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The Effect of Borax on Corrosion of Steels

Year 2021, Volume: 6 Issue: 3, 332 - 337, 30.09.2021
https://doi.org/10.30728/boron.889110

Abstract

In this study, the effect of borax (Na2B4O7) on the corrosion of Ç 1010, Ç 304 and Ç 316 steels was investigated. For this purpose, solutions with borax at different concentrations (0.0125 M, 0.025 M, 0.050 M and 0.100 M) were prepared. Cycling Voltammetry (CV) technique was used to determine the electrochemical behavior of steels in this environment, and Tafel Polarization Method was used to measure corrosion rates. As a result of the experiments, it was determined that the corrosion rate decreased and the corrosion potential increased in all three steels with increasing borax concentrations. The lowest corrosion rate was determined at the highest borax concentration. Corrosion rates of Ç 1010, Ç 304 and Ç 316 steels at 0,100 M borax concentration, it has been measured respectively as 0.251, 0.132 and 0.071 mm / year. Borax protected steels from corrosion by showing anodic inhibitory behavior. It is concluded that the steels can be used safely in borax solutions.

References

  • [1] Yilmaz, A.E., Boncukcuoǧlu, R., Kocakerm, M.M., ve Kocadaǧistan, E., An empirical model for kinetics of boron removal from boroncontaining wastewaters by the electrocoagulation method in a batch reactor. Desalination. 230 (1–3), 288–297.2008.
  • [2] Abu-Hamed, T., Karni, J., ve Epstein, M. The use of boron for thermochemical storage and distribution of solar energy. Solar Energy. 81 (1), 93–101, 2007.
  • [3] Obut, A., Ehsani, İ., Aktosun, Z., Yörükoğlu, A., Girgin, İ., Temel, A., Leaching behaviour of lithium from a clay sample of Kırka borate deposit in sulfuric acid solutions. Journal of Boron. 5 (4), 170–175,2020.
  • [4] Ezechi, E.H., Isa, M.H., Kutty, S.R., Sapari, N.B., Boron recovery, application and economic significance: A review. 2011 National Postgraduate Conference - Energy and Sustainability: Exploring the Innovative Minds, NPC 2011.
  • [5] Mohana, K.N. ve Badiea, A.M., Effect of sodium nitrite-borax blend on the corrosion rate of low carbon steel in industrial water medium. Corrosion Science. 50 (10), 2939–2947.2008.
  • [6] Graham, M.J., Bardwell, J.A., Sproule, G.I., Mitchell, D.F., MacDougall, B.R., The growth and stability of passive films. Corrosion Science. 35 (1–4), 13–18,1993.
  • [7] Silku, P., Özkinali, S., Öztürk, Z., Asan, A., Köse, D.A., Synthesis of novel Schiff Bases containing acryloyl moiety and the investigation of spectroscopic and electrochemical properties. Journal of Molecular Structure. 1116,2016.
  • [8] Tran, M., Mohammedi, D., Fiaud, C., Sutter, E.M.M., Corrosion behaviour of steel in the presence of Y(III) salts: Kinetic and mechanistic studies. Corrosion Science. 48 (12), 4257–4273, 2006.
  • [9] Igual Muñoz, A., García Antón, J., Guiñón, J.L., Pérez Herranz, V., he effect of chromate in the corrosion behavior of duplex stainless steel in LiBr solutions. Corrosion Science. 48 (12), 4127–4151, 2006.
  • [10] Bethencourt, M., Botana, F.J., Calvino, J.J., Marcos, M., Rodríguez-Chacón, M.A., Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: A review. Corrosion Science. 40 (11), 1803–1819, 1998.
  • [11] Sruthi, R., Rampradheep, G.S., Raja, K., A review on natural plant extract as a green inhibitor for steel corrosion resistance. International Journal of Advanced Science and Technology. 29 (3), 2020.
  • [12] Paul, S., Koley, I., Corrosion Inhibition of Carbon Steel in Acidic Environment by Papaya Seed as Green Inhibitor. Journal of Bio- and Tribo-Corrosion. 2 (2), 2016.
  • [13] Abbas, A.S., Fazakas, Török, T.I., Corrosion studies of steel rebar samples in neutral sodium chloride solution also in the presence of a bio-based (Green) inhibitor. International Journal of Corrosion and Scale Inhibition. 7 (1), 2008.
  • [14] Bakirhan, N.K., Asan, A., Colak, N., Sanli, S., The inhibition of steel corrosion in acidic solutions by a new Schiff base. Journal of the Chilean Chemical Society. 61 (3),2016.
  • [15] Olefjord, I., Clayton, C.R., Surface composition of stainless steel during active dissolution and passivation. ISIJ International. 31 (2), 134–141, 1991.
  • [16] Alibakhshi, E., Ramezanzadeh, M., Bahlakeh, G., Ramezanzadeh, B., Mahdavian, M., Motamedi, M., Glycyrrhiza glabra leaves extract as a green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution: Experimental, molecular dynamics, Monte Carlo and quantum mechanics study. Journal of Molecular Liquids. 255 185–198, 2018.
  • [17] Salhi, A., Tighadouini, S., El-Massaoudi, M., Elbelghiti, M., Bouyanzer, A., Radi, S., vd. Keto-enol heterocycles as new compounds of corrosion inhibitors for carbon steel in 1 M HCl: Weight loss, electrochemical and quantum chemical investigation. Journal of Molecular Liquids. 248 340–349,2017.
  • [18] McCafferty, E., Validation of corrosion rates measured by the Tafel extrapolation method. Corrosion Science. 47 (12), 3202–3215, 2005.
  • [19] Pardo, A., Merino, M.C., Coy, A.E., Viejo, F., Arrabal, R., ve Matykina, E., Pitting corrosion behaviour of austenitic stainless steels - combining effects of Mn and Mo additions. Corrosion Science. 50 (6), 1796–1806, 2008.
  • [20] Olsson, C.O.A.. Landolt, D., Passive films on stainless steels - Chemistry, structure and growth. Electrochimica Acta. 48 (9 SPEC.), 1093–1104, 2003.
  • [21] Oguzie, E.E., Li, Y., Wang, F.H., Corrosion inhibition and adsorption behavior of methionine on mild steel in sulfuric acid and synergistic effect of iodide ion. Journal of Colloid and Interface Science. 310 (1), 90–98, 2007.
  • [22] Ingle, A. V., Raja, V.S., Mishra, P., Rangarajan, J., Effect of Mo Addition on the Corrosion Behavior of Al-40Cr-xMo Coatings on Type 316L Stainless Steel. Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science. 51 (4), 1933–1944, 2020.

Çeliklerin korozyonuna Boraksın Etkisi

Year 2021, Volume: 6 Issue: 3, 332 - 337, 30.09.2021
https://doi.org/10.30728/boron.889110

Abstract

Bu çalışmada Ç 1010, Ç 304 ve Ç 316 çeliklerin korozyonuna boraksın (Na2B4O7) etkisi araştırılmıştır. Bu amaçla farklı derişimlerde (0,0125 M, 0,025 M, 0,050 M ve 0,100 M) borakslı çözeltiler hazırlanmıştır. Çeliklerin bu ortamdaki elektrokimyasal davranışını belirlemek için Dönüşümlü Voltametri (CV) tekniği, korozyon hızlarını ölçmek için ise Tafel Polarizasyon Yöntemi uygulanmıştır. Deneyler sonucunda boraks derişiminin artması ile her üç çelikte korozyon hızının azaldığı ve korozyon potansiyelinin arttığı tespit edilmiştir. En yüksek boraks derişiminde en düşük korozyon hızı Ç 316 çeliğinde belirlenmiştir. Ç 1010, Ç 304 ve Ç 316 çeliklerin 0,100 M boraks derişiminde korozyon hızları sırasıyla; 0,251, 0,132 ve 0,071 mm/yıl olarak ölçülmüştür. Boraks anodik inhibitör davranışı göstererek çelikleri korozyondan korumuştur. Çeliklerin borakslı çözeltilerde güvenle kullanılabileceği sonucuna varılmıştır.

References

  • [1] Yilmaz, A.E., Boncukcuoǧlu, R., Kocakerm, M.M., ve Kocadaǧistan, E., An empirical model for kinetics of boron removal from boroncontaining wastewaters by the electrocoagulation method in a batch reactor. Desalination. 230 (1–3), 288–297.2008.
  • [2] Abu-Hamed, T., Karni, J., ve Epstein, M. The use of boron for thermochemical storage and distribution of solar energy. Solar Energy. 81 (1), 93–101, 2007.
  • [3] Obut, A., Ehsani, İ., Aktosun, Z., Yörükoğlu, A., Girgin, İ., Temel, A., Leaching behaviour of lithium from a clay sample of Kırka borate deposit in sulfuric acid solutions. Journal of Boron. 5 (4), 170–175,2020.
  • [4] Ezechi, E.H., Isa, M.H., Kutty, S.R., Sapari, N.B., Boron recovery, application and economic significance: A review. 2011 National Postgraduate Conference - Energy and Sustainability: Exploring the Innovative Minds, NPC 2011.
  • [5] Mohana, K.N. ve Badiea, A.M., Effect of sodium nitrite-borax blend on the corrosion rate of low carbon steel in industrial water medium. Corrosion Science. 50 (10), 2939–2947.2008.
  • [6] Graham, M.J., Bardwell, J.A., Sproule, G.I., Mitchell, D.F., MacDougall, B.R., The growth and stability of passive films. Corrosion Science. 35 (1–4), 13–18,1993.
  • [7] Silku, P., Özkinali, S., Öztürk, Z., Asan, A., Köse, D.A., Synthesis of novel Schiff Bases containing acryloyl moiety and the investigation of spectroscopic and electrochemical properties. Journal of Molecular Structure. 1116,2016.
  • [8] Tran, M., Mohammedi, D., Fiaud, C., Sutter, E.M.M., Corrosion behaviour of steel in the presence of Y(III) salts: Kinetic and mechanistic studies. Corrosion Science. 48 (12), 4257–4273, 2006.
  • [9] Igual Muñoz, A., García Antón, J., Guiñón, J.L., Pérez Herranz, V., he effect of chromate in the corrosion behavior of duplex stainless steel in LiBr solutions. Corrosion Science. 48 (12), 4127–4151, 2006.
  • [10] Bethencourt, M., Botana, F.J., Calvino, J.J., Marcos, M., Rodríguez-Chacón, M.A., Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: A review. Corrosion Science. 40 (11), 1803–1819, 1998.
  • [11] Sruthi, R., Rampradheep, G.S., Raja, K., A review on natural plant extract as a green inhibitor for steel corrosion resistance. International Journal of Advanced Science and Technology. 29 (3), 2020.
  • [12] Paul, S., Koley, I., Corrosion Inhibition of Carbon Steel in Acidic Environment by Papaya Seed as Green Inhibitor. Journal of Bio- and Tribo-Corrosion. 2 (2), 2016.
  • [13] Abbas, A.S., Fazakas, Török, T.I., Corrosion studies of steel rebar samples in neutral sodium chloride solution also in the presence of a bio-based (Green) inhibitor. International Journal of Corrosion and Scale Inhibition. 7 (1), 2008.
  • [14] Bakirhan, N.K., Asan, A., Colak, N., Sanli, S., The inhibition of steel corrosion in acidic solutions by a new Schiff base. Journal of the Chilean Chemical Society. 61 (3),2016.
  • [15] Olefjord, I., Clayton, C.R., Surface composition of stainless steel during active dissolution and passivation. ISIJ International. 31 (2), 134–141, 1991.
  • [16] Alibakhshi, E., Ramezanzadeh, M., Bahlakeh, G., Ramezanzadeh, B., Mahdavian, M., Motamedi, M., Glycyrrhiza glabra leaves extract as a green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution: Experimental, molecular dynamics, Monte Carlo and quantum mechanics study. Journal of Molecular Liquids. 255 185–198, 2018.
  • [17] Salhi, A., Tighadouini, S., El-Massaoudi, M., Elbelghiti, M., Bouyanzer, A., Radi, S., vd. Keto-enol heterocycles as new compounds of corrosion inhibitors for carbon steel in 1 M HCl: Weight loss, electrochemical and quantum chemical investigation. Journal of Molecular Liquids. 248 340–349,2017.
  • [18] McCafferty, E., Validation of corrosion rates measured by the Tafel extrapolation method. Corrosion Science. 47 (12), 3202–3215, 2005.
  • [19] Pardo, A., Merino, M.C., Coy, A.E., Viejo, F., Arrabal, R., ve Matykina, E., Pitting corrosion behaviour of austenitic stainless steels - combining effects of Mn and Mo additions. Corrosion Science. 50 (6), 1796–1806, 2008.
  • [20] Olsson, C.O.A.. Landolt, D., Passive films on stainless steels - Chemistry, structure and growth. Electrochimica Acta. 48 (9 SPEC.), 1093–1104, 2003.
  • [21] Oguzie, E.E., Li, Y., Wang, F.H., Corrosion inhibition and adsorption behavior of methionine on mild steel in sulfuric acid and synergistic effect of iodide ion. Journal of Colloid and Interface Science. 310 (1), 90–98, 2007.
  • [22] Ingle, A. V., Raja, V.S., Mishra, P., Rangarajan, J., Effect of Mo Addition on the Corrosion Behavior of Al-40Cr-xMo Coatings on Type 316L Stainless Steel. Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science. 51 (4), 1933–1944, 2020.
There are 22 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Research Article
Authors

Gülden Asan 0000-0002-6075-159X

Abdurrahman Asan 0000-0002-1010-3981

Publication Date September 30, 2021
Acceptance Date August 8, 2021
Published in Issue Year 2021 Volume: 6 Issue: 3

Cite

APA Asan, G., & Asan, A. (2021). Çeliklerin korozyonuna Boraksın Etkisi. Journal of Boron, 6(3), 332-337. https://doi.org/10.30728/boron.889110