Year 2021, Volume 49 , Issue 1, Pages 93 - 106 2021-01-01

Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers

Şenol KUBİLAY [1] , Kadir SELÇUK [2] , Dursun SARIAYDIN [3]


In the present study, a set of hydrogels were synthesized using N-isopropylacrylamide with various cross linkers at various dosages via free radical polymerization. Thermal and structural properties of the synthesized hydrogels were characterized via thermogravimetric analyzer (TGA) and Fourier Transformation Infrared Radiation (FTIR) spectroscopy. The effect of crosslinkers such as N,N´-Methylenebisacrylamide, ethylene glycol dimethacrylate (EGDMA) polyethylene glycol dimethacrylate (p(EGDMA), and polyethylene glycol diacrylate (p(EGDA) (Mn:258, Mn:575, Mn:700) were used in p(NIPAM) hydrogel preparation and their effect on swelling behavior was investigated. It was found that the swelling rate was increased as the molecular masses of the cross-linkers used decreased, whereas the hydrogel prepared using p(EGDA)-700 swelled more than the other p(EGDA) crosslinked p(NIPAM) hydrogels.
Functional hydrogels, N-isopropylacrylamide, thermoresponsive hydrogels, swelling, crosslinker
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Primary Language en
Subjects Engineering
Journal Section Articles
Authors

Orcid: 0000-0002-3537-6505
Author: Şenol KUBİLAY (Primary Author)
Institution: VAN YÜZÜNCÜ YIL ÜNİVERSİTESİ, FEN FAKÜLTESİ, KİMYA BÖLÜMÜ
Country: Turkey


Orcid: 0000-0002-7626-8295
Author: Kadir SELÇUK
Institution: YÜZÜNCÜ YIL ÜNİVERSİTESİ, MÜHENDİSLİK FAKÜLTESİ, KİMYA MÜHENDİSLİĞİ BÖLÜMÜ
Country: Turkey


Orcid: 0000-0001-7191-510X
Author: Dursun SARIAYDIN
Institution: CUMHURİYET ÜNİVERSİTESİ, FEN FAKÜLTESİ, KİMYA BÖLÜMÜ
Country: Turkey


Supporting Institution Van Yüzüncü Yıl University, Coordinatorship of Scientific Research Projects
Project Number BAP FBA-7893-2019
Thanks The authors grateful for the financial from Van Yüzüncü Yıl University, Coordinatorship of Scientific Research Projects.
Dates

Publication Date : January 1, 2021

Bibtex @research article { hjbc719698, journal = {Hacettepe Journal of Biology and Chemistry}, issn = {2687-475X}, eissn = {2687-475X}, address = {Hacettepe Üniversitesi Fen Fakültesi, 06532, Beytepe/ ANKARA/ TÜRKİYE}, publisher = {Hacettepe University}, year = {2021}, volume = {49}, pages = {93 - 106}, doi = {10.15671/hjbc.719698}, title = {Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers}, key = {cite}, author = {Kubilay, Şenol and Selçuk, Kadir and Sarıaydın, Dursun} }
APA Kubilay, Ş , Selçuk, K , Sarıaydın, D . (2021). Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers . Hacettepe Journal of Biology and Chemistry , 49 (1) , 93-106 . DOI: 10.15671/hjbc.719698
MLA Kubilay, Ş , Selçuk, K , Sarıaydın, D . "Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers" . Hacettepe Journal of Biology and Chemistry 49 (2021 ): 93-106 <https://dergipark.org.tr/en/pub/hjbc/issue/58116/719698>
Chicago Kubilay, Ş , Selçuk, K , Sarıaydın, D . "Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers". Hacettepe Journal of Biology and Chemistry 49 (2021 ): 93-106
RIS TY - JOUR T1 - Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers AU - Şenol Kubilay , Kadir Selçuk , Dursun Sarıaydın Y1 - 2021 PY - 2021 N1 - doi: 10.15671/hjbc.719698 DO - 10.15671/hjbc.719698 T2 - Hacettepe Journal of Biology and Chemistry JF - Journal JO - JOR SP - 93 EP - 106 VL - 49 IS - 1 SN - 2687-475X-2687-475X M3 - doi: 10.15671/hjbc.719698 UR - https://doi.org/10.15671/hjbc.719698 Y2 - 2020 ER -
EndNote %0 Hacettepe Journal of Biology and Chemistry Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers %A Şenol Kubilay , Kadir Selçuk , Dursun Sarıaydın %T Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers %D 2021 %J Hacettepe Journal of Biology and Chemistry %P 2687-475X-2687-475X %V 49 %N 1 %R doi: 10.15671/hjbc.719698 %U 10.15671/hjbc.719698
ISNAD Kubilay, Şenol , Selçuk, Kadir , Sarıaydın, Dursun . "Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers". Hacettepe Journal of Biology and Chemistry 49 / 1 (January 2021): 93-106 . https://doi.org/10.15671/hjbc.719698
AMA Kubilay Ş , Selçuk K , Sarıaydın D . Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers. HJBC. 2021; 49(1): 93-106.
Vancouver Kubilay Ş , Selçuk K , Sarıaydın D . Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers. Hacettepe Journal of Biology and Chemistry. 2021; 49(1): 93-106.
IEEE Ş. Kubilay , K. Selçuk and D. Sarıaydın , "Synthesis and characterization of p (N-isopropylacrylamide) hydrogels with tunable swelling behavior using different crosslinkers", Hacettepe Journal of Biology and Chemistry, vol. 49, no. 1, pp. 93-106, Jan. 2021, doi:10.15671/hjbc.719698