Year 2018, Volume , Issue 041, Pages 1 - 12 2018-12-16

PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU
SYNTHESIS AND CHARACTERIZATION OF PROTON TRANSFER SALT OF PYRIDINE-2,6-DICARBOXYLIC ACID AND ITS Ni(II) AND Cu(II) COMPLEXES

Nurgün Büyükkıdan [1] , Bülent Büyükkıdan [2] , Nedime Demir [3] , Ceyda Karahan [4]


Bu çalışmada piridin-2,6-dikarboksilik asitin (H2dipic), N-metilpiperazin (Meppz) ile reaksiyonundan proton transfer tuzu (H2Meppz)(Hdipic)2 (1) elde edilmiştir. Elde edilen proton transfer tuzunun (1) Ni(CH3COO)2.4H2O ve Cu(CH3COO)2.H2O ile reaksiyonundan ise metal kompleksleri [Ni(H2O)6][Ni(dipic)2].(Meppz).5H2O (2) ve (H2Meppz)[Cu(dipic)2].2H2O (3) sentezlenmiştir. Proton transfer tuzunun (1) yapısı FT-IR, 1H ve 13C NMR, ve UV-Vis spekroskopileri ve elementel analiz teknikleri ile aydınlatılmıştır. Komplekslerin yapıları ise FT-IR, UV-Vis, ICP-OES, manyetik duyarlılık ve elementel analiz yöntemlerinden elde edilen verilere göre önerilmiştir. 

In this study the proton transfer salt (H2Meppz)(Hdipic)2 (1) was obtained by the reaction of N-methylpiperazine (Meppz) with pyridine-2,6-dicarboxylic acid (H2dipic). The metal complexes [Ni(H2O)6][Ni(dipic)2].(Meppz).5H2O (2) and (H2Meppz)[Cu(dipic)2].2H2O (3) were synthesized by the reaction of proton transfer salt (1) with Ni(CH3COO)2.4H2O and Cu(CH3COO)2.2H2O. The structure of proton transfer salt (1)  was characterized by 1H and 13C NMR, FT-IR and UV-Vis spectra and elemental analysis techniques. The structures of the complexes have been suggested according to data obtained from FT-IR, UV-Vis, ICP-OES, magnetic susceptibility and elemental analysis methods. 

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Primary Language tr
Subjects Engineering, Chemical
Journal Section Articles
Authors

Orcid: 0000-0001-6879-9355
Author: Nurgün Büyükkıdan (Primary Author)

Orcid: 0000-0001-9619-3246
Author: Bülent Büyükkıdan

Orcid: 0000-0001-9134-4500
Author: Nedime Demir

Orcid: 0000-0002-9359-0040
Author: Ceyda Karahan

Dates

Publication Date : December 16, 2018

Bibtex @research article { dpufbed495628, journal = {Dumlupınar Üniversitesi Fen Bilimleri Enstitüsü Dergisi}, issn = {1302-3055}, eissn = {2651-2769}, address = {Dumlupınar Üniversitesi Fen Bilimleri Enstitüsü Evliya Çelebi Yerleşkesi Tavşanlı Yolu 10. Km Merkez/KÜTAHYA}, publisher = {Dumlupinar University}, year = {2018}, volume = {}, pages = {1 - 12}, doi = {}, title = {PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU}, key = {cite}, author = {Büyükkıdan, Nurgün and Büyükkıdan, Bülent and Demir, Nedime and Karahan, Ceyda} }
APA Büyükkıdan, N , Büyükkıdan, B , Demir, N , Karahan, C . (2018). PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU. Dumlupınar Üniversitesi Fen Bilimleri Enstitüsü Dergisi , (041) , 1-12 . Retrieved from https://dergipark.org.tr/en/pub/dpufbed/issue/41010/495628
MLA Büyükkıdan, N , Büyükkıdan, B , Demir, N , Karahan, C . "PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU". Dumlupınar Üniversitesi Fen Bilimleri Enstitüsü Dergisi (2018 ): 1-12 <https://dergipark.org.tr/en/pub/dpufbed/issue/41010/495628>
Chicago Büyükkıdan, N , Büyükkıdan, B , Demir, N , Karahan, C . "PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU". Dumlupınar Üniversitesi Fen Bilimleri Enstitüsü Dergisi (2018 ): 1-12
RIS TY - JOUR T1 - PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU AU - Nurgün Büyükkıdan , Bülent Büyükkıdan , Nedime Demir , Ceyda Karahan Y1 - 2018 PY - 2018 N1 - DO - T2 - Dumlupınar Üniversitesi Fen Bilimleri Enstitüsü Dergisi JF - Journal JO - JOR SP - 1 EP - 12 VL - IS - 041 SN - 1302-3055-2651-2769 M3 - UR - Y2 - 2018 ER -
EndNote %0 Dumlupınar Üniversitesi Fen Bilimleri Enstitüsü Dergisi PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU %A Nurgün Büyükkıdan , Bülent Büyükkıdan , Nedime Demir , Ceyda Karahan %T PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU %D 2018 %J Dumlupınar Üniversitesi Fen Bilimleri Enstitüsü Dergisi %P 1302-3055-2651-2769 %V %N 041 %R %U
ISNAD Büyükkıdan, Nurgün , Büyükkıdan, Bülent , Demir, Nedime , Karahan, Ceyda . "PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU". Dumlupınar Üniversitesi Fen Bilimleri Enstitüsü Dergisi / 041 (December 2018): 1-12 .
AMA Büyükkıdan N , Büyükkıdan B , Demir N , Karahan C . PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU. DPÜ Fen Bilimleri Enstitüsü Dergisi. 2018; (041): 1-12.
Vancouver Büyükkıdan N , Büyükkıdan B , Demir N , Karahan C . PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU. Dumlupınar Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2018; (041): 12-1.