MAYA ENDÜSTRİSİ ATIKSUYUNUN ULTRASES İLE RENK GİDERİMİNDE ÇEŞİTLİ TUZLARIN ETKİSİ
Year 2015,
Volume: 16 Issue: 2, 179 - 188, 12.11.2015
Serap Fındık
,
Didem Ildırar
Abstract
Ultrases prosesi son yıllarda önem kazanan kimyasal oksidasyon yöntemidir. Uygun sıcaklık ve basınçta sucul ortama verilen ses dalgaları ile kavitasyon oluşmakta, suyun fiziksel ve kimyasal bileşimini değiştirerek atıksuda bulunan organik maddelerin daha az zararlı bileşiklere dönüşmesini sağlamaktadır. Bu çalışmada Orta Karadeniz bölgesinde bulunan bir maya fabrikasının biyolojik arıtma tesisi girişinden temin edilen atıksu kullanılmıştır. Ultrases ile maya endüstrisi atıksuyunda renk ve kimyasal oksijen ihtiyacı (KOİ) giderimi araştırılmıştır. Ultrases kaynağı olarak 20kHz frekansa sahip ultrasonik homojenizatör kullanılmıştır. Ultrases ile 60dk reaksiyon sonunda %21,7 oranında renk giderimi sağlanmıştır. Çalışmada Na2CO3, CaCO3, NaCl, CaCl2 gibi tuzların ilavesinin ultrasonik bozunma üzerine etkisi incelenmiştir.
References
- Anju, S. G., Yesodharan, S. and Yesodharan, E. P. (2012). Zinc Oxide Mediated Sonophotocatalytic Degradation of Phenol, Chemical Engineering Journal 189-190, 84-93.
- Coca, M., Pena, M. and Gonzalez, G. (2005). Variables Affecting Efficiency of Molasses Fermentation Wastewater Ozonation, Chemosphere 60, 1408-1415.
- Çatalkaya, E. Ç. and Şengül, F. (2006). Application of Box-Wilson Experimental Design Method for the Photodegradation of Bakery’s Yeast İndustry with UV/H2O2 and UV/H2O2/Fe(II) Process, Journal of Hazardous Materials 128(2-3), 201- 207.
- Drijvers, D., Langenhove, H.V., Kim, L.N. and Bray, L. (1999). Sonolysis of an Aqueous Mixture of Trichloroethylene and Chlorobenzene, Ultrasonics Sonochemistry 6, 115-121.
- Dükkancı, M. and Gündüz, G., (2013), Sonolytic Degradation of Butyric Acid in Aqueous Solutions, Journal of Environmental Management 129, 564-568.
- Fındık, S. and Gunduz ,G. (2007). Sonolytic Degradation of Acetic Acid in Aqueous Solutions, Ultrason. Sonochem. 14(2), 241-245.
- Gengec, E., Kobya, M., Demirbas, E., Akyol, A. and Oktor, K. (2012). Optimization of Baker’s Yeast Wastewater using Response Surface Methology by Electrocoagulation, Desalination 286, 200- 209.
- Gogate, P. R., Pandit, A. B., Wilhemn, A. and Ratsimba, B. (2006). Destruction of Formic Acid using High Cup Horn Reactor, Water Research 40, 1697-1705.
- Gogate, P.R. and Katekhaye, S.N. (2012). A Comparison of the Degree of Intensification Due to the use of Additives in Ultrasonic Horn and Ultrasonic Bath, Chemical Engineering and Processing 61, 23-29.
- Gonze, E., Fourel, L., Gonthier, Y., Boldo, P. and Bernis, A. (1999). Wastewater Pretreatment with Ultrasonic Irradiation to Reduce Toxicity, Chemical Engineering Journal 73, 93-100.
- Guo Z., Feng, R., Li, J. and Zheng, Y. ( 2008). Degradation of 2,4 Dinitrophenol by Combining Sonolysis and Different Additives, J. Hazard Mater. 158(1), 164-169.
- Guzman-Duque, F., Petrier, C., Pulgarin, C. and Penuela, G. (2011). Effects of Sonochemical Parameters and Inorganic Ions During the Sonochemical Degradation of Crystal Violet in Water, Ultrasonics Sonochemistry, 18, 440-446.
- Joseph, C. G., Puma, G. L., Bono, A. and Krishnaiah, D. (2009). Sonophotocatalysis in Advanced Oxidation Process: A Short Review, Ultrasonics Sonochemistry 16, 583-589.
- Kobya, M. and Delipınar, S. (2008). Treatment of the Baker’s Yeast Wastewater by Electrocoagulation, Journal of Hazardous Materials 154, 1133-1140.
- Liang, Z., Wang, Y., Zhou, Y., Liu, H. and Wu, Z. (2009a). Variables Affecting Melanoidins Removal from Molasses Wastewater by Coagulation/Flocculation, Separation and Purification Technology 68, 382-389.
- Liang, Z., Wang, Y., Zhou, Y., Liu, H. and Wu, Z. (2009b).Coagulation Removal of Melanoidins from Biologically Treated Molasses Wastewater using Ferric Chloride, Chemical Engineering Journal 152, 88-94.
- Mahamuni, N. N. and Pandit, A. B. (2006). Effect of Additives on Ultrasonic Degradation of Phenol, Ultrasonics Sonochemistry 13, 165-174.
- Merouani, S., Hamdaoui, O., Saoudi, F. and Chiha, M. (2010a). Sonochemical Degradation of Rhodamine B in Aqueous Phase: Effects of Additives, Chemical Engineering Journal 158, 550- 557.
- Merouani, S., Hamdaoui, O., Saoudi, F., Chiha, M. and Petrier, C. (2010b). Influence of Bicarbonate and Carbonate Ions on Sonochemical Degradation of Rhodamine B in Aqueous Phase, Journal of Hazardous Materials 175, 593-599.
- Moumeni, O. and Hamdaoui, O. (2012). Intensification of Sonochemical Degradation of Malachite Green by Bromide Ions, Ultasonics Sonochemistry 19, 404-409.
- Pala, E. and Erden, G. (2005). Decolorization of a Baker’s Yeast Industry Effluent by Fenton Oxidation, Journal of Hazardous Materials B127, 141-148.
- Pang, Y. L., Abdullah, A. Z. and Bhatia, S. (2011). Review on Sonochemical Methods in the Presence of Catalysts and Chemical Additives for Treatment of Organic Pollutants in Wastewater, Desalination 227, 1-14 .
- Pena, M., Coca, M., Gonzalez, R. R. and Garcia, M. T. (2003). Chemical Oxidation of Wastewater from Molasses Fermentation with Ozone, Chemosphere 51, 893-900.
- Sangave, P. C. and Pandit, A. B. (2004). Ultrasound Pre-treatment for Enhanced Biodegradability of the Distillery Wastewater, Ultrasonic Sonochemistry 11, 197-203.
- Sangave, P. C. and Pandit, A. B. (2006). Ultrasound and Enzyme Assisted Biodegradation of Distillery Wastewater, Journal of Enviromental Management 80, 36-46.
- Serpone, N. and Colarusso, P. (1994). Sonochemistry I. Effects of Ultrasounds on Heterogeneous Chemical Reactions – a useful Tool to Generate Radicals and to Examine Reaction Mechanisms, Research on Chemical Intermediates 20(6), 635-679.
- Seymour, J. and Gupta R.B. (1997). Oxidation of Aqueous Pollutants using Ultrasound: Salt Induced Enhancement, Ind Eng. Che. Res. 36, 3453-3457.
- Shimizu, N., Ogino, C., Dadjour, M. F. and Murata, T. (2007). Sonocatalytic Degradation of Methylene Blue with TiO2 Pellets in Water, Ultrasonics Sonochemistry 14 ,184–190.
- Wang, X., Yao, Z., Wang, J., Guo, W. and Li, G. (2008). Degradation of Reactive Brilliant Red in Aqueous Solution by Ultrasonic Cavitation, Ultrasonics Sonochemistry 15, 43-48.
- Xie, W., Qin, Y., Liang, D. and Song, D., He, D. (2011). Degradation of m-xylene Solution using Ultrasonic Irradiation, Ultrasonics Sonochemistry 18, 1077-1081.
- Yılmaz, E.,(2014). Maya Endüstrisi Atıksuyunun Ses Ötesi Dalgalarla Arıtılması, Yüksek Lisans Tezi, Çorum, Türkiye: Hitit Üniversitesi.
- Zeng, Y. F., Liu, Z. L. and Qin, Z. Z. (2009). Decolorization of Molasses Fermentation Wastewater by SnO2-catalyzed Ozonation, Journal of Hazardous Materials 162, 682-687.
- Zhou, Y., Liang, Z. and Wang, Y. (2008). Decolorization and COD Removal of Secondary Yeast Wastewater Effluents by Coagulation using Aluminum Sulfate, Desalination 225, 301-311.
MAYA ENDÜSTRİSİ ATIKSUYUNUN ULTRASES İLE RENK GİDERİMİNDE ÇEŞİTLİ TUZLARIN ETKİSİ
Year 2015,
Volume: 16 Issue: 2, 179 - 188, 12.11.2015
Serap Fındık
,
Didem Ildırar
Abstract
Ultrases prosesi son yıllarda önem kazanan kimyasal oksidasyon yöntemidir. Uygun sıcaklık ve basınçta sucul ortama verilen ses dalgaları ile kavitasyon oluşmakta, suyun fiziksel ve kimyasal bileşimini değiştirerek atıksuda bulunan organik maddelerin daha az zararlı bileşiklere dönüşmesini sağlamaktadır. Bu çalışmada Orta Karadeniz bölgesinde bulunan bir maya fabrikasının biyolojik arıtma tesisi girişinden temin edilen atıksu kullanılmıştır. Ultrases ile maya endüstrisi atıksuyunda renk ve kimyasal oksijen ihtiyacı (KOİ) giderimi araştırılmıştır. Ultrases kaynağı olarak 20kHz frekansa sahip ultrasonik homojenizatör kullanılmıştır. Ultrases ile 60dk reaksiyon sonunda %21,7 oranında renk giderimi sağlanmıştır. Çalışmada Na2CO3, CaCO3, NaCl, CaCl2 gibi tuzların ilavesinin ultrasonik bozunma üzerine etkisi incelenmiştir.
References
- Anju, S. G., Yesodharan, S. and Yesodharan, E. P. (2012). Zinc Oxide Mediated Sonophotocatalytic Degradation of Phenol, Chemical Engineering Journal 189-190, 84-93.
- Coca, M., Pena, M. and Gonzalez, G. (2005). Variables Affecting Efficiency of Molasses Fermentation Wastewater Ozonation, Chemosphere 60, 1408-1415.
- Çatalkaya, E. Ç. and Şengül, F. (2006). Application of Box-Wilson Experimental Design Method for the Photodegradation of Bakery’s Yeast İndustry with UV/H2O2 and UV/H2O2/Fe(II) Process, Journal of Hazardous Materials 128(2-3), 201- 207.
- Drijvers, D., Langenhove, H.V., Kim, L.N. and Bray, L. (1999). Sonolysis of an Aqueous Mixture of Trichloroethylene and Chlorobenzene, Ultrasonics Sonochemistry 6, 115-121.
- Dükkancı, M. and Gündüz, G., (2013), Sonolytic Degradation of Butyric Acid in Aqueous Solutions, Journal of Environmental Management 129, 564-568.
- Fındık, S. and Gunduz ,G. (2007). Sonolytic Degradation of Acetic Acid in Aqueous Solutions, Ultrason. Sonochem. 14(2), 241-245.
- Gengec, E., Kobya, M., Demirbas, E., Akyol, A. and Oktor, K. (2012). Optimization of Baker’s Yeast Wastewater using Response Surface Methology by Electrocoagulation, Desalination 286, 200- 209.
- Gogate, P. R., Pandit, A. B., Wilhemn, A. and Ratsimba, B. (2006). Destruction of Formic Acid using High Cup Horn Reactor, Water Research 40, 1697-1705.
- Gogate, P.R. and Katekhaye, S.N. (2012). A Comparison of the Degree of Intensification Due to the use of Additives in Ultrasonic Horn and Ultrasonic Bath, Chemical Engineering and Processing 61, 23-29.
- Gonze, E., Fourel, L., Gonthier, Y., Boldo, P. and Bernis, A. (1999). Wastewater Pretreatment with Ultrasonic Irradiation to Reduce Toxicity, Chemical Engineering Journal 73, 93-100.
- Guo Z., Feng, R., Li, J. and Zheng, Y. ( 2008). Degradation of 2,4 Dinitrophenol by Combining Sonolysis and Different Additives, J. Hazard Mater. 158(1), 164-169.
- Guzman-Duque, F., Petrier, C., Pulgarin, C. and Penuela, G. (2011). Effects of Sonochemical Parameters and Inorganic Ions During the Sonochemical Degradation of Crystal Violet in Water, Ultrasonics Sonochemistry, 18, 440-446.
- Joseph, C. G., Puma, G. L., Bono, A. and Krishnaiah, D. (2009). Sonophotocatalysis in Advanced Oxidation Process: A Short Review, Ultrasonics Sonochemistry 16, 583-589.
- Kobya, M. and Delipınar, S. (2008). Treatment of the Baker’s Yeast Wastewater by Electrocoagulation, Journal of Hazardous Materials 154, 1133-1140.
- Liang, Z., Wang, Y., Zhou, Y., Liu, H. and Wu, Z. (2009a). Variables Affecting Melanoidins Removal from Molasses Wastewater by Coagulation/Flocculation, Separation and Purification Technology 68, 382-389.
- Liang, Z., Wang, Y., Zhou, Y., Liu, H. and Wu, Z. (2009b).Coagulation Removal of Melanoidins from Biologically Treated Molasses Wastewater using Ferric Chloride, Chemical Engineering Journal 152, 88-94.
- Mahamuni, N. N. and Pandit, A. B. (2006). Effect of Additives on Ultrasonic Degradation of Phenol, Ultrasonics Sonochemistry 13, 165-174.
- Merouani, S., Hamdaoui, O., Saoudi, F. and Chiha, M. (2010a). Sonochemical Degradation of Rhodamine B in Aqueous Phase: Effects of Additives, Chemical Engineering Journal 158, 550- 557.
- Merouani, S., Hamdaoui, O., Saoudi, F., Chiha, M. and Petrier, C. (2010b). Influence of Bicarbonate and Carbonate Ions on Sonochemical Degradation of Rhodamine B in Aqueous Phase, Journal of Hazardous Materials 175, 593-599.
- Moumeni, O. and Hamdaoui, O. (2012). Intensification of Sonochemical Degradation of Malachite Green by Bromide Ions, Ultasonics Sonochemistry 19, 404-409.
- Pala, E. and Erden, G. (2005). Decolorization of a Baker’s Yeast Industry Effluent by Fenton Oxidation, Journal of Hazardous Materials B127, 141-148.
- Pang, Y. L., Abdullah, A. Z. and Bhatia, S. (2011). Review on Sonochemical Methods in the Presence of Catalysts and Chemical Additives for Treatment of Organic Pollutants in Wastewater, Desalination 227, 1-14 .
- Pena, M., Coca, M., Gonzalez, R. R. and Garcia, M. T. (2003). Chemical Oxidation of Wastewater from Molasses Fermentation with Ozone, Chemosphere 51, 893-900.
- Sangave, P. C. and Pandit, A. B. (2004). Ultrasound Pre-treatment for Enhanced Biodegradability of the Distillery Wastewater, Ultrasonic Sonochemistry 11, 197-203.
- Sangave, P. C. and Pandit, A. B. (2006). Ultrasound and Enzyme Assisted Biodegradation of Distillery Wastewater, Journal of Enviromental Management 80, 36-46.
- Serpone, N. and Colarusso, P. (1994). Sonochemistry I. Effects of Ultrasounds on Heterogeneous Chemical Reactions – a useful Tool to Generate Radicals and to Examine Reaction Mechanisms, Research on Chemical Intermediates 20(6), 635-679.
- Seymour, J. and Gupta R.B. (1997). Oxidation of Aqueous Pollutants using Ultrasound: Salt Induced Enhancement, Ind Eng. Che. Res. 36, 3453-3457.
- Shimizu, N., Ogino, C., Dadjour, M. F. and Murata, T. (2007). Sonocatalytic Degradation of Methylene Blue with TiO2 Pellets in Water, Ultrasonics Sonochemistry 14 ,184–190.
- Wang, X., Yao, Z., Wang, J., Guo, W. and Li, G. (2008). Degradation of Reactive Brilliant Red in Aqueous Solution by Ultrasonic Cavitation, Ultrasonics Sonochemistry 15, 43-48.
- Xie, W., Qin, Y., Liang, D. and Song, D., He, D. (2011). Degradation of m-xylene Solution using Ultrasonic Irradiation, Ultrasonics Sonochemistry 18, 1077-1081.
- Yılmaz, E.,(2014). Maya Endüstrisi Atıksuyunun Ses Ötesi Dalgalarla Arıtılması, Yüksek Lisans Tezi, Çorum, Türkiye: Hitit Üniversitesi.
- Zeng, Y. F., Liu, Z. L. and Qin, Z. Z. (2009). Decolorization of Molasses Fermentation Wastewater by SnO2-catalyzed Ozonation, Journal of Hazardous Materials 162, 682-687.
- Zhou, Y., Liang, Z. and Wang, Y. (2008). Decolorization and COD Removal of Secondary Yeast Wastewater Effluents by Coagulation using Aluminum Sulfate, Desalination 225, 301-311.