and Qin, Q. (2014). Adsorption of Anionic and Cationic Dyes on Ferromagnetic Ordered Mesoporous Carbon from Aqueous Solution: Equilibrium, Thermodynamic and Kinetics. Journal of Colloid and Interface Science 430, 272- 282.
  • Semerjian, L. (2010). Equilibrium and Kinetics of Cadmium Adsorption from Aqueous Solutions using Untreated Pinushalepensis Sawdust. Journal of Hazardous Materials 173.1, 236-242.
  • Senthil, K.P., Sivaranjanee, R., Vinothini, U., Raghavi, M., Rajasekar, K. and Ramakrishnan, K. (2014). Adsorption of Dye Onto Raw and Surface Modified Tamarind Seeds: Isotherms, Process Design, Kinetics and Mechanism. Desalination and Water Treatment 52.13-15, 2620-2633.
  • Uddin, M.T., Islam, M.A., Mahmud, S. and Rukanuzzaman, M. (2009). Adsorptive Removal of Methylene Blue by Tea Waste. Journal of Hazardous Materials 164.1, 53-60.
  • Uzunoğlu, D. (2014). Levrek Balığı (Dicentrarchus labrax) Pulu ve Ticari Hidroksiapatit ile Acid Blue 121 Boyarmaddesinin Adsorbsiyonu. Mersin Üniversitesi, Fen Bilimleri Enstitüsü, Kimya Mühendisliği Ana Bilim Dalı, Yüksek Lisans Tezi.
  • Vieira, E.F., Cestari, A.R., Carvalho, W.A., Oliveira, C.D.S. and Chagas, R.A. (2012). The use of Freshwater Fish Scale of the Species Leporinus elongatus as Adsorbent for Anionic Dyes Journal of Thermal Analysis and Calorimetry 109.3, 1407-1412.
  • Villanueva-Espinosa, J.F., Hernandez-Esparza, M. and Ruiz-Trevino, F.A. (2001). Adsorptive Properties of Fish Scales of Oreochromis Niloticus (Mojarra Tilapia) for Metallic Ion Removal from Waste Water. Industrial and Engineering Chemistry Research 40.16, 3563-3569.
  • Zhang, R., Zhang, J., Zhang, X., Dou, C. and Han, R. (2014). Adsorption of Congo Red from Aqueous Solutions using Cationic Surfactant Modified Wheat Straw in Batch Mode: Kinetic and Equilibrium Study. Journal of the Taiwan Institute of Chemical Engineers 45.5, 2578-2583.
  • Zhang, Z., Moghaddam, L., O’Hara, I.M. and Doherty, W.O. (2011). Congo Red Adsorption by Ball- Milled Sugarcane Bagasse. Chemical Engineering Journal 178, 122-128.
There are 29 citations in total.

Details

Primary Language Turkish
Journal Section Articles
Authors

Deniz Uzunoğlu

Ayla Özer This is me

Ercan Tuncay This is me

Ercan Tuncay This is me

Abdullah Küntaş This is me

Publication Date November 11, 2015
Published in Issue Year 2015 Volume: 16 Issue: 2

Cite

APA Uzunoğlu, D., Özer, A., Tuncay, E., Tuncay, E., et al. (2015). ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 16(2), 283-292. https://doi.org/10.18038/btd-a.25614
AMA Uzunoğlu D, Özer A, Tuncay E, Tuncay E, Küntaş A. ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU. AUJST-A. November 2015;16(2):283-292. doi:10.18038/btd-a.25614
Chicago Uzunoğlu, Deniz, Ayla Özer, Ercan Tuncay, Ercan Tuncay, and Abdullah Küntaş. “ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16, no. 2 (November 2015): 283-92. https://doi.org/10.18038/btd-a.25614.
EndNote Uzunoğlu D, Özer A, Tuncay E, Tuncay E, Küntaş A (November 1, 2015) ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16 2 283–292.
IEEE D. Uzunoğlu, A. Özer, E. Tuncay, E. Tuncay, and A. Küntaş, “ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU”, AUJST-A, vol. 16, no. 2, pp. 283–292, 2015, doi: 10.18038/btd-a.25614.
ISNAD Uzunoğlu, Deniz et al. “ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16/2 (November 2015), 283-292. https://doi.org/10.18038/btd-a.25614.
JAMA Uzunoğlu D, Özer A, Tuncay E, Tuncay E, Küntaş A. ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU. AUJST-A. 2015;16:283–292.
MLA Uzunoğlu, Deniz et al. “ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 16, no. 2, 2015, pp. 283-92, doi:10.18038/btd-a.25614.
Vancouver Uzunoğlu D, Özer A, Tuncay E, Tuncay E, Küntaş A. ACİD BLUE 324 BOYARMADDESİNİN LEVREK BALIĞI PULUNA ADSORBSİYONU. AUJST-A. 2015;16(2):283-92.