Removal of Cu (II) from wastewater of metal coating process by borax sludge

Year 2018, Volume: 1 Issue: 4, 1 - 5, 01.12.2018

Esma Burcu Rona Meral Yildirim Ozen Emek Moroydor Derun

Abstract

The aim of this study is to
determine the adsorption behavior of borax sludge for removal of copper from
industrial wastewater. The borax sludge was generated during borax production
and used for treatment of wastewater of metal coating process. The parameters
of pH, concentration and contact time were investigated in batch experiments to
determine the efficiency of adsorption. Inductively Coupled Plasma-Optical
Emission Spectrometer (ICP-OES) was used to calculate the reduced amount of Cu
(II). The results were applied to various kinetic models and adsorption
isotherms. The pseudo second order model was successful to fit the adsorption
process in the kinetic study because the regression coefficient values (R²)
were changed between 0.9995 and 0.9978. Langmuir (R²=0.9985) and
Temkin (R²=0.9985) isotherms models were the best to explain the
process.

Keywords

Adsorption, borax sludge, heavy metal, waste water treatment

References

• [1]. F. Fu and Q. Wang, “Removal of heavy metal ions from wastewaters: a review,” Journal of Environmental Management, Vol. 92, pp. 407–418, 2011.
• [2]. H. D. Özsoy and H. Kumbur, “Endüstriyel atıksulardan adsorpsiyon yöntemi ile ağır metal gideriminde kullanılan çeşitli adsorbanlar ve giderim verimleri,” in Proc. Ulusal Çevre Sempozyumu, Mersin, Turkey, 2007 (In Turkish).
• [3]. D. Marani, G. Macci and M. Pagano, “Lead precipitation in the presence of sulfate and carbonate- testing of thermodynamic predictions,” Water Research, Vol. 29, pp. 1085-1092, 1995.
• [4]. M. P. Papini, Y. D. Kahie, B. Troia and M. Majone, “Adsorption of lead at variable pH onto a natural porous medium: modeling of batch and column experiments,” Environmental Science and Technology, Vol. 33, pp. 3357-4464, 1999.
• [5]. A. T. Paulino, F. A. Minasse, M. R. Guilherme, A. V. Reis, E. C. Muniz and J. Nozaki, “Novel adsorbent based on silkworm chrysalides for removal of heavy metals from wastewaters,” Journal of Colloid and Interface Science, Vol. 301, pp. 479–487, 2006.
• [6]. S. A. Mirbagheri and S. N. Hosseini, “Pilot plant investigation on petrochemical wastewater treatment for the removal of copper and chromium with the objective of reuse,” Desalination, Vol. 171, pp. 85–93, 2005.
• [7]. O. Hamdaoui, “Removal of copper (II) from aqueous phase by purolite C100-MB cation exchange resin in fixed bed columns: modeling,” Journal of Hazardous Materials, Vol. 161, pp. 737–746, 2009.
• [8]. F. Akbal and S. Camcı, “Copper, chromium and nickel removal from metal plating wastewater by electrocoagulation,” Desalination, Vol. 269, pp. 214–222, 2011.
• [9]. E. L. Cochrane, S. Lu, S. W. Gibb and I. Villaescusa, “A comparison of low-cost biosorbents and commercial sorbents for the removal of copper from aqueous media,” Journal of Hazardous Materials, Vol. 137, pp. 198-206, 2006.
• [10]. H. Sis and T. Uysal, “Removal of heavy metal ions from aqueous medium using Kuluncak (Malatya) vermiculites and effect of precipitation on removal,” Applied Clay Science, Vol. 95, pp. 1–8, 2014.
• [11]. M. Irani, M. Amjadi, M. A. Mousavian, “Comparative study of lead sorption onto natural perlite, dolomite and diatomite,” Chemical Engineering Journal, Vol. 178, pp. 317–323, 2011.
• [12]. K. G. Bhattacharyya and S. S. Gupta, “Removal of Cu(II) by natural and acid-activated clays: an insight of adsorption isotherm, kinetic and thermodynamics,” Desalination, Vol. 272, pp. 66–75, 2011.
• [13]. O. Yavuz, Y. Altunkaynak and F. Guzel, “Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite,” Water Research, Vol. 37, pp. 948–952, 2003.
• [14]. N. G. Turan, S. Elevli and B. Mesci, “Adsorption of copper and zinc ions on illite: Determination of the optimal conditions by the statistical design of experiments,” Applied Clay Science, Vol. 52, pp. 392–399, 2011.
• [15]. A. Sheikhhosseini, M. Shirvani and Shariatmadari, “Competitive sorption of nickel, cadmium, zinc and copper on palygorskite and sepiolite silicate clay minerals,” Geoderma, Vol. 192, pp. 249–253, 2013.
• [16]. A. B. Albadarin, J. Mo, Y. Glocheux, S. Allen, G. Walker and C. Mangwandi, “Preliminary investigation of mixed adsorbents for the removal of copper and methylene blue from aqueous solutions,” Chemical Engineering Journal, Vol. 255, pp. 525–534, 2014.
• [17]. Y. J. Lee, E. J. Elzinga and R.J. Reeder, “Cu(II) adsorption at the calcite–water interface in the presence of natural organic matter,” Geochimica et Cosmochimica Acta, Vol. 69, pp. 49–61, 2005.
• [18]. F. T. Senberber, M. Yıldırım, N. Karamahmut Mermer and E. Derun, “Adsorption of Cr(III) from aqueous solution using borax sludge,” Acta Chimica Slovenica, Vol. 64, pp. 654-660, 2017.
• [19]. A. Olgun and N. Atar, “Equilibrium and kinetic adsorption study of Basic Yellow 28 and Basic Red 46 by a boron industry waste,” Journal of Hazardous Materials, Vol. 161, pp. 148-156, 2009.
• [20]. N. Atar and A. Olgun and S. Wang, “Adsorption of copper (II) and zinc (II) on boron enrichment process waste in aqueous solutions: Batch and fixed-bed system studies,” Chemical Engineering Journal, Vol. 192, pp. 1–7, 2012.
• [21]. Y. S. Ho and G. McKay, “Pseudo-second order model for sorption processes,” Process Biochemistry, Vol. 34, pp. 451–465, 1999.
• [22]. I. Langmuir, “The adsorption of gases on plane surfaces of glass, mica and platinum,” Journal of the American Chemical Society, Vol. 40, pp. 1361–1403, 1918.
• [23]. R. Slimani, I. Ouahabi, A. Elmchaouri, B. Cagnon, S. Antri and S. Lazar, “Adsorption of copper (II) and zinc (II) onto calcined animal bone meal. Part I: Kinetic and thermodynamic parameters,” Chemical Data Collections, Vol. 9, pp. 184-196, 2017.