BibTex RIS Cite

Effect of a New Schiff Base on the Corrosion and Dezincification of Brass in 1 M HCl

Year 2010, Volume: 23 Issue: 3, 287 - 293, 06.07.2010

Abstract

ABSTRACT

In this study the effect of a new synthetic Schiff base namely bis -(2-hydroxy-3-methoxy)-1,6-diaminohexane salicylaldimine on the corrosion and dezincification of a 70/30 brass in 1M HCl has been studied using weight loss , electrochemical (polarization & impedance) and solution analysis techniques. Results obtained revealed that this compound is very good inhibitor and behaves as mixed type of inhibitor for brass 70/30 in this acid medium. Solution analysis and surface composition (weight%) of the alloy in the presence and absence of inhibitor by atomic absorption spectroscopy (AAS) and energy dispersive X-Ray analysis (EDAX) revealed the decrease in dissolution of both Cu and Zn in the presence of this inhibitor. The dezincification factor (Z) was calculated by using analysis solution.

 

 

Key Words: Inhibitor, polarization, impedance, dezincification,

corrosion.

References

  • Karpagavalli, R., of brasses resist “Development dezincification”, Corrosion Science, 49: 963-979 (2007). to
  • Larabi, L., Harek, Y., Traisnel, M., Mansri, A., “Synergistic influence of poly(4-vinylpyridine) and potassium iodide on inhibition of corrosion mild steel in 1M HCl”, J. of Applied Electrochemistry, 34: 833-839 (2004)
  • Agmal, M., Mideen, A.S., Qurasihi, M.A., “2- hydrazino-6-methyl-benzothiazole as an effective inhibitor for the corrosion of mild steel in acidic solutions”, Corrosion Science, 36: 79 (1994).
  • Ei-Taib Heakal, F., Haruyama, S., “Impedance studies of the inhibitive effect of benzotriazole on the corrosion of copper in sodium chloride medium”, Corros. Sci., 20: 887 (1980).
  • Meticos-Hukovic, M., Grubac, Z., Stupnisk-Lisac, E., “Organic corrosion inhibitors for aluminum in perchloric acid”, Corros., 50: 2 (1994).
  • Upec, U., Iboc, U., Ita, B., Offiong, O., Ebenso, E., “Inhibitory thiosemicarbazone derivatives on the corrosion of mild steel in hydrochloric acid”, Mater.Chem. Phys., 40: 87 (1995). methyl and phenyl
  • Tadros, A.B., Abd-El-Nabey, A.B., “Inhibition of the acid corrosion of steel by 4-amino-3-hydrazino- 5-thio-1, 2, 4-triazoles ”, J. Electroanal.Chem., 24: 433 (1988).
  • Aouniti, A., Hammouti, B., Brighli, M., Kertit, S., Berhili, F., El Kadiri, S., Ramdani, A., “Inhibition of the acid corrosion of iron with new pyrazole derivatives”, J. Chim. Phys., 93: 1262 (1996).
  • Kertit, S., Hammouti, B., “Corrosion inhibition of iron in 1M HCl by 1-phenyl-5-mercapto-1, 2, 3, 4- tetrazole”, Appl. Surf.. Sci., 93: 59 (1996).
  • Bouayed, M., Rabaa, H., Srhiri, A., Saillard, J.Y., Ben Bachir, A., Le Beuze, A., “Experimental and theoretical study of organic corrosion inhibitors on iron in acidic medium”, Corros. Sci., 41:501 (1999).
  • Cheng, X.L., Ma, H.Y., Chen, S.H., Yu, R., Chen, X., Yao, Z.M.,“Corrosion of stainless steels in acid solutions compounds”, Corros. Sci., 41: 321 (1999). sulfur-containing
  • Raicheva, S.N., Aleksiev, B.V., Sokolova, E.I., “The effect of the chemical structure of some nitrogen- and sulphur-containing organic compounds on their corrosion inhibiting action”, Corros. Sci., 34: 343 (1993).
  • Schweinsberg, D.P., Ashworth,V., “The inhibition of the corrosion of pure iron in 0.5 M sulphuric acid by n-alkyl quaternary ammonium iodides”, Corros. Sci., 28: 539 (1988).
  • Agrawal, Y.K., Talati, J.D., Shah, M.D., Desai, M. N., Shah, N.K., “Schiff bases of ethylenediamine as corrosion inhibitors of zinc in sulphuric acid”, Corros. Sci., 46: 633 (2004).
  • ASTM, “Standard practice for laboratory immersion corrosion testing of metals”, G31-72, ASTM, 401 (1990).
  • Bentiss, F., Traisnel, M., Lagrenee, M., “The substituted 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media”, Corros .Sci., 42: 127 (2000).
  • Hosseini, M., Mertens, S.F.L., Chorbani, M.C., Arshadi, M.R., “Asymmetrical schiff bases as inhibitors of mild steel corrosion in sulphuric acid media“, Materials Chemistry and Physics., 9647:1- 9 (2002).
  • Bentiss, F., Traisnel, M., Lagrene. M., “The substituted 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media”, Corros .Sci ., 42: 127 (2000).
  • Quan, Z., Chen, S., Li, Y., Cui, X.,“Adsorption behaviour of Schiff base and corrosion protection of resulting films to copper substrate”, Corrs.Sci.,44: 703 (2002).
  • Ravichandran, R., Nanjundan, S., Rajendran, N., “Effect of benzotriazole on the corrosion of brass in NaCl solutions”, Applied Surface Science, 236: 241-250 (2004).
  • Van Ooij, W.J., “ Surface composition, oxidation and sulfidation of cold-worked brass and brass- coated steel wire as studied by x-ray photoelectron spectroscopy I. Surface composition of commercial cold-worked brass”, Surface Technology, 6(1):1-18 (1977).
  • Ravichandran, R., Rajendran, N., “Influence of benzotriazole derivatives on the dezicification of 65- 35 brass in sodium chloride”, Applied Surface Science, 239: 182-192 (2005).
  • Emregul, K.C., Kurtaran, R., Atakol, O., “An investigation of chloride-substituted Schiff bases as corrosion inhibitors for steel”, Corrosion Science, 45: 2803-2817 (2003).
Year 2010, Volume: 23 Issue: 3, 287 - 293, 06.07.2010

Abstract

References

  • Karpagavalli, R., of brasses resist “Development dezincification”, Corrosion Science, 49: 963-979 (2007). to
  • Larabi, L., Harek, Y., Traisnel, M., Mansri, A., “Synergistic influence of poly(4-vinylpyridine) and potassium iodide on inhibition of corrosion mild steel in 1M HCl”, J. of Applied Electrochemistry, 34: 833-839 (2004)
  • Agmal, M., Mideen, A.S., Qurasihi, M.A., “2- hydrazino-6-methyl-benzothiazole as an effective inhibitor for the corrosion of mild steel in acidic solutions”, Corrosion Science, 36: 79 (1994).
  • Ei-Taib Heakal, F., Haruyama, S., “Impedance studies of the inhibitive effect of benzotriazole on the corrosion of copper in sodium chloride medium”, Corros. Sci., 20: 887 (1980).
  • Meticos-Hukovic, M., Grubac, Z., Stupnisk-Lisac, E., “Organic corrosion inhibitors for aluminum in perchloric acid”, Corros., 50: 2 (1994).
  • Upec, U., Iboc, U., Ita, B., Offiong, O., Ebenso, E., “Inhibitory thiosemicarbazone derivatives on the corrosion of mild steel in hydrochloric acid”, Mater.Chem. Phys., 40: 87 (1995). methyl and phenyl
  • Tadros, A.B., Abd-El-Nabey, A.B., “Inhibition of the acid corrosion of steel by 4-amino-3-hydrazino- 5-thio-1, 2, 4-triazoles ”, J. Electroanal.Chem., 24: 433 (1988).
  • Aouniti, A., Hammouti, B., Brighli, M., Kertit, S., Berhili, F., El Kadiri, S., Ramdani, A., “Inhibition of the acid corrosion of iron with new pyrazole derivatives”, J. Chim. Phys., 93: 1262 (1996).
  • Kertit, S., Hammouti, B., “Corrosion inhibition of iron in 1M HCl by 1-phenyl-5-mercapto-1, 2, 3, 4- tetrazole”, Appl. Surf.. Sci., 93: 59 (1996).
  • Bouayed, M., Rabaa, H., Srhiri, A., Saillard, J.Y., Ben Bachir, A., Le Beuze, A., “Experimental and theoretical study of organic corrosion inhibitors on iron in acidic medium”, Corros. Sci., 41:501 (1999).
  • Cheng, X.L., Ma, H.Y., Chen, S.H., Yu, R., Chen, X., Yao, Z.M.,“Corrosion of stainless steels in acid solutions compounds”, Corros. Sci., 41: 321 (1999). sulfur-containing
  • Raicheva, S.N., Aleksiev, B.V., Sokolova, E.I., “The effect of the chemical structure of some nitrogen- and sulphur-containing organic compounds on their corrosion inhibiting action”, Corros. Sci., 34: 343 (1993).
  • Schweinsberg, D.P., Ashworth,V., “The inhibition of the corrosion of pure iron in 0.5 M sulphuric acid by n-alkyl quaternary ammonium iodides”, Corros. Sci., 28: 539 (1988).
  • Agrawal, Y.K., Talati, J.D., Shah, M.D., Desai, M. N., Shah, N.K., “Schiff bases of ethylenediamine as corrosion inhibitors of zinc in sulphuric acid”, Corros. Sci., 46: 633 (2004).
  • ASTM, “Standard practice for laboratory immersion corrosion testing of metals”, G31-72, ASTM, 401 (1990).
  • Bentiss, F., Traisnel, M., Lagrenee, M., “The substituted 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media”, Corros .Sci., 42: 127 (2000).
  • Hosseini, M., Mertens, S.F.L., Chorbani, M.C., Arshadi, M.R., “Asymmetrical schiff bases as inhibitors of mild steel corrosion in sulphuric acid media“, Materials Chemistry and Physics., 9647:1- 9 (2002).
  • Bentiss, F., Traisnel, M., Lagrene. M., “The substituted 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media”, Corros .Sci ., 42: 127 (2000).
  • Quan, Z., Chen, S., Li, Y., Cui, X.,“Adsorption behaviour of Schiff base and corrosion protection of resulting films to copper substrate”, Corrs.Sci.,44: 703 (2002).
  • Ravichandran, R., Nanjundan, S., Rajendran, N., “Effect of benzotriazole on the corrosion of brass in NaCl solutions”, Applied Surface Science, 236: 241-250 (2004).
  • Van Ooij, W.J., “ Surface composition, oxidation and sulfidation of cold-worked brass and brass- coated steel wire as studied by x-ray photoelectron spectroscopy I. Surface composition of commercial cold-worked brass”, Surface Technology, 6(1):1-18 (1977).
  • Ravichandran, R., Rajendran, N., “Influence of benzotriazole derivatives on the dezicification of 65- 35 brass in sodium chloride”, Applied Surface Science, 239: 182-192 (2005).
  • Emregul, K.C., Kurtaran, R., Atakol, O., “An investigation of chloride-substituted Schiff bases as corrosion inhibitors for steel”, Corrosion Science, 45: 2803-2817 (2003).
There are 23 citations in total.

Details

Primary Language English
Journal Section Chemical Engineering
Authors

Athare Dadgarınezhad This is me

Fatemeh Baghaeı This is me

Publication Date July 6, 2010
Published in Issue Year 2010 Volume: 23 Issue: 3

Cite

APA Dadgarınezhad, A., & Baghaeı, F. (2010). Effect of a New Schiff Base on the Corrosion and Dezincification of Brass in 1 M HCl. Gazi University Journal of Science, 23(3), 287-293.
AMA Dadgarınezhad A, Baghaeı F. Effect of a New Schiff Base on the Corrosion and Dezincification of Brass in 1 M HCl. Gazi University Journal of Science. September 2010;23(3):287-293.
Chicago Dadgarınezhad, Athare, and Fatemeh Baghaeı. “Effect of a New Schiff Base on the Corrosion and Dezincification of Brass in 1 M HCl”. Gazi University Journal of Science 23, no. 3 (September 2010): 287-93.
EndNote Dadgarınezhad A, Baghaeı F (September 1, 2010) Effect of a New Schiff Base on the Corrosion and Dezincification of Brass in 1 M HCl. Gazi University Journal of Science 23 3 287–293.
IEEE A. Dadgarınezhad and F. Baghaeı, “Effect of a New Schiff Base on the Corrosion and Dezincification of Brass in 1 M HCl”, Gazi University Journal of Science, vol. 23, no. 3, pp. 287–293, 2010.
ISNAD Dadgarınezhad, Athare - Baghaeı, Fatemeh. “Effect of a New Schiff Base on the Corrosion and Dezincification of Brass in 1 M HCl”. Gazi University Journal of Science 23/3 (September 2010), 287-293.
JAMA Dadgarınezhad A, Baghaeı F. Effect of a New Schiff Base on the Corrosion and Dezincification of Brass in 1 M HCl. Gazi University Journal of Science. 2010;23:287–293.
MLA Dadgarınezhad, Athare and Fatemeh Baghaeı. “Effect of a New Schiff Base on the Corrosion and Dezincification of Brass in 1 M HCl”. Gazi University Journal of Science, vol. 23, no. 3, 2010, pp. 287-93.
Vancouver Dadgarınezhad A, Baghaeı F. Effect of a New Schiff Base on the Corrosion and Dezincification of Brass in 1 M HCl. Gazi University Journal of Science. 2010;23(3):287-93.