Araştırma Makalesi
Epoksi Reçine-MgO Polimer Matrisli Kompozit Malzemelerin Üretilmesi ve Pin On Disk Abrasiv Aşınma Özelliklerinin İncelenmesi
Öz
Bu
çalışmada; epoksi
reçine içerisine farklı oranlarda MgO (1/1.5, 1/2.0 ve 1/2.5 oranında
Epoksi/MgO) ilave edilerek kompozit malzemeler üretilmiştir. Hacimsel olarak karıştırılan bütün kompozit malzemeler
plastik kalıplara dökülerek oda sıcaklığında 24 saat kurutulmaya bırakılmıştır.
Farklı kompozisyonlarda üretilen kompozit malzemelerin aşınmaya karşı
davranışlarını belirlemek amacıyla pin on disk kuru aşınma testi yapılmıştır.
Farklı yüklerde yapılan (10-30N) aşınma testleri sonucu MgO bileşiğinin epoksi
malzemenin aşınma özellikleri üzerine etkileri incelenmiştir. Farklı oranlarda
MgO ilave edilerek üretilen kompozit malzemeler ile takviyesiz epoksinin aşınma
sonuçları kıyaslandığında, en iyi sonucun 2.5/1 oranında MgO/Epoksi içerikli
kompozit malzemeden elde edildiği gözlenmiştir. Ayrıca kompozit malzemelerin
takviyesiz epoksiye göre daha iyi sonuç verdiği ve genel olarak MgO miktarı arttıkça
sürtünme katsayısı değerlerinin düştüğü tespit edilmiştir. Farklı yüklerde
yapılan (10-30N) aşınma testi sonucu, aşınma yükü arttıkça bütün malzemelerde
sürtünme katsayısının düştüğü gözlenmiştir. Aşınma sırasında aşındırıcı pimin
kompozit malzemeye temas ettiği yerdeki sıcaklık değerlerine bakıldığında ise
aşınma yükü arttığında aşındırıcı pim ve malzemeler arasındaki sürtünme arttığı
için sıcaklığın yükseldiği belirlenmiştir.
Anahtar Kelimeler
Kaynakça
- [1] Rout A, Satapathy A. Analysis of dry sliding wear behaviour of rice husk filledepoxy composites using design of experiment and NN. Procedia Engineering 2012; 38: 1218-1232. [2] Zum Gahr KH. Microstracture and Wear of Materials. Elsevier 1987; Amsterdam. [3] Bahadur S, Zheng Y. Mechanical and tribological behaviour of polyester reinforced with short glass fibers, Wear 1990; 137, 251-266. [4] Xing XS, Li RKY. Wear behavior of epoxy matrix composites filled with uniform sized sub-micron spherical silica particles, Wear 2004; 256(1-2): 21-26. [5] Pul M, Çalın R, Çıtak R Şeker U. Düşük takviyeli MgO-Al kompozitlerin vakumlu infiltrasyonunda takviye oranının infiltrasyon davranışına etkisi. Politeknik Dergisi 2009; 12- 3: 173-177. [6] Dhandapanı SP, Jayaram V, Surappa MK. Growth and microstructure of Al2O3-SiC-Si(Al) composites prepared byre active infiltration of silicon carbide preforms, Acta Met. Ma 1994; 42: 649-656. [7] Ateş E, Aztekin K. Parçacık ve fiber takviyeli polimer kompozitlerin yoğunluk ve basma dayanımı özellikleri, J Fac Eng Arch Gazi Univ 2011; 26(2): 479-486. [8] Deveci H. Mechanical and thermal properties of a novel composite prepared with epoxy resin and lateritic ore. Polymer Composites 2013; 34 (8), 1375-1381. [9] Zhang J, Qi S. Mechanical, thermal, and dielectric properties of aluminum nitride/glass fiber/epoxy resin composites, Polymer Composites 2014; 35 (2): 381- 385. [10] Mavani, SI, Mehta NM, Parsania PH. Synthesis, fabrication, mechanical, electrical, and moisture absorption study of epoxy polyurethane–jute and epoxy polyurethane–jute–rice/wheat husk composites, Journal of Applied Polymer Science 2007; 106 (2): 1228-1233. [11] Soroush A, Rezaie Haghighat H, Sajadinia SH. Thermal and mechanical properties of polysulfide/epoxy copolymer system: the effect of anhydride content, Polymers for Advanced Technologies 2014; 25 (2): 184-190. [12] Zhou Y, Feng J, Peng H, Qu H, Hao J. Catalytic pyrolysis and flame retardancy of epoxy resins with solid acid boron phosphate, Polymer Degradation and Stability 2014; 110: 395-404. [13] Li X, Kang H, Shen J, Zhang L, Nishi T. Ito K. Miscibility, intramolecular specific interactions and mechanical properties of a DGEBA based epoxy resin toughened with a sliding graft copolymer, Chinese Journal of Polymer Science 2015; 33 (3): 433-443. [14] Xue Y, Jin X, Fan Y, Tian R, Xu X, Li J, Lin J, Zhang J, Hu L, Tang C. Large-scale synthesis of hexagonal boron nitride nanosheets and their improvement in thermal properties of epoxy composites. Polymer Composites 2014; 35 (9): 1707-1715. [15] Li X, Ni C, Ma F, Yao B, Zhu C. Preparation of poly(N-butyl acrylate-coglycidyl methacrylate) and its application in enhancement of epoxy resin. Polymer-Plastics Technology and Engineering 2014; 53 (3): 262-267. [16] Ding G, Fu J, Dong X, Chen L, Jia H, Wenqi Y, Shi L. Preparation and properties of polyhedral oligomeric silsesquioxane/epoxy hybrid resins. Polymer Composites 2013; 34: 1753-1760. [17] Ma A, Wu Y, Chen W, Wu X. Preparation and properties of multi-walled carbon nanotubes/carbon fiber/epoxy composites. Polymer Composites 2014; 35 (11): 2150-2153. [18] Devaraju S, Vengatesan MR, Selvi M, Song JK, Alagar M. Hyperbranched polysiloxane-based diglycidyl ether of bisphenol a epoxy composite for low k dielectric application. Polymer Composites 2013; 34 (6): 904-911. [19] Zotti A, Borriello A, Martone A, Antonucci V, Giordano M, Zarrelli M. .Effect of sepiolite filler on mechanical behaviour of a bisphenol A-based epoxy system. Composites Part B: Engineering 2014; 67: 400-409. [20] Yekani Fard M, Raji B, Chattopadhyay A. The ratio of flexural strength to uniaxial tensile strength in bulk epoxy resin polymeric materials. Polymer Testing 2014; 40: 156-162. [21] Ibtihal A, Ahmed A and Manal F. Study the Mechanical Properties of Epoxy Resin Reinforced With silica (quartz) and Alumina Particles. The Iraqi Journal For Mechanical and Material Engineering 2011; 3(11): 486-505. [22] Visconti IC, Langella A, Durante M. The wear behaviour of composite materials with epoxy matrix filled with hard powder. Appl Comp Mater 2001; 8: 179-189. [23] Rong MZ, Zhang MQ, Liu HM. ZengMicrostructure and tribological behavior of polymeric nanocomposites. Ind Lubric Tribol 2001; 53 (2): 72-77. [24] Solmaz MY, Kelestemur MH. Wear behavior of boron-doped Ni3Al material at elevated temperature. 2004; Wear 257(9-10):1015-1021 [25] Shi G, Zhang MQ, Rong MZ, Wetzel B, Friedrich K. Friction and wear of low nanometer Si3N4 filled epoxy composites. Wear 2003; 254: 784–796. [26] Al-Rawi K R, Abd-Ulwahid MZ. Wear and mechanical properties of epoxy/MgO-SiO2 hybrid nanocomposites. Iraqi Journal of Physics 2015; 13-26: 58-63. [27] Unal H, Sen U, Mimaroglu A. Abrasive Wear Behavior of Polymeric Materials. Materials and Design 2005; 26: 705–710. [28] Solmaz MY, Muratoğlu M, Eroğlu M. Al2O3 Partikülleriyle takviyelendirilmiş polyester matrisli kompozitin abrasiv aşınma davranişinin incelenmesi, 6th International Advanced Technologies Symposium (IATS’11), 16-18 May 2011, Elazığ, Turkey.
Yıl 2019,
Cilt: 31 Sayı: 1, 1 - 10, 15.03.2019
Öz
Kaynakça
- [1] Rout A, Satapathy A. Analysis of dry sliding wear behaviour of rice husk filledepoxy composites using design of experiment and NN. Procedia Engineering 2012; 38: 1218-1232. [2] Zum Gahr KH. Microstracture and Wear of Materials. Elsevier 1987; Amsterdam. [3] Bahadur S, Zheng Y. Mechanical and tribological behaviour of polyester reinforced with short glass fibers, Wear 1990; 137, 251-266. [4] Xing XS, Li RKY. Wear behavior of epoxy matrix composites filled with uniform sized sub-micron spherical silica particles, Wear 2004; 256(1-2): 21-26. [5] Pul M, Çalın R, Çıtak R Şeker U. Düşük takviyeli MgO-Al kompozitlerin vakumlu infiltrasyonunda takviye oranının infiltrasyon davranışına etkisi. Politeknik Dergisi 2009; 12- 3: 173-177. [6] Dhandapanı SP, Jayaram V, Surappa MK. Growth and microstructure of Al2O3-SiC-Si(Al) composites prepared byre active infiltration of silicon carbide preforms, Acta Met. Ma 1994; 42: 649-656. [7] Ateş E, Aztekin K. Parçacık ve fiber takviyeli polimer kompozitlerin yoğunluk ve basma dayanımı özellikleri, J Fac Eng Arch Gazi Univ 2011; 26(2): 479-486. [8] Deveci H. Mechanical and thermal properties of a novel composite prepared with epoxy resin and lateritic ore. Polymer Composites 2013; 34 (8), 1375-1381. [9] Zhang J, Qi S. Mechanical, thermal, and dielectric properties of aluminum nitride/glass fiber/epoxy resin composites, Polymer Composites 2014; 35 (2): 381- 385. [10] Mavani, SI, Mehta NM, Parsania PH. Synthesis, fabrication, mechanical, electrical, and moisture absorption study of epoxy polyurethane–jute and epoxy polyurethane–jute–rice/wheat husk composites, Journal of Applied Polymer Science 2007; 106 (2): 1228-1233. [11] Soroush A, Rezaie Haghighat H, Sajadinia SH. Thermal and mechanical properties of polysulfide/epoxy copolymer system: the effect of anhydride content, Polymers for Advanced Technologies 2014; 25 (2): 184-190. [12] Zhou Y, Feng J, Peng H, Qu H, Hao J. Catalytic pyrolysis and flame retardancy of epoxy resins with solid acid boron phosphate, Polymer Degradation and Stability 2014; 110: 395-404. [13] Li X, Kang H, Shen J, Zhang L, Nishi T. Ito K. Miscibility, intramolecular specific interactions and mechanical properties of a DGEBA based epoxy resin toughened with a sliding graft copolymer, Chinese Journal of Polymer Science 2015; 33 (3): 433-443. [14] Xue Y, Jin X, Fan Y, Tian R, Xu X, Li J, Lin J, Zhang J, Hu L, Tang C. Large-scale synthesis of hexagonal boron nitride nanosheets and their improvement in thermal properties of epoxy composites. Polymer Composites 2014; 35 (9): 1707-1715. [15] Li X, Ni C, Ma F, Yao B, Zhu C. Preparation of poly(N-butyl acrylate-coglycidyl methacrylate) and its application in enhancement of epoxy resin. Polymer-Plastics Technology and Engineering 2014; 53 (3): 262-267. [16] Ding G, Fu J, Dong X, Chen L, Jia H, Wenqi Y, Shi L. Preparation and properties of polyhedral oligomeric silsesquioxane/epoxy hybrid resins. Polymer Composites 2013; 34: 1753-1760. [17] Ma A, Wu Y, Chen W, Wu X. Preparation and properties of multi-walled carbon nanotubes/carbon fiber/epoxy composites. Polymer Composites 2014; 35 (11): 2150-2153. [18] Devaraju S, Vengatesan MR, Selvi M, Song JK, Alagar M. Hyperbranched polysiloxane-based diglycidyl ether of bisphenol a epoxy composite for low k dielectric application. Polymer Composites 2013; 34 (6): 904-911. [19] Zotti A, Borriello A, Martone A, Antonucci V, Giordano M, Zarrelli M. .Effect of sepiolite filler on mechanical behaviour of a bisphenol A-based epoxy system. Composites Part B: Engineering 2014; 67: 400-409. [20] Yekani Fard M, Raji B, Chattopadhyay A. The ratio of flexural strength to uniaxial tensile strength in bulk epoxy resin polymeric materials. Polymer Testing 2014; 40: 156-162. [21] Ibtihal A, Ahmed A and Manal F. Study the Mechanical Properties of Epoxy Resin Reinforced With silica (quartz) and Alumina Particles. The Iraqi Journal For Mechanical and Material Engineering 2011; 3(11): 486-505. [22] Visconti IC, Langella A, Durante M. The wear behaviour of composite materials with epoxy matrix filled with hard powder. Appl Comp Mater 2001; 8: 179-189. [23] Rong MZ, Zhang MQ, Liu HM. ZengMicrostructure and tribological behavior of polymeric nanocomposites. Ind Lubric Tribol 2001; 53 (2): 72-77. [24] Solmaz MY, Kelestemur MH. Wear behavior of boron-doped Ni3Al material at elevated temperature. 2004; Wear 257(9-10):1015-1021 [25] Shi G, Zhang MQ, Rong MZ, Wetzel B, Friedrich K. Friction and wear of low nanometer Si3N4 filled epoxy composites. Wear 2003; 254: 784–796. [26] Al-Rawi K R, Abd-Ulwahid MZ. Wear and mechanical properties of epoxy/MgO-SiO2 hybrid nanocomposites. Iraqi Journal of Physics 2015; 13-26: 58-63. [27] Unal H, Sen U, Mimaroglu A. Abrasive Wear Behavior of Polymeric Materials. Materials and Design 2005; 26: 705–710. [28] Solmaz MY, Muratoğlu M, Eroğlu M. Al2O3 Partikülleriyle takviyelendirilmiş polyester matrisli kompozitin abrasiv aşınma davranişinin incelenmesi, 6th International Advanced Technologies Symposium (IATS’11), 16-18 May 2011, Elazığ, Turkey.
Toplam 1 adet kaynakça vardır.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Bölüm | MBD |
| Yazarlar | |
| Yayımlanma Tarihi | 15 Mart 2019 |
| Gönderilme Tarihi | 23 Eylül 2017 |
| Yayımlandığı Sayı | Yıl 2019 Cilt: 31 Sayı: 1 |
