Year 2018, Volume , Issue 14, Pages 315 - 322 2018-12-31

Synthesis of Metal Complexes of Some Formazans Obtaining From Cinnamaldehyde and Investigation of Their Dyeing Properties Using Different Methods
Synthesis of Metal Complexes of Some Formazans Obtaining From Cinnamaldehyde and Investigation of Their Dyeing Properties Using Different Methods

Nursabah SARIKAVAKLI [1] , Fatma EROL [2]


In this study, two formazans were synthesized by coupling cinnamaldehyde phenyl hydrazone which was obtained by activation of cinnamaldehyde with phenylhydrazone, with diazonium salts of anthranilic acid and sulfonilic acid. The complexes of Co+2, Ni+2, Cu2+ salts of these formazans were also synthesized. These compounds were characterized by elemental analysis, infrared (IR), ultraviolet–visible (UV–vis),1H nuclear magnetic resonance (1H-NMR) and  13C-NMR spectra datas. Investigation of availability of these compounds as dyes were carried out for this purpose. In the present experimental approach, we applied two methods; The first one was direct dyeing with these complexes, and the other one was complex formation on the fibres. Finally, an investigation was carried out  for the fastness values (test) and it was found higher values, which was quite better and different from the other workers / researcher working in the same field.

In this study, two formazans were synthesized by coupling cinnamaldehyde phenyl hydrazone which was obtained by activation of cinnamaldehyde with phenylhydrazone, with diazonium salts of anthranilic acid and sulfonilic acid. The complexes of Co+2, Ni+2, Cu2+ salts of these formazans were also synthesized. These compounds were characterized by elemental analysis, infrared (IR), ultraviolet–visible (UV–vis),1H nuclear magnetic resonance (1H-NMR) and  13C-NMR spectra datas. Investigation of availability of these compounds as dyes were carried out for this purpose. In the present experimental approach, we applied two methods; The first one was direct dyeing with these complexes, and the other one was complex formation on the fibres. Finally, an investigation was carried out  for the fastness values (test) and it was found higher values, which was quite better and different from the other workers / researcher working in the same field.

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Primary Language en
Subjects Engineering
Journal Section Articles
Authors

Orcid: 0000-0002-9359-7672
Author: Nursabah SARIKAVAKLI (Primary Author)
Institution: Department of Chemistry, Faculty of Sciences, and Arts, Adnan Menderes University, 09010 Aytepe/Aydin, Turkey
Country: Turkey


Orcid: 0000-0002-4103-0148
Author: Fatma EROL
Institution: Gazi University, Technical Sciences Vocational School, 06374 Ostim/ Ankara, Turkey
Country: Turkey


Dates

Publication Date : December 31, 2018

APA Sarıkavaklı, N , Erol, F . (2018). Synthesis of Metal Complexes of Some Formazans Obtaining From Cinnamaldehyde and Investigation of Their Dyeing Properties Using Different Methods . Avrupa Bilim ve Teknoloji Dergisi , (14) , 315-322 . DOI: 10.31590/ejosat.442722