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Year 2015, Volume: 16 Issue: 2, 211 - 217, 12.11.2015
https://doi.org/10.18038/btd-a.11729

Abstract

In the present study, thermal degradation process of tobacco farm waste was examined by means of a thermogravimetric analysis (TGA) and differential thermogravimetric analysis (DTA) under nitrogen atmosphere at different heating rates of 5, 10, 15 and 20 C /min from 20 C to 1000 C. Using TGA data, the kinetic parameters, such as activation energy, pre-exponential factor and reaction order were determined by applying the Coats-Redfern (CR) method. In this study, by means of Thermogravimetric Analyzer coupled with Fourier Transform Infrared Spectrometer and Mass Spectrometer (TGA-FTIR-MS), gases evolved during the degradation of the sample were analyzed sensitively and at real time. Furthermore, the main gas products released during the pyrolysis of tobacco farm waste were determined as methane, amonia, water, hydrogen cyanide and formaldehyde, carbondioxide and propanal

References

  • Cordoso, C.R., Miranda, M.R., Santos, K.G. and Ataide, C.H. (2011). Determination of Kinetic Parameters and Analytical Pyrolysis of Tobacco Waste and Sorghum Bagasse, Journal of Analytical and Applied Pyrolysis 92(2), 392-400.
  • Damartzis, Th., Vamvuka, D., Sfakiotakis, S. and Zabaniotou, A. (2011). Thermal Degradation Studies and Kinetic Modeling of Cardoon (Cynara cardunculus) Pyrolysis using Thermogravimetric Analysis (TGA), Bioresource Technology 102(10), 6230- 6238.
  • Gao, W., Chen, K., Xiang, Z., Yang, F., Zeng, J., Li, J., Yang, R., Rao and G., Tao, H.(2013). Kinetic Study on Pyrolysis of Tobacco Residues from The Cigarette Industry, Industrial Crops and Products 44, 152-157.
  • Ounas, A., Aboulkas, A., Bacaoui, A. and Yaacoubi, A. (2011). Pyrolysis of Olive Residue and Sugar Cane Bagasse: Non-İsothermal Thermogravimetric Kinetic Analysis, Bioresource Technology 102(24), 11234-11238.
  • Singh, S., Wu, C. and Williams, P.T. (2012). Pyrolysis of Waste Materials using TGA-MS and TGAFTIR as Complementary Characterisation Techniques, Journal of Analytical and Applied Pyrolysis 94, 99-107.
  • Yang, Y., Li, T., Jin, S., Lin, Y. and Yang, H. (2011). Catalytic Pyrolysis of Tobacco Rob: Kinetic Study and Fuel Gas Produceed, Bioresource Technology 102, 11027-11033.
  • Zhao, G.B., Qian, J. and Qin, Y. (2010). TG-FTIR Characterization of Pyrolysis of Waste Mixtures of Paint and Tar Slag, Journal of Hazardous Materials 175(1-3), 754–761.
  • Zhou, L., Luo, T. and Huang, Q. (2009). Co-Pyrolysis Characteristics and Kinetics of Coal and Plastic Blends, Energy Conversion and Managements 50(3), 705-710.

TÜTÜN TARLA ATIĞININ TGA-FTIR-MS İLE TERMAL DAVRANIŞININ BELİRLENMESİ

Year 2015, Volume: 16 Issue: 2, 211 - 217, 12.11.2015
https://doi.org/10.18038/btd-a.11729

Abstract

Bu çalışmada, tütün tarla atığı için termal bozundurma işlemi termogravimetrik analiz (TGA) cihazı ile 20 °C başlangıç sıcaklığından 1000°C’ye kadar 5, 10, 15 ve 20 °C /dk ısıtma hızlarında ve azot atmosferi altında gerçekleştirilmiştir. TGA’dan elde edilen eğriler ve veriler yardımıyla, tütün tarla atığı için Coats-Redfern yöntemi kullanılarak, aktivasyon enerjisi, reaksiyon mertebesi ve frekans faktörü belirlenmiştir. Yapılan çalışmada, termogravimetrik analiz cihazıyla birleştirilmiş Fourier Transform Infrared Spektroskopisi ve Kütle Spektroskopisi (TGA-FTIR-MS) kullanılarak, hammaddenin bozunması sırasında açığa çıkan gazlar tespit edilmiştir. Tütün tarla atığının pirolizi sırasında açığa çıkan başlıca ürünlerin, metan, amonyak, su, hidrojen siyanür, formaldehit, karbon dioksit ve propanal olduğu belirlenmiştir.

References

  • Cordoso, C.R., Miranda, M.R., Santos, K.G. and Ataide, C.H. (2011). Determination of Kinetic Parameters and Analytical Pyrolysis of Tobacco Waste and Sorghum Bagasse, Journal of Analytical and Applied Pyrolysis 92(2), 392-400.
  • Damartzis, Th., Vamvuka, D., Sfakiotakis, S. and Zabaniotou, A. (2011). Thermal Degradation Studies and Kinetic Modeling of Cardoon (Cynara cardunculus) Pyrolysis using Thermogravimetric Analysis (TGA), Bioresource Technology 102(10), 6230- 6238.
  • Gao, W., Chen, K., Xiang, Z., Yang, F., Zeng, J., Li, J., Yang, R., Rao and G., Tao, H.(2013). Kinetic Study on Pyrolysis of Tobacco Residues from The Cigarette Industry, Industrial Crops and Products 44, 152-157.
  • Ounas, A., Aboulkas, A., Bacaoui, A. and Yaacoubi, A. (2011). Pyrolysis of Olive Residue and Sugar Cane Bagasse: Non-İsothermal Thermogravimetric Kinetic Analysis, Bioresource Technology 102(24), 11234-11238.
  • Singh, S., Wu, C. and Williams, P.T. (2012). Pyrolysis of Waste Materials using TGA-MS and TGAFTIR as Complementary Characterisation Techniques, Journal of Analytical and Applied Pyrolysis 94, 99-107.
  • Yang, Y., Li, T., Jin, S., Lin, Y. and Yang, H. (2011). Catalytic Pyrolysis of Tobacco Rob: Kinetic Study and Fuel Gas Produceed, Bioresource Technology 102, 11027-11033.
  • Zhao, G.B., Qian, J. and Qin, Y. (2010). TG-FTIR Characterization of Pyrolysis of Waste Mixtures of Paint and Tar Slag, Journal of Hazardous Materials 175(1-3), 754–761.
  • Zhou, L., Luo, T. and Huang, Q. (2009). Co-Pyrolysis Characteristics and Kinetics of Coal and Plastic Blends, Energy Conversion and Managements 50(3), 705-710.
There are 8 citations in total.

Details

Primary Language Turkish
Journal Section Articles
Authors

Sevgi Polat

Ayşe Pütün

Publication Date November 12, 2015
Published in Issue Year 2015 Volume: 16 Issue: 2

Cite

APA Polat, S., & Pütün, A. (2015). TÜTÜN TARLA ATIĞININ TGA-FTIR-MS İLE TERMAL DAVRANIŞININ BELİRLENMESİ. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 16(2), 211-217. https://doi.org/10.18038/btd-a.11729
AMA Polat S, Pütün A. TÜTÜN TARLA ATIĞININ TGA-FTIR-MS İLE TERMAL DAVRANIŞININ BELİRLENMESİ. AUJST-A. November 2015;16(2):211-217. doi:10.18038/btd-a.11729
Chicago Polat, Sevgi, and Ayşe Pütün. “TÜTÜN TARLA ATIĞININ TGA-FTIR-MS İLE TERMAL DAVRANIŞININ BELİRLENMESİ”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16, no. 2 (November 2015): 211-17. https://doi.org/10.18038/btd-a.11729.
EndNote Polat S, Pütün A (November 1, 2015) TÜTÜN TARLA ATIĞININ TGA-FTIR-MS İLE TERMAL DAVRANIŞININ BELİRLENMESİ. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16 2 211–217.
IEEE S. Polat and A. Pütün, “TÜTÜN TARLA ATIĞININ TGA-FTIR-MS İLE TERMAL DAVRANIŞININ BELİRLENMESİ”, AUJST-A, vol. 16, no. 2, pp. 211–217, 2015, doi: 10.18038/btd-a.11729.
ISNAD Polat, Sevgi - Pütün, Ayşe. “TÜTÜN TARLA ATIĞININ TGA-FTIR-MS İLE TERMAL DAVRANIŞININ BELİRLENMESİ”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16/2 (November 2015), 211-217. https://doi.org/10.18038/btd-a.11729.
JAMA Polat S, Pütün A. TÜTÜN TARLA ATIĞININ TGA-FTIR-MS İLE TERMAL DAVRANIŞININ BELİRLENMESİ. AUJST-A. 2015;16:211–217.
MLA Polat, Sevgi and Ayşe Pütün. “TÜTÜN TARLA ATIĞININ TGA-FTIR-MS İLE TERMAL DAVRANIŞININ BELİRLENMESİ”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 16, no. 2, 2015, pp. 211-7, doi:10.18038/btd-a.11729.
Vancouver Polat S, Pütün A. TÜTÜN TARLA ATIĞININ TGA-FTIR-MS İLE TERMAL DAVRANIŞININ BELİRLENMESİ. AUJST-A. 2015;16(2):211-7.