Synthesis of Metal Complexes of Some Formazans Obtaining From Cinnamaldehyde and Investigation of Their Dyeing Properties Using Different Methods

Year 2018, Issue: 14, 315 - 322, 31.12.2018

Nursabah Sarıkavaklı Fatma Erol

https://doi.org/10.31590/ejosat.442722

Abstract

In this study, two formazans were synthesized by coupling cinnamaldehyde phenyl hydrazone which was obtained by activation of cinnamaldehyde with phenylhydrazone, with diazonium salts of anthranilic acid and sulfonilic acid. The complexes of Co⁺², Ni⁺², Cu²⁺ salts of these formazans were also synthesized. These compounds were characterized by elemental analysis, infrared (IR), ultraviolet–visible (UV–vis),¹H nuclear magnetic resonance (¹H-NMR) and  ¹³C-NMR spectra datas. Investigation of availability of these compounds as dyes were carried out for this purpose. In the present experimental approach, we applied two methods; The first one was direct dyeing with these complexes, and the other one was complex formation on the fibres. Finally, an investigation was carried out  for the fastness values (test) and it was found higher values, which was quite better and different from the other workers / researcher working in the same field.

Keywords

Formazans, Metal complexes, Dyeing, Fastness properties, Polyamide fibres

Synthesis of Metal Complexes of Some Formazans Obtaining From Cinnamaldehyde and Investigation of Their Dyeing Properties Using Different Methods

Abstract

In this study,
two formazans were synthesized by coupling cinnamaldehyde phenyl hydrazone
which was obtained by activation of cinnamaldehyde with phenylhydrazone, with
diazonium salts of anthranilic acid and sulfonilic acid. The complexes of Co⁺²,
Ni⁺², Cu²⁺ salts of these formazans were also
synthesized. These compounds were characterized by elemental analysis, infrared
(IR), ultraviolet–visible (UV–vis),¹H nuclear magnetic resonance (¹H-NMR) and  ¹³C-NMR spectra datas. Investigation of availability of
these compounds as dyes were
carried out for this purpose. In the present experimental approach, we
applied two methods; The first one was direct dyeing with these complexes, and
the other one was complex formation on the fibres. Finally, an
investigation was carried out  for the fastness
values (test) and it was found higher values, which was quite better and
different from the other workers / researcher working in the same field.

Keywords

Formazans, Metal complexes, Dyeing, Fastness properties

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