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Some physical properties of the Pbs films obtained by chemical bath deposition using different molarity Pb No3 2 solution

Year 2018, Volume: 7 Issue: 1, 42 - 49, 01.03.2018

Abstract

Nanocrystalline PbS thin films produced using the chemical bath deposition method have been investigated. In all experiments, Pb NO3 2 solution and CS NH2 2 solution were used and the deposition temperature was maintained at 200C throughout the deposition. The pH value of the deposition solution is set to 11,5. Characterization of nanocrystalline PbS thin films was performed using X-ray diffraction XRD and scanning electron microscopy SEM methods. XRD results show that all films are in the cubic PbS structure. As the molarity value of the Pb NO3 2concentration increases, the thickness of the films increases. It has been observed that the thin filmin produced as Pb NO3 2 molarity 0,011 M has a higher XRD peak intensity than the other thin films produced. However, when SEM images are examined, it is observed that the thin filmin produced as 0,009 M of Pb NO3 2 molarity has less pinhole

References

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  • [2] H.K arami, M. Ghasemi, S. Matini, 2013, Synthesis, Characterization and Application of Lead Sulfide Nanostructures as Ammonia Gas Sensing Agent, International Journal of electrochemical science, 8, 11661– 11679
  • [3] A. P. Alivisatos, 1996, Perspectives on the physical chemistry of semiconductor nanocrystals, Journal of Physical Chemistry, 100, 13226–13239.
  • [4] C. E. Steven, Z. Lijun, M. Haftel, L. E. Alexander, A. K. Thomas, J. N. David, Doping semiconductor nanocrystals, 2005, Nature, 436, 91-94
  • [5] X. Peng, L. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich, A. P. Alivisatos, 2000, Shape control of CdSe nanocrystals, Nature, 404, 6773, 59
  • [6] Y. Peng, A. W. Xu, B. Deng, M. Antonietti, H. Cölfen, 2006, Polymer-controlled crystallization of zinc oxide hexagonal nanorings and disks, Journal of Physical Chemistry B, 110, 2988- 2993
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  • [12]S. Lindross, T. Kanniainen, J. Ihanus, M. Leskela, 1996, ZnS thin films grown by SILAR on poly (vinyl chloride) and polycarbonate substrates, Journal of Materials Chemistry, 6, 1497–1500
  • [13]B. Thangaraju, P. Kaliannan, 2000, Spray pyrolytically deposited PbS thin films, Semiconductor Science and Technology, 15, 849– 853
  • [14]D.L. Partin, J. Heremans, T.S. Moss, S. Mahajan, 1994, Handbook on Semiconductors, Elsevier, 3, 369
  • [15]P. O’Brien and J. McAleese, 1998, Developing an understanding of the processes controlling the chemical bath deposition of ZnS and CdS, Journal of Materials Chemistry, 8, 2309-2314
  • [16]P.K. Nair, M.T.S Nair, 1989, Versatile solar control characteristics of chemically deposited PbS-CuxS thin film combinations, Semiconductor Science and Technology, 4, 807
  • [17]K.M. Gadave, S.A. Jodgudri, C.D. Lokhande, 1994, Chemical deposition of PbS from acidic bath, Thin Solid Films, 245, 7-9
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  • [23] M. Saleem, L. F. Liang, A. Wakeel, M. Rashad and C. Y. Kong, 2012, Simple preparation and characterization of nano-crystalline zinc oxide thin films by sol-gel method on glass substrate, World Journal of Condensed Matter Physics, 2, 10-15
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  • [25] A. Hussain, A. Begum, and A. Rahman, 2013, Characterization of Nanocrystalline Lead Sulphide Thin Films Prepared by Chemical Bath Deposition Technique, Arabian Journal for Science and Engineering, 38, 1, 169–174
  • [26] S. Rajathi, K. Kirubavathi, and K. Selvaraju, 2015, Structural, morphological, optical, and photoluminescence properties of nanocrystalline PbS thin films grown by chemical bath deposition, Arabian Journal of Chemistry
  • [27] A. N. Fouda, M. Marzook, H. M. Abd El-Khalek, S. Ahmed, E. A. Eid, A. B. El Basaty, 2017, Structural and Optical Characterization of Chemically Deposited PbS Thin Films, Silicon, 9, 6, 809–816
  • [28] A. Hussain, A. Begum, A. Rahman, 2013, Characterization of nanocrystalline lead sulphide thin films prepared by chemical bath deposition technique, Arabian Journal for Science and Engineering, 38, 169–174
  • [29] B. Altıokka, M. C. Baykul, M. R. Altıokka, 2013, Some physical effects of reaction rate on PbS thin films obtained by chemical bath deposition, Journal of Crystal Growth, 384, 50-54

Farklı molaritede Pb No3 2 çözeltisi kullanılarak kimyasal banyo depolaması yöntemi ile elde edilen Pbs filmlerin bazı fiziksel özellikleri

Year 2018, Volume: 7 Issue: 1, 42 - 49, 01.03.2018

Abstract

Kimyasal banyo depozisyon metot kullanılarak üretilen nanokristal PbS ince filmler incelenmiştir. Tüm deneylerde, Pb NO3 2 ve CS NH2 2 çözeltisi kullanılmıştır. Depozisyon sıcaklığı depozisyon boyunca 200C’de tutulmuştur. Depozisyon çözeltisinin pH değeri 11,5 olarak ayarlanmıştır. Nanokristal PbS ince filmlerin karakterizasyonu X-ışını kırınımı XRD ve taramalı elektron mikroskobu SEM yöntemleri kullanılarak gerçekleştirilmiştir. XRD sonuçlarına göre, tüm filmlerin kübik PbS yapısında olduğu anlaşılmıştır. Pb NO3 2 konsantrasyonunun molarite değeri arttıkça filmlerin kalınlığının arttığı gözlenmiştir. Pb NO3 2 molaritesi 0,011 M olarak üretilen ince filmin , üretilen diğer ince filmlere göre daha yüksek XRD pik şiddetine sahip olduğu gözlenmiştir. Fakat SEM görüntüleri incelendiğinde Pb NO3 2 molaritesi 0,009 M olarak üretilen ince filmin daha az pinhole sahip olduğu gözlenmiştir

References

  • [1] Y.N. Xia, P.D. Yang, Y.G. Sun, Y.Y. Wu, B. Mayers, B. Gates, Y.D. Yin, F. Kim, H.Q. Yan, 2003, One-dimensional nanostructures: synthesis, characterization, and applications, Advanced Materials, 15 (5), 353-359.
  • [2] H.K arami, M. Ghasemi, S. Matini, 2013, Synthesis, Characterization and Application of Lead Sulfide Nanostructures as Ammonia Gas Sensing Agent, International Journal of electrochemical science, 8, 11661– 11679
  • [3] A. P. Alivisatos, 1996, Perspectives on the physical chemistry of semiconductor nanocrystals, Journal of Physical Chemistry, 100, 13226–13239.
  • [4] C. E. Steven, Z. Lijun, M. Haftel, L. E. Alexander, A. K. Thomas, J. N. David, Doping semiconductor nanocrystals, 2005, Nature, 436, 91-94
  • [5] X. Peng, L. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich, A. P. Alivisatos, 2000, Shape control of CdSe nanocrystals, Nature, 404, 6773, 59
  • [6] Y. Peng, A. W. Xu, B. Deng, M. Antonietti, H. Cölfen, 2006, Polymer-controlled crystallization of zinc oxide hexagonal nanorings and disks, Journal of Physical Chemistry B, 110, 2988- 2993
  • [7] A. Hussain, A. Begum, A. Rahman, 2012, Characterization of Nanocrystalline Lead Sulphide Thin Films Prepared by Chemical Bath Deposition Technique, King Fahd University of Petroleum and Minerals
  • [8] Y.B. Zhao, J.H. Zou, W.F. Shi, 2005, In situ synthesis and characterization of lead sulfide nanocrystallites in the modified hyperbranched polyester by gamma ray irradiation, Journal of Physical Chemistry B, 121,20, 1–2
  • [9] M. Takahashi, Y. Ohshima, K. Nagata, S. Furuta, 1993, Electrodeposition of PbS films from acidic solution. Journal of Electroanalytical Chemistry, 281, 359
  • [10]D. Kumar, G. Agarwal, B. Tripathi, D. Vyas, V. Kulshrestha, 2009, Characterization of PbS nanoparticles synthesized by chemical bath deposition. Journal of Alloys and Compounds, 484, 463–466
  • [11]L.F. Koao, F. B. Dejene and H.C. Swart, 2014, Synthesis of PbS Nanostructures by Chemical Bath Deposition Method, International journal of electrochemical science, 147, 85-89
  • [12]S. Lindross, T. Kanniainen, J. Ihanus, M. Leskela, 1996, ZnS thin films grown by SILAR on poly (vinyl chloride) and polycarbonate substrates, Journal of Materials Chemistry, 6, 1497–1500
  • [13]B. Thangaraju, P. Kaliannan, 2000, Spray pyrolytically deposited PbS thin films, Semiconductor Science and Technology, 15, 849– 853
  • [14]D.L. Partin, J. Heremans, T.S. Moss, S. Mahajan, 1994, Handbook on Semiconductors, Elsevier, 3, 369
  • [15]P. O’Brien and J. McAleese, 1998, Developing an understanding of the processes controlling the chemical bath deposition of ZnS and CdS, Journal of Materials Chemistry, 8, 2309-2314
  • [16]P.K. Nair, M.T.S Nair, 1989, Versatile solar control characteristics of chemically deposited PbS-CuxS thin film combinations, Semiconductor Science and Technology, 4, 807
  • [17]K.M. Gadave, S.A. Jodgudri, C.D. Lokhande, 1994, Chemical deposition of PbS from acidic bath, Thin Solid Films, 245, 7-9
  • [18]S. Bhushan, M.Mukharjee and P. Bose, 2002, Electro-optical studies in chemically deposited La/Nd doped (Cd-Pb) S films, Journal of Materials Science: Materials in Electronics,13, 581-584
  • [19]A. Hussain, A. Begum and A. Rahman, 2012, Electrical and optical properties of nanocrystalline lead sulphide thin films prepared by chemical bath deposition, 86, 8, 697–701
  • [20] J. P. Nair, R. Jayakrishnan, C. B. Nanduve, R. K. Pandley, 1998, In situ Sb-doped CdTe Films, Semicond. Science and Technology, 13(3), 340
  • [21] S. B. Park, S. W. Moon and I. S. Woo, 2000, Preparation and characterization of lead zirconate titanate thin flims, Thin Solid Films, 339, 77-81
  • [22] P. K. Manoj, K. G. Gopchandran, P. Koshy, V. K. Vaidyan and B. Josephc, 2006, Growth and characterization of indium oxide thin films prepared by spray pyrolysis, Optical Materials, 28(12), 1405- 1411
  • [23] M. Saleem, L. F. Liang, A. Wakeel, M. Rashad and C. Y. Kong, 2012, Simple preparation and characterization of nano-crystalline zinc oxide thin films by sol-gel method on glass substrate, World Journal of Condensed Matter Physics, 2, 10-15
  • [24]Cullity B.D., X-Işınlarının Difaksiyonu, Çeviren; Sümer A., İTÜ Fizik Profesörü, İstanbul Teknik Üniversite Matbaası Gümüşsuyu, (1966).
  • [25] A. Hussain, A. Begum, and A. Rahman, 2013, Characterization of Nanocrystalline Lead Sulphide Thin Films Prepared by Chemical Bath Deposition Technique, Arabian Journal for Science and Engineering, 38, 1, 169–174
  • [26] S. Rajathi, K. Kirubavathi, and K. Selvaraju, 2015, Structural, morphological, optical, and photoluminescence properties of nanocrystalline PbS thin films grown by chemical bath deposition, Arabian Journal of Chemistry
  • [27] A. N. Fouda, M. Marzook, H. M. Abd El-Khalek, S. Ahmed, E. A. Eid, A. B. El Basaty, 2017, Structural and Optical Characterization of Chemically Deposited PbS Thin Films, Silicon, 9, 6, 809–816
  • [28] A. Hussain, A. Begum, A. Rahman, 2013, Characterization of nanocrystalline lead sulphide thin films prepared by chemical bath deposition technique, Arabian Journal for Science and Engineering, 38, 169–174
  • [29] B. Altıokka, M. C. Baykul, M. R. Altıokka, 2013, Some physical effects of reaction rate on PbS thin films obtained by chemical bath deposition, Journal of Crystal Growth, 384, 50-54
There are 29 citations in total.

Details

Primary Language Turkish
Journal Section Research Article
Authors

Ayça Kıyak Yıldırım This is me

Barış Altıokka This is me

Publication Date March 1, 2018
Published in Issue Year 2018 Volume: 7 Issue: 1

Cite

IEEE A. K. Yıldırım and B. Altıokka, “Farklı molaritede Pb No3 2 çözeltisi kullanılarak kimyasal banyo depolaması yöntemi ile elde edilen Pbs filmlerin bazı fiziksel özellikleri”, DUFED, vol. 7, no. 1, pp. 42–49, 2018.


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