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The Investigation of Electrochemical Corrosion Behaviour of Fe Matrix Composites at Room and Elevated Temperatures

Year 2020, Volume: 8 Issue: 1, 418 - 427, 31.01.2020
https://doi.org/10.29130/dubited.542876

Abstract

In this study,
pure Fe and Fe matrix composites (5 wt. % nano-Al2O3, 5
wt. % micron-B4C and 2.5 wt. % nano-Al2O3-2.5
wt. % micron-B4C) were manufactured via powder metallurgy. The
density and phase analysis of the produced samples were performed. The
electrochemical corrosion behaviour of the samples in a 3.5 wt. % NaCl solution
was studied using potentiodynamic polarization at 25, 50 and 75 ºC. The
corrosion rate of the samples significantly increased with increasing test
temperature. Also, the effect of reinforcement particulates leads to
deteriorate corrosion resistance of pure Fe due to the presence of galvanic
reactions.

References

  • [1] A. K. Srivastava, K. Das and S. K. Toor, “Corrosion behaviour of TiC-Reinforced hadfield manganese austenitic steel matrix In-Situ composites,” Open Journal of Metals, vol. 5, pp. 11-17, 2015.
  • [2] K. Das, T. K. Bandyopadhyay and S. Das, “A review on the various synthesis routed of TiC reinforced ferrous based composites,” Journal of Materials Science, vol. 37, no. 18, pp. 3881-3892, 2002.
  • [3] J. Pelleg, “Reactions in the matrix and interface of the Fe–SiC metal matrix composite system,” Materials Science and Engineering A, vol. 269, no.1-2, pp. 225–241, 1999.
  • [4] W. Jing and W. Yisan, “In-situ production of Fe–TiC composite,” Materials Letters, vol. 61, no. 22, pp. 4393–4395, 2007.
  • [5] P. Gupta, D. Kumar, O. Parkash, A.K. Jha and K.K. Sadasivuni, “Dependence of wear behavior on sintering mechanism for Iron- alumina metal matrix nanocomposites,” Materials Chemistry and Physics, vol. 220, pp. 441-448, 2018.
  • [6] J. Cheng, T. Huang and Y.F. Zheng, “Microstructure, mechanical property, biodegradation behavior, and biocompatibility of biodegradable Fe–Fe2O3 composites,” Journal of Biomedical Materials Research Part A, vol. 102, no. 7, pp. 2277-2287, 2014.
  • [7] D. Liu, L. Li, F. Li and Y. Chen, “WCp/Fe metal matrix composites produced by laser melt injection,” Surface & Coatings Technology, vol.202, no. 9, pp. 1771-1777, 2008.
  • [8] T. R. Prabhu, V. K.Varma and S. Vedantam, “Effect of reinforcement type, size, and volume fraction on the tribological behavior of Fe matrix composites at high sliding speed conditions,” Wear, vol. 309, no. 1-2, pp. 247–255, 2014.
  • [9] P. Gupta, D. Kumar, O. Parkash, and A.K. Jha, “Sintering and hardness beahavior of Fe-Al2O3 metal matrix nanocomposites prepared by powder metallurgy,” Journal of Composites, vol. 2014, pp.1-10, 2014.
  • [10] A. Kumar, M.K. Banerjee, and U. Pandel, “Development of a novel MWCNT reinforced iron matrix nanocomposite through powder metallurgy route,” Powder Technology, vol. 331, pp. 41–51, 2018.
  • [11] A. Kumar, U. Banerjee, M. K. Chowrasia, H. Shekhar, and M.K. Banerjee, “Effect of MWCNT Content on the structure and properties of spark plasma-sintered Iron-MWCNT composites synthesized by high-energy ball milling,” Journal of Materials Engineering and Performance, vol.28, no. 5, pp. 2983-3000, 2019.
  • [12] F. Chen, Z. Li, Q. Shan, Y. Jiang, Y. Zhang, and F. Zhang, “Effects of different matrix on interface and compression fracture behavior of WC particles reinforced iron matrix composites,” Materials Science Forum, vol. 913, pp. 480-489, 2018.
  • [13] V. Ramya, A. Gangwar, S.K Shaw, N.K. Mukhopadhyay and N.K. Prasad, “Fe/Fe3O4 nanocomposite powders with giant high magnetization values by high energy ball milling,” Bulletin of Materials Science, vol. 42, no. 93, pp. 1-7, 2019.
  • [14] P. Gupta, D. Kumar, M.A. Quraishi and O. Parkash, “Effect of sintering parameters on the corrosion characteristics of Iron-Alumina metal matrix nanocomposites,” Journal of Materials and Environmental Science, vol. 6, no. 1, pp. 155-167, 2015.
  • [15] P. Khosla, H. K Singh, V. Katoch, A. Dubey, N. Singh, D. Kumar and P. Gupta, “Synthesis, mechanical and corrosion behaviour of iron–silicon carbide metal matrix nanocomposites,” Journal of Composite Materials, vol. 52, no. 1, pp. 91-107, 2018.
  • [16] M.S. Jasinska, P. Chevallier, S. Turgeon, C. Paternoster, E. Mostaed, M. Vedani, and D. Mantovania, “Understanding the effect of the reinforcement addition on corrosion behavior of Fe/Mg2Si composites for biodegradable implant applications,” Materials Chemistry and Physics, vol. 223, pp. 771–778, 2019.
  • [17] Y.C. Zhao, Y. Tang, M.C. Zhao, L. Liu, C. Gao, C. Shuai, R.C. Zeng, A. Atrens, and Y. Lin, Graphene oxide reinforced ıron matrix composite with enhanced biodegradation rate prepared by selective laser melting,” Advanced Engineering Materials, vol. 21, no. 8, pp. 1-5, 2019.
  • [18] F. Aydin and Y. Sun, “Investigation of wear behaviour and microstructure of hot-pressed TiB2 particulate-reinforced magnesium matrix composites,” Canadian Metallurgical. Quarterly, vol. 57, no. 4, pp. 455-469, 2018.
  • [19] A. Standard, Standard practice for calculation of corrosion rates and related information from electrochemical measurements, Annu. Book ASTM Stand. ASTM Int.West Conshohocken PA 3 (1994) G102–G89.
  • [20] H.M. Zakaria, “Microstructural and corrosion behavior of Al/SiC metal matrix composites, Ain Shams Engineering Journal,” vol. 5, no. 3, pp. 831–838, 2014.
  • [21] S.C. Sharma,“A study on stress corrosion behavior of Al6061/albite composite in higher temperature acidic medium using autoclave,” Corrosion Science, vol. 43, no. 10, pp. 1877-1889, 2001.

Fe Matrisli Kompozitlerin Oda ve Yüksek Sıcaklıklardaki Elektrokimyasal Korozyon Davranışının İncelenmesi

Year 2020, Volume: 8 Issue: 1, 418 - 427, 31.01.2020
https://doi.org/10.29130/dubited.542876

Abstract

Bu çalışmada, saf Fe ve Fe matrisli kompozitler (%
5ağ. nano-Al2O3, %5ağ. mikron-B4C ve %2.5 ağ. 
nano-Al2O3-2.5 ağ. % mikron-B4C) toz metalurjisi ile üretilmiştir.
Üretilen numunelerin yoğunluk ölçümleri ve faz analizleri gerçekleştirilmiştir.
Numunelerin elektrokimyasal korozyon davranışı 25, 50 ve 75 ºC’de %3.5NaCl
çözeltisi içinde potansiyodinamik polarizasyon ile gerçekleştirilmiştir.
Numunelerin korozyon hızları artan test sıcaklığıyla önemli ölçüde artmıştır.
Ayrıca, takviye partikülleri galvanik reaksiyonlar sebebiyle saf Fe’in korozyon
dayanımını kötüleştirmiştir.

References

  • [1] A. K. Srivastava, K. Das and S. K. Toor, “Corrosion behaviour of TiC-Reinforced hadfield manganese austenitic steel matrix In-Situ composites,” Open Journal of Metals, vol. 5, pp. 11-17, 2015.
  • [2] K. Das, T. K. Bandyopadhyay and S. Das, “A review on the various synthesis routed of TiC reinforced ferrous based composites,” Journal of Materials Science, vol. 37, no. 18, pp. 3881-3892, 2002.
  • [3] J. Pelleg, “Reactions in the matrix and interface of the Fe–SiC metal matrix composite system,” Materials Science and Engineering A, vol. 269, no.1-2, pp. 225–241, 1999.
  • [4] W. Jing and W. Yisan, “In-situ production of Fe–TiC composite,” Materials Letters, vol. 61, no. 22, pp. 4393–4395, 2007.
  • [5] P. Gupta, D. Kumar, O. Parkash, A.K. Jha and K.K. Sadasivuni, “Dependence of wear behavior on sintering mechanism for Iron- alumina metal matrix nanocomposites,” Materials Chemistry and Physics, vol. 220, pp. 441-448, 2018.
  • [6] J. Cheng, T. Huang and Y.F. Zheng, “Microstructure, mechanical property, biodegradation behavior, and biocompatibility of biodegradable Fe–Fe2O3 composites,” Journal of Biomedical Materials Research Part A, vol. 102, no. 7, pp. 2277-2287, 2014.
  • [7] D. Liu, L. Li, F. Li and Y. Chen, “WCp/Fe metal matrix composites produced by laser melt injection,” Surface & Coatings Technology, vol.202, no. 9, pp. 1771-1777, 2008.
  • [8] T. R. Prabhu, V. K.Varma and S. Vedantam, “Effect of reinforcement type, size, and volume fraction on the tribological behavior of Fe matrix composites at high sliding speed conditions,” Wear, vol. 309, no. 1-2, pp. 247–255, 2014.
  • [9] P. Gupta, D. Kumar, O. Parkash, and A.K. Jha, “Sintering and hardness beahavior of Fe-Al2O3 metal matrix nanocomposites prepared by powder metallurgy,” Journal of Composites, vol. 2014, pp.1-10, 2014.
  • [10] A. Kumar, M.K. Banerjee, and U. Pandel, “Development of a novel MWCNT reinforced iron matrix nanocomposite through powder metallurgy route,” Powder Technology, vol. 331, pp. 41–51, 2018.
  • [11] A. Kumar, U. Banerjee, M. K. Chowrasia, H. Shekhar, and M.K. Banerjee, “Effect of MWCNT Content on the structure and properties of spark plasma-sintered Iron-MWCNT composites synthesized by high-energy ball milling,” Journal of Materials Engineering and Performance, vol.28, no. 5, pp. 2983-3000, 2019.
  • [12] F. Chen, Z. Li, Q. Shan, Y. Jiang, Y. Zhang, and F. Zhang, “Effects of different matrix on interface and compression fracture behavior of WC particles reinforced iron matrix composites,” Materials Science Forum, vol. 913, pp. 480-489, 2018.
  • [13] V. Ramya, A. Gangwar, S.K Shaw, N.K. Mukhopadhyay and N.K. Prasad, “Fe/Fe3O4 nanocomposite powders with giant high magnetization values by high energy ball milling,” Bulletin of Materials Science, vol. 42, no. 93, pp. 1-7, 2019.
  • [14] P. Gupta, D. Kumar, M.A. Quraishi and O. Parkash, “Effect of sintering parameters on the corrosion characteristics of Iron-Alumina metal matrix nanocomposites,” Journal of Materials and Environmental Science, vol. 6, no. 1, pp. 155-167, 2015.
  • [15] P. Khosla, H. K Singh, V. Katoch, A. Dubey, N. Singh, D. Kumar and P. Gupta, “Synthesis, mechanical and corrosion behaviour of iron–silicon carbide metal matrix nanocomposites,” Journal of Composite Materials, vol. 52, no. 1, pp. 91-107, 2018.
  • [16] M.S. Jasinska, P. Chevallier, S. Turgeon, C. Paternoster, E. Mostaed, M. Vedani, and D. Mantovania, “Understanding the effect of the reinforcement addition on corrosion behavior of Fe/Mg2Si composites for biodegradable implant applications,” Materials Chemistry and Physics, vol. 223, pp. 771–778, 2019.
  • [17] Y.C. Zhao, Y. Tang, M.C. Zhao, L. Liu, C. Gao, C. Shuai, R.C. Zeng, A. Atrens, and Y. Lin, Graphene oxide reinforced ıron matrix composite with enhanced biodegradation rate prepared by selective laser melting,” Advanced Engineering Materials, vol. 21, no. 8, pp. 1-5, 2019.
  • [18] F. Aydin and Y. Sun, “Investigation of wear behaviour and microstructure of hot-pressed TiB2 particulate-reinforced magnesium matrix composites,” Canadian Metallurgical. Quarterly, vol. 57, no. 4, pp. 455-469, 2018.
  • [19] A. Standard, Standard practice for calculation of corrosion rates and related information from electrochemical measurements, Annu. Book ASTM Stand. ASTM Int.West Conshohocken PA 3 (1994) G102–G89.
  • [20] H.M. Zakaria, “Microstructural and corrosion behavior of Al/SiC metal matrix composites, Ain Shams Engineering Journal,” vol. 5, no. 3, pp. 831–838, 2014.
  • [21] S.C. Sharma,“A study on stress corrosion behavior of Al6061/albite composite in higher temperature acidic medium using autoclave,” Corrosion Science, vol. 43, no. 10, pp. 1877-1889, 2001.
There are 21 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Fatih Aydın 0000-0002-0768-7162

Mehmet Akif Erden 0000-0003-1081-4713

Publication Date January 31, 2020
Published in Issue Year 2020 Volume: 8 Issue: 1

Cite

APA Aydın, F., & Erden, M. A. (2020). The Investigation of Electrochemical Corrosion Behaviour of Fe Matrix Composites at Room and Elevated Temperatures. Düzce Üniversitesi Bilim Ve Teknoloji Dergisi, 8(1), 418-427. https://doi.org/10.29130/dubited.542876
AMA Aydın F, Erden MA. The Investigation of Electrochemical Corrosion Behaviour of Fe Matrix Composites at Room and Elevated Temperatures. DUBİTED. January 2020;8(1):418-427. doi:10.29130/dubited.542876
Chicago Aydın, Fatih, and Mehmet Akif Erden. “The Investigation of Electrochemical Corrosion Behaviour of Fe Matrix Composites at Room and Elevated Temperatures”. Düzce Üniversitesi Bilim Ve Teknoloji Dergisi 8, no. 1 (January 2020): 418-27. https://doi.org/10.29130/dubited.542876.
EndNote Aydın F, Erden MA (January 1, 2020) The Investigation of Electrochemical Corrosion Behaviour of Fe Matrix Composites at Room and Elevated Temperatures. Düzce Üniversitesi Bilim ve Teknoloji Dergisi 8 1 418–427.
IEEE F. Aydın and M. A. Erden, “The Investigation of Electrochemical Corrosion Behaviour of Fe Matrix Composites at Room and Elevated Temperatures”, DUBİTED, vol. 8, no. 1, pp. 418–427, 2020, doi: 10.29130/dubited.542876.
ISNAD Aydın, Fatih - Erden, Mehmet Akif. “The Investigation of Electrochemical Corrosion Behaviour of Fe Matrix Composites at Room and Elevated Temperatures”. Düzce Üniversitesi Bilim ve Teknoloji Dergisi 8/1 (January 2020), 418-427. https://doi.org/10.29130/dubited.542876.
JAMA Aydın F, Erden MA. The Investigation of Electrochemical Corrosion Behaviour of Fe Matrix Composites at Room and Elevated Temperatures. DUBİTED. 2020;8:418–427.
MLA Aydın, Fatih and Mehmet Akif Erden. “The Investigation of Electrochemical Corrosion Behaviour of Fe Matrix Composites at Room and Elevated Temperatures”. Düzce Üniversitesi Bilim Ve Teknoloji Dergisi, vol. 8, no. 1, 2020, pp. 418-27, doi:10.29130/dubited.542876.
Vancouver Aydın F, Erden MA. The Investigation of Electrochemical Corrosion Behaviour of Fe Matrix Composites at Room and Elevated Temperatures. DUBİTED. 2020;8(1):418-27.