Characterization and dye adsorption effectiveness of activated carbon synthesized from olive pomace

Year 2022, Volume: 5 Issue: 4, 369 - 379, 31.12.2022

Fatma Deniz , Öyküm Başgöz Ömer Güler , Mehmet Ali Mazmancı

https://doi.org/10.35208/ert.1163939

Cited By: 2

Abstract

Studies, about products obtained from agricultural wastes, have increased within the scope of zero waste studies . The olive pomace is produced as a result of olive oil production. In the present study, activated carbon was synthesized using the olive pomace taken from the olive pomace processing plant operating with a three-phase process. The synthesized activated carbon characterization was performed using Scanning Electron Microscope (SEM), Fourier-Transform Infrared Spectroscopy (FT-IR), Brunauer – Emmett – Teller (BET), and X-Ray Crystallography (XRD) devices. Olive pomace activated carbon (OPAC) was used for the adsorption of dye from an aqueous solution. The adsorption efficiency of the OPAC was investigated. The initial pH value of dye solution (6-9), the amount of activated carbon (0.5 and 1.0 g/L), and initial dye concentration (600-1200 mg/L) were optimized. Also, adsorption kinetic and isotherm calculations were evaluated. The optimum parameters were found as the original pH value (pH=8) of dye solutions, OPAC amount of 1.0 g/L and the initial concentration of 1000 mg/L. The Langmuir isotherm model and the pseudo-second-order kinetic model were found as the most suitable models. It can be said that the synthesized material can be used at dye removing from wastewater.

Keywords

Activated carbon, adsorption, aqueous solution, dye removing, olive pomace

Supporting Institution

Cukurova Development Agency

Project Number

TR62/18/ÜRET/0036

Thanks

In this study, laboratory facilities in Mersin University Environmental Engineering Department funded by Cukurova Development Agency were used (TR62/18/ÜRET/0036). The authors would like to thank all those who supported and help them to conduct this research.

References

• [1] TC, Comparison of olive oil production processes, Republic of Turkey Ministry of Environment and Urbanization, Turkey, 2020.
• [2] TC, 2019 olive and olive oil report, Republic of Turkey Ministry of Trade, Turkey, 2020.
• [3] J. Saleem, U.B. Shahid, M. Hijab, H. Mackey, and G. McKay, "Production and applications of activated carbons as adsorbents from olive stones," Biomass Conversion and Biorefinery, pp. 1-28, 2019.
• [4] C. Fernández, M.S. Larrechi, and M.P. Callao, "An analytical overview of processes for removing organic dyes from wastewater effluents," TrAC Trends in Analytical Chemistry, 29, pp. 1202-1211, 2010.
• [5] S. Ahmed, S. Aktar, S. Zaman, R.A. Jahan, and M.L. Bari, "Use of natural bio-sorbent in removing dye, heavy metal and antibiotic-resistant bacteria from industrial wastewater," Applied Water Science, 10, pp. 1-10, 2020.
• [6] V. Selen and Ö. Güler, "Modeling of congo red adsorption onto multi-walled carbon nanotubes using response surface methodology: Kinetic, isotherm and thermodynamic studies," Arabian Journal for Science and Engineering, 46, pp. 6579-6592, 2021.
• [7] V.D. Pakhale and P.R. Gogate, "Removal of rhodamine 6g from industrial wastewater using combination approach of adsorption followed by sonication," Arabian Journal for Science and Engineering, 46, pp. 6473-6484, 2021.
• [8] M. Bahrami, M. Amiri, and F. Bagheri, "Optimization of crystal violet adsorption by chemically modified potato starch using response surface methodology," Pollution, 6, pp. 159-170, 2020.
• [9] M. Berrios, M.A. Martin, and A. Martin, "Treatment of pollutants in wastewater: Adsorption of methylene blue onto olive-based activated carbon," Journal of Industrial and Engineering Chemistry, 18, pp. 780-784, 2012.
• [10] T. Bohli, N. Fiol Santaló, I. Villaescusa Gil, and A. Ouederni, "Adsorption on activated carbon from olive stones: Kinetics and equilibrium of phenol removal from aqueous solution," Journal of Chemical Engineering and Process Technology, 4, pp. 165, 2013.
• [11] M. Uğurlu, A. Gürses, and M. Açıkyıldız, "Comparison of textile dyeing effluent adsorption on commercial activated carbon and activated carbon prepared from olive stone by zncl2 activation," Microporous and Mesoporous Materials, 111, pp. 228-235, 2008.
• [12] K. Mohanty, D. Das, and M. Biswas, "Adsorption of phenol from aqueous solutions using activated carbons prepared from tectona grandis sawdust by zncl2 activation," Chemical Engineering Journal, 115, pp. 121-131, 2005.
• [13] N. Hossain, M.A. Bhuiyan, B.K. Pramanik, S. Nizamuddin, and G. Griffin, "Waste materials for wastewater treatment and waste adsorbents for biofuel and cement supplement applications: A critical review," Journal of Cleaner Production, 255, pp. 120261, 2020.
• [14] J. Coates. Interpretation of infrared spectra, a practical approach, John Wiley & Sons, Inc., Newtown, USA, 2006.
• [15] R. Rotaru, P. Samoila, N. Lupu, M. Grigoras, and V. Harabagiu, "Ferromagnetic materials obtained through ultrasonication. 1. Maghemite/goethite nanocomposites," Revue Roumaine de Chimie, 2017, pp. 131-138, 2017.
• [16] S.M. Yakout and G. Sharaf El-Deen, "Characterization of activated carbon prepared by phosphoric acid activation of olive stones," Arabian Journal of Chemistry, 70, pp., 2011.
• [17] H. Arslanoglu, H. Altundogan, and F. Tumen, "Preparation of cation exchanger from lemon and sorption of divalent heavy metals," Bioresource technology, 99, pp. 2699-2705, 2008.
• [18] I.H. Aljundi and N. Jarrah, "A study of characteristics of activated carbon produced from jordanian olive cake," Journal of Analytical and Applied Pyrolysis, 81, pp. 33-36, 2008.
• [19] L.J. Kennedy, J.J. Vijaya, and G. Sekaran, "Effect of two-stage process on the preparation and characterization of porous carbon composite from rice husk by phosphoric acid activation," Industrial & engineering chemistry research, 43, pp. 1832-1838, 2004.
• [20] T.-H. Liou, "Development of mesoporous structure and high adsorption capacity of biomass-based activated carbon by phosphoric acid and zinc chloride activation," Chemical Engineering Journal, 158, pp. 129-142, 2010.
• [21] E.I. Ugwu and J.C. Agunwamba, "A review on the applicability of activated carbon derived from plant biomass in adsorption of chromium, copper, and zinc from industrial wastewater," Environmental Monitoring and Assessment, 192, pp. 1-12, 2020.
• [22] A. Maleki, A. Mahvi, R. Ebrahimi, and K. Jamil, "Evaluation of barley straw and its ash in removal of phenol from aqueous system," World Applied Sciences Journal, 8, pp. 369-373, 2010.
• [23] M. Bahrami, M.J. Amiri, and F. Bagheri, "Optimization of the lead removal from aqueous solution using two starch based adsorbents: Design of experiments using response surface methodology (rsm)," Journal of Environmental Chemical Engineering, 7, pp. 102793, 2019.
• [24] A. Pala, P. Galiatsatou, E. Tokat, H. Erkaya, C. Israilides, and D. Arapoglou, "The use of activated carbon from olive oil mill residue, for the removal of colour from textile wastewater," Eur. Water, 13, pp. 29-34, 2006.
• [25] G. Cimino, R. Cappello, C. Caristi, and G. Toscano, "Characterization of carbons from olive cake by sorption of wastewater pollutants," Chemosphere, 61, pp. 947-955, 2005.
• [26] A. Türkyılmaz and K. Işınkaralar, "Removal of antibiotics (tetracycline and penicillin g) from water solutions by adsorption on activated carbon," Journal of Engineering Sciences and Design, 8, pp. 943-951, 2020.
• [27] N. Soudani, S. Souissi-najar, and A. Ouederni, "Influence of nitric acid concentration on characteristics of olive stone based activated carbon," Chinese Journal of Chemical Engineering, 21, pp. 1425-1430, 2013.
• [28] I. Langmuir, "The adsorption of gases on plane surfaces of glass, mica and platinum," Journal of the American Chemical society, 40, pp. 1361-1403, 1918.
• [29] H. Freundlich, "Über die adsorption in lösungen," Zeitschrift für physikalische Chemie, 57, pp. 385-470, 1907.
• [30] N. Abdel-Ghani, E. Rawash, and G. El-Chaghaby, "Equilibrium and kinetic study for the adsorption of p-nitrophenol from wastewater using olive cake based activated carbon," Global Journal of Environmental Science and Management, 2, pp. 11, 2016.
• [31] J.-j. Gao, Y.-b. Qin, T. Zhou, D.-d. Cao, P. Xu, D. Hochstetter, and Y.-f. Wang, "Adsorption of methylene blue onto activated carbon produced from tea (camellia sinensis l.) seed shells: Kinetics, equilibrium, and thermodynamics studies," Journal of Zhejiang University Science B, 14, pp. 650-658, 2013.
• [32] G. Vijayakumar, R. Tamilarasan, and M. Dharmendirakumar, "Adsorption, kinetic, equilibrium and thermodynamic studies on the removal of basic dye rhodamine-b from aqueous solution by the use of natural adsorbent perlite," J. Mater. Environ. Sci, 3, pp. 157-170, 2012.
• [33] E. Musin, "Adsorption modelling," Environmental Engineering Thesis, Mikkeli University of Applied Sciences, Finland, 2013.
• [34] G. Stavropoulos and A. Zabaniotou, "Production and characterization of activated carbons from olive-seed waste residue," Microporous and Mesoporous Materials, 82, pp. 79-85, 2005.
• [35] W.K. Lafi, "Production of activated carbon from acorns and olive seeds," Biomass and Bioenergy, 20, pp. 57-62, 2001.
• [36] A. Baçaoui, A. Yaacoubi, A. Dahbi, C. Bennouna, R.P.T. Luu, F. Maldonado-Hodar, J. Rivera-Utrilla, and C. Moreno-Castilla, "Optimization of conditions for the preparation of activated carbons from olive-waste cakes," Carbon, 39, pp. 425-432, 2001.
• [37] S. Lagergren, "Zur theorie der sogenannten adsorption geloster stoffe, kungliga svenska vetenskapsakademiens," Handlingar, 24, pp. 1-39, 1898.
• [38] S. Deng, R. Ma, Q. Yu, J. Huang, and G. Yu, "Enhanced removal of pentachlorophenol and 2, 4-d from aqueous solution by an aminated biosorbent," Journal of hazardous materials, 165, pp. 408-414, 2009.
• [39] W.J. Weber and J.C. Morris, "Kinetics of adsorption on carbon from solution," Journal of the sanitary engineering division, 89, pp. 31-60, 1963.
• [40] T.A. Saleh, M.N. Siddiqui, and A.A. Al-Arfaj, "Kinetic and intraparticle diffusion studies of carbon nanotubes-titania for desulfurization of fuels," Petroleum Science and Technology, 34, pp. 1468-1474, 2016.
• [41] O. Keskinkan, M.Z.L. Goksu, A. Yuceer, M. Başibüyük, and C.F. Forster, "Heavy metal adsorption characteristics of a submerged aquatic plant (myriophyllum spicatum)," Process Biochemistry, 39, pp. 179-183, 2003.
• [42] P. Waranusantigul, P. Pokethitiyook, M. Kruatrachue, and E. Upatham, "Kinetics of basic dye (methylene blue) biosorption by giant duckweed (spirodela polyrrhiza)," Environmental pollution, 125, pp. 385-392, 2003.
• [43] P. Ramachandran, R. Vairamuthu, and S. Ponnusamy, "Adsorption isotherms, kinetics, thermodynamics and desorption studies of reactive orange 16 on activated carbon derived from ananas comosus (l.) carbon," Journal of Engineering and Applied Sciences, 6, pp. 15-26, 2011.