Tuning Optical and Electrical Properties of Ultra-Fast Prepared Nanoflower Mg:ZnO Films by MWCNTs Coating

Year 2022, Volume: 6 Issue: 2, 83 - 90, 30.09.2022

İrmak Karaduman Er , Fatma Sarf , Emin Yakar

https://doi.org/10.30516/bilgesci.1060177

Abstract

Mg doped ZnO films were coated multi-walled carbon nanotubes (MWCNTs) via fast chemical bath onto ZnO seed layers. XRD analysis showed preferential orientation shift from high-energy (002) peak to low-energy (101) peak with MWCNTs coating. Average crystalline size of Mg doped ZnO samples are 15 nm. diameter and 50% percent reduction has been observed with MWCNTs coating. SEM images reveals the presence of high accumulative nanoflower forms on Mg:ZnO surfaces and homogenous net-shaped coating has been achieved by MWCNTs inclusion so active surface area may increase. No major difference of optical absorption edge is detected in both films however MWCNTs coating cause an increase direct band gap. Due to Burstein-Moss effect, Mg:ZnO and Mg:ZnO/MWCNTs films with using Tauc plot calculated band gap values are 3.04 eV and 3.34 eV, respectively. From FTIR spectra, no obvious change is not detected the functional groups of the samples. Electrical studies show that MWCNTs decrease the resistance and the resistance of films at room temperature were calculated 29.85 and 8.53 k for Mg:ZnO and Mg:ZnO/MWCNTs films , respectively.

Keywords

chemical bath deposition, ZnO, MWCNTs, electrical, optical

References

• Altun, B., Karaduman Er, I., Çağırtekin, A.O., Ajjaq A., Sarf, F., Acar, S. (2021). Effect of Cd dopant on structural, optical and CO2 gas sensing properties of ZnO thin film sensors fabricated by chemical bath deposition method. Appl. Phys. A, 127, 687.
• Asikuzun, E., Donmez, A., Arda, L., Cakiroglu, O., Ozturk, O., Akcan, D., Tosun, M., AtaoglU, S., Terzioglu, C. (2015). Structural and mechanical properties of (Co/Mg) co-doped nano ZnO Ceramic Inter. 41 6326.
• Asikuzun, E., Ozturk, O., Arda, L., Terzioglu, C. (2017). Microstructural and electrical characterizations of transparent Er-doped ZnO nano-thin films prepared by sol-gel process J. Mater. Sci., Mater. Electron. 28, 14314–22.
• Asikuzun, E., Ozturk, O., Arda, L., Terzioglu, C. (2018). Preparation, growth and characterization of nonvacuum Cu-doped ZnO thin films, Journal of Molecular Structure, 1165, 1-7.
• Barthwala, S., Singh, N.B. (2020). Urea detection by ZnO-MWCNT nanocomposite sensor, Materials Today: Proceedings, 29;3, 749-752.
• Bilgili, Ö. (2021). The structural and optical properties of Al and Mg doped ZnO synthesized by solid state reaction method, J. Baun Inst. Sci. Technol., 23(1), 50-64.
• Chen, C. S., Xie, X. D., Liu, T. G., Lin, L. W., Kuang, J. C., Xie, X. L., Lu, L. J., Cao, S. Y. (2012). Multi-walled carbon nanotubes supported Cu-doped ZnO nanoparticles and their optical property, J Nanopart Res 14, 817.
• Chen, W., Wang, J., Wang, M.R. (2007). Influence of doping concentration on the properties of ZnO:Mn thin films by sol–gel method, Vacuum 81, 894.
• Cwirzen, A., Habermehl-Cwirzen, K., Penttala, V. (2008). No Access Surface decoration of carbon nanotubes and mechanical properties of cement/carbon nanotube composites, Advances in Cement Research, 20;2, 65-73.
• Diaz-Corona, N., Martínez‐Juárez, J., Pérez‐Luna, J. G., Hernández‐de la Luz, A. D., Rabanal, M. E., Robles‐Águila, M. J. (2019). Structural, optical and electrical behavior of zinc oxide/ MWCNT composite thin films, Optical and Quantum Electronics, 51:220.
• Edinger, S., Bansal, N., Bauch , M.,Wibowo, R.A., Hamid, R., Trimmel, G., Dimopoulos, T. (2017). Comparison of chemical bath-deposited ZnO films doped with Al, Ga and In. J Mater Sci., 52, 9410–9423.
• Etacheri, V., Roshan, R., Kumar, V. (2012). Mg-doped ZnO nanoparticles for efficient sunlight-driven photocatalysis. ACS applied materials & interfaces.
• Heiba, Z.K., Arda, L., Mohamed, M.B., Al-Jalali, M.A., Dogan, N. (2013). Structural and magnetic properties of (Al/Mg) Co-doped nano ZnO J. Supercond Nov. Magn 26 3299–304.
• Ilican, S., Caglar, Y., Caglar, M., Yakuphanoglu, F. (2008). Structural, optical and electrical properties of F-doped ZnO nanorod semiconductor thin films deposited by sol–gel process, Applied Surface Science 255, 2353–2359.
• Jaballah, S., Benamara, M., Dahman, H., A. Ly, D. Lahem , M. Debliquy, L. El Mir. (2020). Effect of Mg-doping ZnO nanoparticles on detection of low ethanol concentrations, Materials Chemistry and Physics, 255, 123643.
• Kim, S., Nam, G., Yim, K.G. (2013). Effects of post-heated ZnO seed layers on structural and optical properties of ZnO nanostructures grown by hydrothermal method, Electron. Mater. Lett., 9, 293–298.
• Majumder, S., Chatterjee, S., Basnet, P., Mukherjee, J. (2020). ZnO based nanomaterials for photocatalytic degradation of aqueous pharmaceutical waste solutions – A contemporary review, Environmental Nanotechnology, Monitoring & Management, 14, 100386.
• Karaduman E. I., Nurtayeva, T., Sbeta, M., Cagirtekin, A. O., Acar, S., Yildiz,A. (2019). Carbon monoxide gas sensing performance of ZnO:Al thin films prepared using different solvent–stabilizer combinations. J Mater Sci: Mater Electron., 30, 10560–10570.
• Kılınç, N., Arda, L., Öztürk, S., Öztürk, Z. Z. (2010). Structure and electrical properties of Mg-doped ZnO nanoparticles, Cryst. Res. Technol. 45; 5, 529 – 538.
• Kumar V. A., Lee, W.-J., Chung., Y.-D., Kim, J. (2021). Growth and device properties of ALD deposited ZnO films for CIGS solar cells, Materials Science in Semiconductor Processing, 121, 105406.
• Liu, S., Zhu, L., Cao, W., Li, P., Zhan, Z., Chen , Z., Yuan, X., Wang, J. (2021). Defect-related optical properties of Mg-doped ZnO nanoparticles synthesized via low temperature hydrothermal method, Journal of Alloys and Compounds 858, 157654.
• Mariappan, R., Ponnuswamy, V., Chandra A. Bose, Chithambararaj, A., Suresh, R., Ragavendar, M. (2014). Structural, optical and electrical characterization of nebulizer sprayed ZnO nano-rods. Superlattices Microstruct., 65, 184–94.
• Mia, M.N.H., Pervez, M.F., Khalid Hossain, M., Reefaz M. Rahman, Jalal Uddin, M., Al Mashud, M.A., Ghosh, H.K., Hoq, M. (2017). Influence of Mg content on tailoring optical bandgap of Mg-doped ZnO thin film prepared by sol-gel method, Results in Physics. 7, 2683–2691.
• Mujahıd, M. (2015). Synthesis, characterization and electrical properties of visible-light-driven Pt-ZnO/CNT, Bull. Mater. Sci., 38;4, 995–1001.
• Mohar, R.S., Sugihartono, I., Fauzia, V., Umar, A.A. (2020). Dependence of optical properties of Mg-doped ZnO nanorods on Al dopant, Surfaces and Interfaces, 19, 100518.
• Naccarato, F., Ricci, F., Suntivich, J., Hautier, G., Wirtz, L., Rignanese, G.-M. (2019). Searching for materials with high refractive index and wide band gap: A first-principles high-throughput study, Phys. Rev. Materials 3, 044602.
• Okeke, I.S., Agwu, K.K., Ubachukwu, A.A., Madiba, I.G., Maaza, M., Whyte, G.M., Ezema, F. I. (2021). Impact of particle size and surface defects on antibacterial and photocatalytic activities of undoped and Mg-doped ZnO nanoparticles, biosynthesized using one-step simple process, Vacuum, 187, 110110.
• Özütok, F., Karaduman E.I., Acar, S., Demiri, S. (2019). Enhancing the CO gas sensing properties of ZnO thin films with the decoration of MWCNTs. J Mater Sci: Mater Electron., 30, 259–265.
• Pattanaik, A., Tripathy, S.K., Naik, P., Meher, D.K. (2021). Structural and elastic properties of binary semiconductors from energy gaps, Applied Physics A, 127, 14.
• Popielarski, P., Mosinska, L., Bala, W., Paprocki, K., Yu Zorenko, Zorenko, T., Sypniewska, M. (2019). Persistent photoconductivity in ZnO thin films grown on Si substrate by spin coating method, Optical Materials, 97, 109343.
• Ramos-Corona, A., Rangela, R., Alvarado-Gil, J.J., Bartolo-Pérez, P., Quintana, P., Rodríguez-Gattorno, G. (2019). Photocatalytic performance of nitrogen doped ZnO structures supported on graphene oxide for MB degradation, Chemosphere, 236, 124368.
• Rodnyi, P.A., Khodyuk, I.V. (2011). Optical and luminescence properties of zinc oxide Opt. Spectrosc. 111 776–85.
• Sarf, F., Karaduman I. E., Yakar, E., Acar, S. (2020). The role of rare‑earth metal (Y, Ru and Cs)‑doped ZnO thin films in NH3 gas sensing performances at room temperature, Journal of Materials Science: Materials in Electronics 31, 10084–10095.
• Sarf, F., Kızıl, H. (2021). Defect Emission Energy and Particle Size Effects in Fe:ZnO Nanospheres Used in Li-Ion Batteries as Anode. J. Electron. Mater. 50, 6475–6481.
• Srinet, G., Kumar, R., Sajal., V. (2013). Effects of Mg doping on the structural and optical properties of ZnO nanoparticles, AIP Conference Proceedings 1536, 247.
• Sathya, M., Pushpanathan, K. (2018). Synthesis and Optical Properties of Pb Doped ZnO Nanoparticles, Applied Surface Science, 449, 346–357.
• Srinivasan, G., Rajendra Kumar, R.T., Kumar, J. (2007). Li doped and undoped ZnO nanocrystalline thin films: a comparative study of structural and optical properties. J Sol-Gel Sci Technol, 43, 171–7.
• Sahoo, T., Jang, LW., Jeon, DW., Yu, Y.-T., Lee, I.-H. (2013). Hydrothermal growth of single crystal ZnO nanorods on surface-modified graphite. Electron. Mater. Lett., 9, 715–718.
• Samadi, M., Zirak, M., Naseri, A., Khorashadizade E., Moshfegh A. Z. (2016). Recent progress on doped ZnO nanostructures for visible-light photocatalysis, Thin Solid Films, 605, 2–19.
• Sagheer, R., Khalil, M., Abbas, V., Kayani, Z.N., Tariq, U., Ashraf, F. (2020). Effect of Mg doping on structural, morphological, optical and thermal properties of ZnO nanoparticles, Optik - International Journal for Light and Electron Optics 200, 163428.
• Sharma, S., Periasamy, C., Chakrabarti, P. (2015). Thickness dependent study of RF sputtered ZnO thin films for optoelectronic device applications. Electron. Mater. Lett., 11, 1093–1101.
• Senol, S.D., Yalcin, B., Ozugurlu, E., Arda, L. (2020). Structure, microstructure, optical and photocatalytic properties of Mn-doped ZnO nanoparticles, Mater. Res. Express 7, 015079.
• Siregar, N., M. dan Johnny Panggabean (2020). The effect magnesium (Mg) on structural and optical properties of ZnO:Mg thin film by sol-gel spin coating method, Journal of Physics: Conference Series 1428, 012026.
• Tan, C., Sun, D., Xu, D., Tian, X., Huang, Y. (2016). Tuning electronic structure and optical properties of ZnO monolayer by Cd doping. Ceramics International, 42, 10997–11002.
• Umaralikhan, L., Mohamed Jaffar, M.J. (2017). Green synthesis of ZnO and Mg doped ZnO nanoparticles, and its optical properties, J Mater Sci: Mater Electron., 28, 7677–7685.
• Üzar, N., Algün, G., Akçay, N., Akcan, D., Arda, L. (2017). Structural, optical, electrical and humidity sensing properties of (Y/Al) co-doped ZnO thin films J. Mater. Sci., Mater. Electron. 28, 11861–70.
• Yang, Y., Wang, J., Li, X., Lang, J., Liu, F., Yang, L., Zhai, H., Gao, M., Zhao, X. (2012). Effect of polar and non-polar surfaces of ZnO nanostructures on photocatalytic properties, Journal of Alloys and Compounds, 528 28–33.
• Yao, M., Ding, F., Cao, Y., Hu, P., Fan, J., Lu, C., Yuan, F., Shi, C., Chen, Y. (2014). Sn doped ZnO layered porous nanocrystals with hierarchical structures and modified surfaces for gas sensors, Sensors and Actuators B, 201, 255–265.
• Wahyuono, R.A., Schmidt, C., Dellith, A., Dellith, J., Schulz, M., Seyring, M., Rettenmayr, M., Plentz, J., Dietzek, B. (2016). ZnO nanoflowers-based photoanodes: Aqueous chemical synthesis, microstructure and optical properties. Open Chem., 14:158-169.