KURŞUN(II) ASETAT KOORDİNASYON POLİMERLERİ - LEAD(II) ACETATE COORDINATION POLYMERS

Year 2013, Volume: 9 Issue: 2, 1 - 8, 06.01.2015

Şebnem Esen Sözerli

Abstract

KURŞUN(II) ASETAT KOORDİNASYON POLİMERLERİ

Çok çeşitli topolojileri ve kataliz, moleküler tanımlama, ayırma, gaz depolama, iyon değişimi, kimyasal sensörler, manyetizm, doğrusal olmayan optikler ve lüminesans gibi pek çok olası uygulamaları nedeniyle çok çeşitli olağandışı yapılar ve özellikler gösteren koordinasyon polimerlerinin tasarım ve sentezi giderek artan öneme sahiptir. Son yıllarda, metal karboksilatları metal-organik çerçeve malzemeleri olarak olası uygulamaları ile literatürde öne çıkmaktadır. Ağır p-blok metal iyonu olan Pb(II), değişken koordinasyon sayısı ve stereokimyasal aktivitesi ile ilgi çekici fiziksel özellikler gösteren olağanüstü ağ topolojileri inşa etmeye uygunluğu nedeniyle dikkat çekici bir ilgiye sahiptir. Bu derlemede, asetat ve N-verici atomlu organik ligandlar içeren kurşun(II) koordinasyon polimerlerinin yapılarından bahsedilmiştir.

LEAD(II) ACETATE COORDINATION POLYMERS

The design and synthesis of coordination polymers with unusual structures and properties have growing interest due to their diverse topologies and numerous potential applications in catalysis, molecular recognition, separation, gas storage, ion exchange, chemical sensing, magnetism, nonlinear optics and luminescence. In recent years, metal carboxylates have appeared as metal-organic framework materials with potential applications in the literature. Lead(II) as a heavy p-block metal ion with flexible coordination environment and variable stereochemical activity has considerable attention because of the suitability to construct incredible network topologies with intriguing physical properties. In this review, structures of the lead(II) coordination polymers containing acetate and N-donor organic ligands are described.

 

 

 

Keywords

Kurşun(II) kompleksleri, Asetat, Koordinasyon polimeri

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