Yeni Bir Schiff Bazı Ve Geçiş Metalleri İle Oluşturdukları Komplekslerin Sentezi Ve Karakterizasyonu

Year 2012, Volume: 1 Issue: 1, 34 - 39, 01.06.2012

Oğuz Kağan Taşkın Ömer Faruk Öztürk Erdal Canpolat

Abstract

Bu çalışmada, salisilaldehit ve 1,2-diborometan’ın kondenzesyonundan 2.2’-[etan-1,2-diilbis (oksi)] dibenzaldehid bileşiği sentezlendi. Bu bileşiğin 2-aminofenol ile reaksiyonundan yeni bir Schiff bazı ligandı (LH2) hazırlandı. Bu Schiff bazı ligandı ile Co+2, Ni+2 ve Zn+2 asetat tuzları reaksiyona sokularak Co(L)(H2O)2, Ni(L)(H2O)2 ve Zn(L)(H2O)2 kompleksleri elde edildi. Schiff bazı ve komplekslerinin yapıları, elementel analiz, IR, 1H-NMR, 13C-NMR, UV, manyetik duyarlılık ve termogravimetrik analiz ile aydınlatıldı.

Keywords

Schiff Bazları, Geçiş Metal Kompleksleri, Okso Grubu, Termal Analiz

References

• Pfeiffer P., Breith E., Lubbe E., Tsumaki T. 1933. Tricyclische Orthokondenzierte Nebenvolenzringe. Annalen Der Chemie, 503: 84-127.
• Köksal H. 1999. Yeni İmin-Oksim Ligandlarının ve Metal Komplekslerinin Sentezi ve Yapılarının Aydınlatılması. Fırat Üniversitesi, Fen Bilimleri Enstitüsü, Doktora tezi, 105s, Elazığ.
• Patai S. 1970. The Chemistry of Carbon-Nitrogen Double Bond. Interscience Publisher, 360p, London.
• Birbiçer N. 1998. Suda Çözünülebilir Boyar Maddelerin Metal Komplekslerinin Sentezi ve Boyar Madde Özelliklerinin İncelenmesi. Çukurova Üniversitesi, Fen Bilimleri Enstitüsü Doktora Tezi, 69s, Adana.
• Scovill J.P., Klayman D. L., Franchino F.F. 1982. 2-Acetylpyridine Thiosemicarbazones. 4. Complexes with Transition Metals as Antimalarial and Antileukemic Agents, Journal of Medicinal Chemistry, 25 (10): 1261-1264.
• West D.X., Pannell L.K. 1989. Transition-Metal Ion Complexes of Thiosemicarbazones Derived from 2-Acetrypyridine N-oxide 2. the N-4- Dimethyl Derivative, Transition Metal Chemistry, 14 (6): 457-462.
• Taşkın O.K. 2011. Yeni Bir Schiff Bazı ve Geçiş Metalleri ile Oluşturdukları Komplekslerin Sentezi ve Karakterizasyonu. Çanakkale Onsekiz Mart Üniversitesi, Fen Bilimleri Enstitüsü, Yüksek Lisans tezi, 76s, Çanakkale.
• Amer S.A., Gaber M., Issa R.M. 1988. Syntesis and Properties of the Binuclear Vanadium(III) and Oxovanadium(IV) Chelates with Tetradentate Schiff Bases, Poyhedron, 7 (24): 2635-2640.
• Hundekar A.M., Sen D.N. 1984. Preparation and Charcterization of Metal Complexes of N-Acetyl- N-Aroylferrocenyle Hydrazides, Indian Journal of Chemistry Sec A, 23 (6): 477-479.
• Saxena A., Tandon J.P. 1984. StructuralFeatures of Some Organotin(IV) Complexes of Semi- Semicabazone and Thio-Semicarbazones, Polyhedron, 3 (6): 681-688.
• Nelson S.M., Knox C.V., McCann M., Drew, M.G.B. 1981. Metal-Ion-Controlled Transamination in the Synthesis of Macrocyclic Schiff Base Ligans. 1. Reaction of 2,6-Diacetylepyridine and Dicarbonyle-Compounds with 3,6-Dioxaoctane-1,8-Diamine, Journal of the Chemical Society Dalton Transactions, (8): 1669-1677.
• Canpolat E., Kaya M., Öztürk Ö.F. 2007. Studies on Mononuclear Chelates Derived from Substituted Schiff-base Ligands (part 6): Synthesis and Characterization of a New 3- Ethoxysalicyliden-p-aminoacetophenoneoxime and Its Complexes with Co(II) Ni(II), Cu(II) and Zn(II), Journal of Coordination Chemistry, 60 (23): 2621-2627.
• Huang Y.H., Shen H.Y., Long S. 2002, Synthesis, Characterizaiton and Biological Activities of Schiff Base Complexes Derived from Methyl-Substituted Salicylaldehyde and D-Glucosamine, ML2 (M= Cu(II), Zn(II), Fe(II), Co(II), Ni(II): L= 3- or 4-Methylsalyclaldehyde D-Glucoseimine), Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 32 (9): 1611-1624.
• Canpolat E., Kaya M. 2004. Synthesis and Characterization of Two vic-Dioximes Containing the 1,3-Dioxolane Ring and 1,4-Diaminobutane and Their Cobalt(II), Nickel(II), Copper(II) and Zinc(II) Metal Complexes, Transition Metal Chemistry, 29 (5): 550-556.
• Singh H.R., Agarwala B.V. 1988. Journal of the Indian Chemical Society, 65: 591.
• Aboaly M.M., Khalil M.M.H. 2001. Synthesis and Spectroscopic Study of Cu(II), Ni(II), and Co(II) Complexes of the Ligand Salicylidene-2-Amino Thiophenol, Spectroscopy Letters, 34 (4): 495-504.
• Rsmussen J.C., Toftlund H., Nivorzhkin A.N., Bourasse J., Ford P.C. 1996. Luminescent Tetranuclear Copper(I) Clusters Containing Tetradentate NS Schiff Base Ligands. X-Ray Crystal Structure of Cu4L2 (L=N,N’-(2,2’-Diphenyl)-Bis(1,3-Diphenyl-4-İminomethyl-5-Thiopyrazole), Inorganica Chimica Acta, 251 (1-2): 291-298.
• Tanabe Y., Sugano S. 1954. On the Absorptıon Spectra of Complex Ions, Journal of the Physical Society of Japan, 9: 753-766.
• Tümer M., Köksal H., Şener M. K., Serin S. 1999. Antimicrobial ActivityStudies of the Binuclear Metal Complexes Derived From Tridentate Schiff Base Ligands, Transition Metal Chemistry, 24 (4): 414-420.
• Shanmuga B.K., Sreedarana S., Hema P.P., Kalilur R.A., Rajesha K., Jagadishb L., Kaviyarasanb V., Narayanan V. 2009. Synthesis of New Unsymmetrical “End-Off” Phenoxo Bridged Copper(II), Nickel(II) and Zinc(II) Complexes: Spectral, Magnetic, Electrochemical, Catalytic, and Antimicrobial Studies, Journal of Coordination Chemistry, 62 (8): 1356-1372.