Research Article
BibTex RIS Cite

Vibrational Spectroscopic Study on the Hofmann-Td-type 1,4-Dioxane Clathrates

Year 2019, Volume: 47 Issue: 1, 99 - 106, 01.02.2019

Abstract

Two new 1,4-dioxane-Td-type clathrates of the form Cd(CPA)2M(CN)4.2C4H8O2 (CPA= cyclopentylamine; M = Cd or Hg) have been prepared in powder form and their FT-IR (400-4000 cm-1), FT-Raman (70-4000 cm-1), far-IR (50-400 cm-1) spectra, X-ray diffraction (XRD) and elemental analyses are reported. The spectral data suggest that the host frameworks of these compounds are similar to those of the Hofmann-Td-type benzene clathrates.

References

  • 1. H. Yuge, T. Iwamoto, Different coordination behaviour of 1,2-diaminoethane (en) and tetracyanonickelate(II) upon accommodation of polar guest molecules in their metalcomplex hosts crystal-structures of [M(en)2Ni(CN)4].2phNH2 (M= Ni, Cu, Zn or Cd) and [Cd(en)2(en)(Ni(CN)4)2].4phOH, J. Incl. Phenom., 14 (1992) 217-235.
  • 2. R. Kuroda, A new type clathrate compound: the crystal structure of Cd(NH3)2Hg(CN)4.2C6H6, Inorg. Nucl. Chem. Lett., 9 (1973) 13-17.
  • 3. T. Iwamoto, Past, present and future of the clathrate inclusion compounds built of cyanometallate hosts, J. Incl. Phenom., 24 (1996) 61-132.
  • 4. Z. Kantarcı, C. Bayrak, Infrared spectroscopic and gravimetric studies on the cyclopentylaminemetal(II) tetracyanonickellate (II) host-aromatic guest systems, J. Incl. Phenom., 45 (2003) 59-67.
  • 5. E. Kasap, Z. Kantarcı, Vibrational spectroscopic studies on the Hofmann-Td-type clathrates: M(ethylenediamine) M(CN)4.2C6H6 (M= Mn or Cd, M= Cd or Hg), J. Incl. Phenom., 20 (1995) 33-44.
  • 6. V.F. Kalasinsky, T.S. Little, Vibrational spectra and structure of cyclopentylamine, J. Raman Spectrosc. 9 (1980) 224-229.
  • 7. S. Akyüz, J.E.D. Davies, Solid-state vibrational spectroscopy: Part 11. An infrared and raman vibrational spectroscopic study of metal(II) halide aniline complexes, J. Mol. Struct., 95 (1982) 157-168.
  • 8. D.A. Thornton, Metal complexes of aniline: Infrared and Raman spectra, J. Coord. Chem., 24 (1991) 261-289.
  • 9. Z. Kantarcı, M. M. Bülbül, Infrared spectroscopic and gravimetric studies on the cyclohexylaminemetal(II) tetracyanonickellate(II)host-aromatic guest systems, J. Incl. Phenom. 40 (2001) 105-116.
  • 10. Z. Kantarcı, M. Karabacak, M.M. Bülbül, Infrared spectroscopic study on the Td-type clathrates: Cd(cyclohexylamine)2M(CN).2C6H6 (M= Cd or Hg), J. Inclusion Phenom., 40 (2001) 317-321.
  • 11. H. Yuge, T. Iwamoto, Cyano-linked structures in polymeric cadmium cyanide–pyridine (py) and –isoquinoline (iquin) complexes: crystal structures of [Cd(py)2][Cd(CN)4], [{Cd(CN) (py)2}3][Cd2(CN)7] and [Cd(iquin)2][Cd(CN)3(iquin)2]2, J. Chem. Soc. Dalton Trans., (1993) 2841-2847.
  • 12. L.H. Jones, Vibrational spectra and structures of metal cyanide complexes in the solid state V. K2Zn(CN)4, K2Cd(CN)4 and K2Hg(CN)4, Spectrochim. Acta., 17 (1961) 188.
  • 13. B. Ziegler, D. Babel, Die kristallstructur des Cyanospinelles K2Cd(CN)4, Z. Naturforsch. 46B (1991) 47-49.
  • 14. P.N. Gerlach, B.M. Powell, Crystal structure and phase transition of the cyanospinel K2Hg(CN)4, J. Chem. Phys., 85 (1986) 6004-6010.
  • 15. Z. Kantarcı, C. Bayrak, Vibrational spectroscopic studies on the tn-Td-Type: Mn(tn) Zn(CN)4.2C6H6 a nd t he c helated t n- Td-Type Zn(tn)Zn(CN)4.2C6H6 clathrates, J. Incl. Phenom., 30 (1998) 59-68.
  • 16. Z. Kantarcı, C. Bayrak, E. Kasap, An infrared and Raman spectroscopic study of pn-Td-type dipropylenendiaminemetal(II)teracyanometallate(II) benzene clathrates: M(dl-pn)M′(CN)4.2C6H6 (M= Mn, M′= Zn, Cd or Hg; M= Cd, M′= Cd or Hg; 1≤n≤1.5), J. Incl. Phenom., 33 (1999) 285-294.
  • 17. S. Bayarı, Z. Kantarcı, S. Akyüz, An infrared and Raman spectroscopic study of the Td-type 4,4′-bipyridylcadmium(II) tetracyanometallate(II)benzene(1/2) clathrates: Cd(C10H8N2) Cd(CN)4.2C6H6 and Cd(C10H8N2)Hg(CN)4.2C6H6, J. Incl. Phenom., 17 (1994) 291-302.
  • 18. Z. Kantarcı, N. Karacan, B. Davarcıoğlu, Infrared spectroscopic studies on the Hofmann-Td-type complexes: Mn(pyridine)2Cd(CN)4 and Mn(pyridine)2Hg(CN)4, J. Mol. Struct., 323 (1994) 53-58.
  • 19. Z. Kantarcı, C. Bayrak, S. Bayarı, An Infrared and Raman spectroscopic study on the Hofmann-Td-type complexes: ML2M’(CN)4, M= Mn or Zn, Cd or Hg, L= pyridine, α-,ß- or γ-picoline, J. Mol. Struct., 407 (1997) 155-163.
  • 20. M. Davis, O. Hassel, Electron diffraction investigation of molecules c ontaining a c yclohexane t ype s ix-membered ring, Acta Chem. Scand. 17 (1963) 1181.
  • 21. R.J. W. Le Fevre, A. Sundaram, R.K. Pierens, Molecular polarizability: the anisotropy of the carbon–oxygen link, J. Chem. Soc., (1963) 479-488.
  • 22. O.H. Ellestad, P. Klaboe, G. Hagen, The vibrational spectra of 1,4-dioxane-do, Spectrochim. Acta, 27 (1971) 1025-1048.
  • 23. E. Kendi, D. Ülkü, The crystal structure of the cadmiumnickel dioxane clathrate, Z. Kristallogr., 144 (1976) 91-96.
  • 24. T. Zengin, Z. Kantarcı, E. Kasap, An infrared and Raman spectroscopic study on the Hofmann-Td-type 1,4-dioxane cl athrates:M(NH3)2M′(CN)4·2C4H8O2 (M=Mn or Cd, M′= Hg; M= Cd, M′= Cd), J. Mol. Strcut., 482-483 (1999) 81-85.
  • 25. A.B. Dempster, H. Uslu, Infrared spectra and stability of Hofmann-type dioxane clathrates, Spectrochim. Acta, 34 (1978) 71-75.
  • 26. C. Parlak, Ö. Alver, M. Şenyel, Vibrational spectroscopic study of the Hofmann-Td-type clathrates: Ni(4- phenylpyridine)2M(CN)4.2G (M= Cd or Hg, G= 1,4-dioxane), Spectrochim. Acta, 78 (2011)1487-1491.
  • 27. E. Ruiz, J.J. Novoa, S. Alvarez, Ab initio study of the intermolecular interactions in the Hofmann clathrates, J. Phys.Chem., 99 (1995) 2296-2306.
Year 2019, Volume: 47 Issue: 1, 99 - 106, 01.02.2019

Abstract

References

  • 1. H. Yuge, T. Iwamoto, Different coordination behaviour of 1,2-diaminoethane (en) and tetracyanonickelate(II) upon accommodation of polar guest molecules in their metalcomplex hosts crystal-structures of [M(en)2Ni(CN)4].2phNH2 (M= Ni, Cu, Zn or Cd) and [Cd(en)2(en)(Ni(CN)4)2].4phOH, J. Incl. Phenom., 14 (1992) 217-235.
  • 2. R. Kuroda, A new type clathrate compound: the crystal structure of Cd(NH3)2Hg(CN)4.2C6H6, Inorg. Nucl. Chem. Lett., 9 (1973) 13-17.
  • 3. T. Iwamoto, Past, present and future of the clathrate inclusion compounds built of cyanometallate hosts, J. Incl. Phenom., 24 (1996) 61-132.
  • 4. Z. Kantarcı, C. Bayrak, Infrared spectroscopic and gravimetric studies on the cyclopentylaminemetal(II) tetracyanonickellate (II) host-aromatic guest systems, J. Incl. Phenom., 45 (2003) 59-67.
  • 5. E. Kasap, Z. Kantarcı, Vibrational spectroscopic studies on the Hofmann-Td-type clathrates: M(ethylenediamine) M(CN)4.2C6H6 (M= Mn or Cd, M= Cd or Hg), J. Incl. Phenom., 20 (1995) 33-44.
  • 6. V.F. Kalasinsky, T.S. Little, Vibrational spectra and structure of cyclopentylamine, J. Raman Spectrosc. 9 (1980) 224-229.
  • 7. S. Akyüz, J.E.D. Davies, Solid-state vibrational spectroscopy: Part 11. An infrared and raman vibrational spectroscopic study of metal(II) halide aniline complexes, J. Mol. Struct., 95 (1982) 157-168.
  • 8. D.A. Thornton, Metal complexes of aniline: Infrared and Raman spectra, J. Coord. Chem., 24 (1991) 261-289.
  • 9. Z. Kantarcı, M. M. Bülbül, Infrared spectroscopic and gravimetric studies on the cyclohexylaminemetal(II) tetracyanonickellate(II)host-aromatic guest systems, J. Incl. Phenom. 40 (2001) 105-116.
  • 10. Z. Kantarcı, M. Karabacak, M.M. Bülbül, Infrared spectroscopic study on the Td-type clathrates: Cd(cyclohexylamine)2M(CN).2C6H6 (M= Cd or Hg), J. Inclusion Phenom., 40 (2001) 317-321.
  • 11. H. Yuge, T. Iwamoto, Cyano-linked structures in polymeric cadmium cyanide–pyridine (py) and –isoquinoline (iquin) complexes: crystal structures of [Cd(py)2][Cd(CN)4], [{Cd(CN) (py)2}3][Cd2(CN)7] and [Cd(iquin)2][Cd(CN)3(iquin)2]2, J. Chem. Soc. Dalton Trans., (1993) 2841-2847.
  • 12. L.H. Jones, Vibrational spectra and structures of metal cyanide complexes in the solid state V. K2Zn(CN)4, K2Cd(CN)4 and K2Hg(CN)4, Spectrochim. Acta., 17 (1961) 188.
  • 13. B. Ziegler, D. Babel, Die kristallstructur des Cyanospinelles K2Cd(CN)4, Z. Naturforsch. 46B (1991) 47-49.
  • 14. P.N. Gerlach, B.M. Powell, Crystal structure and phase transition of the cyanospinel K2Hg(CN)4, J. Chem. Phys., 85 (1986) 6004-6010.
  • 15. Z. Kantarcı, C. Bayrak, Vibrational spectroscopic studies on the tn-Td-Type: Mn(tn) Zn(CN)4.2C6H6 a nd t he c helated t n- Td-Type Zn(tn)Zn(CN)4.2C6H6 clathrates, J. Incl. Phenom., 30 (1998) 59-68.
  • 16. Z. Kantarcı, C. Bayrak, E. Kasap, An infrared and Raman spectroscopic study of pn-Td-type dipropylenendiaminemetal(II)teracyanometallate(II) benzene clathrates: M(dl-pn)M′(CN)4.2C6H6 (M= Mn, M′= Zn, Cd or Hg; M= Cd, M′= Cd or Hg; 1≤n≤1.5), J. Incl. Phenom., 33 (1999) 285-294.
  • 17. S. Bayarı, Z. Kantarcı, S. Akyüz, An infrared and Raman spectroscopic study of the Td-type 4,4′-bipyridylcadmium(II) tetracyanometallate(II)benzene(1/2) clathrates: Cd(C10H8N2) Cd(CN)4.2C6H6 and Cd(C10H8N2)Hg(CN)4.2C6H6, J. Incl. Phenom., 17 (1994) 291-302.
  • 18. Z. Kantarcı, N. Karacan, B. Davarcıoğlu, Infrared spectroscopic studies on the Hofmann-Td-type complexes: Mn(pyridine)2Cd(CN)4 and Mn(pyridine)2Hg(CN)4, J. Mol. Struct., 323 (1994) 53-58.
  • 19. Z. Kantarcı, C. Bayrak, S. Bayarı, An Infrared and Raman spectroscopic study on the Hofmann-Td-type complexes: ML2M’(CN)4, M= Mn or Zn, Cd or Hg, L= pyridine, α-,ß- or γ-picoline, J. Mol. Struct., 407 (1997) 155-163.
  • 20. M. Davis, O. Hassel, Electron diffraction investigation of molecules c ontaining a c yclohexane t ype s ix-membered ring, Acta Chem. Scand. 17 (1963) 1181.
  • 21. R.J. W. Le Fevre, A. Sundaram, R.K. Pierens, Molecular polarizability: the anisotropy of the carbon–oxygen link, J. Chem. Soc., (1963) 479-488.
  • 22. O.H. Ellestad, P. Klaboe, G. Hagen, The vibrational spectra of 1,4-dioxane-do, Spectrochim. Acta, 27 (1971) 1025-1048.
  • 23. E. Kendi, D. Ülkü, The crystal structure of the cadmiumnickel dioxane clathrate, Z. Kristallogr., 144 (1976) 91-96.
  • 24. T. Zengin, Z. Kantarcı, E. Kasap, An infrared and Raman spectroscopic study on the Hofmann-Td-type 1,4-dioxane cl athrates:M(NH3)2M′(CN)4·2C4H8O2 (M=Mn or Cd, M′= Hg; M= Cd, M′= Cd), J. Mol. Strcut., 482-483 (1999) 81-85.
  • 25. A.B. Dempster, H. Uslu, Infrared spectra and stability of Hofmann-type dioxane clathrates, Spectrochim. Acta, 34 (1978) 71-75.
  • 26. C. Parlak, Ö. Alver, M. Şenyel, Vibrational spectroscopic study of the Hofmann-Td-type clathrates: Ni(4- phenylpyridine)2M(CN)4.2G (M= Cd or Hg, G= 1,4-dioxane), Spectrochim. Acta, 78 (2011)1487-1491.
  • 27. E. Ruiz, J.J. Novoa, S. Alvarez, Ab initio study of the intermolecular interactions in the Hofmann clathrates, J. Phys.Chem., 99 (1995) 2296-2306.
There are 27 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Celal Bayrak

Publication Date February 1, 2019
Published in Issue Year 2019 Volume: 47 Issue: 1

Cite

APA Bayrak, C. (2019). Vibrational Spectroscopic Study on the Hofmann-Td-type 1,4-Dioxane Clathrates. Hacettepe Journal of Biology and Chemistry, 47(1), 99-106.
AMA Bayrak C. Vibrational Spectroscopic Study on the Hofmann-Td-type 1,4-Dioxane Clathrates. HJBC. February 2019;47(1):99-106.
Chicago Bayrak, Celal. “Vibrational Spectroscopic Study on the Hofmann-Td-Type 1,4-Dioxane Clathrates”. Hacettepe Journal of Biology and Chemistry 47, no. 1 (February 2019): 99-106.
EndNote Bayrak C (February 1, 2019) Vibrational Spectroscopic Study on the Hofmann-Td-type 1,4-Dioxane Clathrates. Hacettepe Journal of Biology and Chemistry 47 1 99–106.
IEEE C. Bayrak, “Vibrational Spectroscopic Study on the Hofmann-Td-type 1,4-Dioxane Clathrates”, HJBC, vol. 47, no. 1, pp. 99–106, 2019.
ISNAD Bayrak, Celal. “Vibrational Spectroscopic Study on the Hofmann-Td-Type 1,4-Dioxane Clathrates”. Hacettepe Journal of Biology and Chemistry 47/1 (February 2019), 99-106.
JAMA Bayrak C. Vibrational Spectroscopic Study on the Hofmann-Td-type 1,4-Dioxane Clathrates. HJBC. 2019;47:99–106.
MLA Bayrak, Celal. “Vibrational Spectroscopic Study on the Hofmann-Td-Type 1,4-Dioxane Clathrates”. Hacettepe Journal of Biology and Chemistry, vol. 47, no. 1, 2019, pp. 99-106.
Vancouver Bayrak C. Vibrational Spectroscopic Study on the Hofmann-Td-type 1,4-Dioxane Clathrates. HJBC. 2019;47(1):99-106.

HACETTEPE JOURNAL OF BIOLOGY AND CHEMİSTRY

Copyright © Hacettepe University Faculty of Science

http://www.hjbc.hacettepe.edu.tr/

https://dergipark.org.tr/tr/pub/hjbc