BibTex RIS Cite

Removal of Heavy Metals From Aqueus Solution Using Activated Carbon Embedded Cryogels

Year 2017, Volume: 45 Issue: 1, 135 - 142, 01.03.2017

Abstract

In this study poly hydroxyethyl methacrylate PHEMA based activated carbon AC embedded cryogel discs were synthesized, characterized and their application for nickel and copper removal from aqueous solutions were investigated. The effect of pH and initial metal concentration on the adsorption capacity of the cryogels were studied in batch systems. Desorption of heavy metal ions was also studied and it was shown that synthe- sized discs could be repeatedly used without significant loss in the adsorption capacity after five repetitive adsorption–desorption processes.

References

  • A. Agrawal, K.K. Sahu, B.D. Pandey, Removal of zinc from aqueous solutions using sea nodule residue, Colloids and Surfaces A: Physicochem. Eng. Asp., 237 (2004) 133-138.
  • Srivastava, V.C., Mall, I.D., Mishra, I.M., Equilibrium modelling of single and binary adsorption of cadmium and nickel onto bagasse fly ash, Chem. Eng. J., 117 (2006) 79-91.
  • T. Gotoh, K. Matsushima, K.I. Kikuchi, Adsorption of Cu and Mn on covalently cross-linked alginate gel beads, Chemosphere, 55 (2004) 57–64.
  • N.P. Raval, P.U. Shah, N.K. Shah, Adsorptive removal of nickel(II) ions from aqueous environment: A review, Journal of Environmental Management, 179 (2016) 1-20.
  • M.A. Acheampong, J.P.C. Pereira, R.J.W. Meulepas, P.N.L. Lens, Kinetics modelling of Cu(II) biosorption on to coconut shell and Moringa oleifera seeds from tropical regions, Environ. Technol., 33 (2012) 409-417.
  • M.K. Jha, R.R. Upadhyay, J.C. Lee, V. Kumar, Treatment of rayon waste effluent for the removal of Zn and Ca using Indion BSR resin, Desalination, 228 (2008) 97– 107.
  • A. Denizli, N. Sanli, B. Garipcan, S. Patir, G. Alsancak, Ind. Eng. Chem. Res., 43 (2004) 6095–6101.
  • M. Sciban, M. Klasnja, B. Skrbic, Modified softwood sawdust as adsorbent of heavy metal ions from water, J. Hazard. Mater. B., 136 (2006) 266–271.
  • R.A. Beuvais, S.D. Alexandratos, State-of-the-Art: Selective Ion Complexing Polymers, React. Funct. Polym., 36 (1998) 113–123.
  • K. Tekin, L. Uzun, Ç.A. Sahin, S.Bektas, A.Denizli, Preparation and characterization of composite cryogels containing imidazole group and use in heavy metal removal, React. Functl. Polym., 71 (2011) 985- 993.
  • D.Çimen, D.Türkmen, A.Denizli, Poly-L-Histidine Attached Poly(glycidyl methacrylate) Cryogels for Heavy Metal Removal, J. Macromol. Sci., Part A 52 (2015) 724–731.
  • F. Augusto, E. Carasek, R.G. Silva, S.R. Rivellino, A.D. Batista, E. Martendal, New sorbents for extraction and microextraction techniques, J. Chromatogr. A, 1217 (2010) 2533–2542.
  • B.L. Rivas, M. Jara, E.D. Pereira, Preparation and adsorption properties of the chelating resins containing carboxylic, sulfonic, and imidazole groups, J. Appl. Polym. Sci., 89 (10) (2003) 2852-2856.
  • B.L. Rivas, E. Pereira, M. Jara, C. Esparza, Resins with the ability to bind copper and uranyl ions, J. Appl. Polym. Sci., 99:3 (2006) 706-711.
  • E.Dana, A.Sayari, Preparation and characterization of PEG bis(amine) grafted PMMA/SPION composite nanoparticles, Desal., 285(2012) 62-71.
  • S. Senel, L. Uzun, A. Kara, A. Denizli, Heavy Metal Removal from Synthetic Solutions with Magnetic Beads Under Magnetic Field Sci. Pure Appl. Chem., 45 (2008) 635–642.
  • D.W. O’Connell, C. Birkinshaw, T.F. O’Dwyer, A modified Cellulose Adsorbent for the removal of Ni(II) from aqueous solutions, J. Chem. Technol. Biotechnol., 81(11) (2006) 1820.
  • D.W. O’Connell, C. Birkinshaw, T.F. O’Dwyer, A chelating cellulose adsorbent for the removal of Cu(II) from aqueous solutions, J. Appl. Polym. Sci., 99 (6) (2005) 2888-2897. W.L.Ningmei, L.Zhengkui, Synthesis and characterization of poly(HEMA/MALA) hydrogel and its application in removal of heavy metal ions from water Chem. Eng. J., 894 (2013) 215–216.
  • L. Onnby, C. Giorgi, F.M. Plieva, B. Mattiasson, Removal of heavy metals from water effluents using supermacroporous metal chelating cryogels, Biotechnol. Prog., 26 (2010) 1295–1302.
  • O. Ozay, S. Ekici, Y. Barana, S. Kubilay, N. Aktas, N. Sahiner, Utilization of magnetic hydrogels in the separation of toxic metal ions from aqueous environments, Desalination, 260 (1–3) (2010) 57.
  • H. Kirsebom, B. Mattiasson, I.Y. Galaev, Building Macroporous Materials from Microgels and Microbes via One-Step Cryogelation, Langmuir, 25 (2009) 8462.
  • H. Kirsebom, D. Topgaard, I.Y. Galaev, B. Mattiasson, Modulating the Porosity of Cryogels by Influencing the Nonfrozen Liquid Phase through the Addition of Inert Solutes, Langmuir, 26 (2010) 16129.
  • R.C.Mansal, M.Goyal, Activated Carbon Adsorption, Taylor & Francis Group , LLC, CRC Press, Boca Raton, 2005.
  • T.M. Alslaibi, I. Abustan, M.A. Ahmad, A.A. Foul, Cadmium removal from aqueous solution using microwaved olive stone activated carbon, J. Environ. Chem. Eng., 1 (2013) 589-599.
  • F. Bouhamed, Z. Elouear, J. Bouzid, Adsorptive removal of copper(II) from aqueous solutions on activated carbon prepared from Tunisian date stones: Equilibrium, kinetics and thermodynamics, J. Taiwan Inst. Chem. Eng., 43 (2012) 741-749.
  • A.I. Esmael, M.E. Matta, H.A. Halim, F.M. Abdel Azziz, Adsorption of heavy metals from industrial wastewater using palm date pits as low cost adsorbent, Int. J. Eng. Adv. Technol. (IJEAT), 3 (2014) 71-76.
  • P.O. Ameh, Modeling of the adsorption of Cu (II) and Cd (II) from aqueous solution by Iraqi palm-date activated carbon (IPDAC), Int. J. Modern Chem., 5 (2013) 136-144.
  • F. Bouhamed, Z. Elouear, J. Bouzid, Adsorptive removal of copper(II) from aqueous solutions on activated carbon prepared from Tunisian date stones: Equilibrium, kinetics and thermodynamics, J. Taiwan Inst. Chem. Eng., 43 (2012) 741-749.
  • A. Denizli, E. Pişkin, Dye-ligand Affinity Systems, J. Biochem. Biophys. Methods, 49 (2001) 391–416.

Aktif Karbon Gömülü Kriyojeller Kullanılarak Atık Sulardan Ağır Metal Uzaklaştırılması

Year 2017, Volume: 45 Issue: 1, 135 - 142, 01.03.2017

Abstract

B u çalışmada poli hidroksi metakrilat temelli aktif karbon gömülü kriyojel diskler sentezlenmiş, karakterize edilmiş ve sulu çözeltilerden ağır metal giderimi incelenmiştir. Sentezlenen kompozit kriyojel disklerin adsorpsiyon kapasitesine pH ve başlangıç metal iyonu derişiminin etkisi kesikli adsorpsiyon süreci kullanılarak incelenmiştir. Metal iyonlarının desorpsiyon çalışmaları gerçekleştirilmiş ve ard arda yapılan beş adsorpsiyondesorpsiyon döngüsünden sonra kriyojellerin belirgin bir kapasite kaybına uğramadan tekrar kullanılabildiği gözlenmiştir

References

  • A. Agrawal, K.K. Sahu, B.D. Pandey, Removal of zinc from aqueous solutions using sea nodule residue, Colloids and Surfaces A: Physicochem. Eng. Asp., 237 (2004) 133-138.
  • Srivastava, V.C., Mall, I.D., Mishra, I.M., Equilibrium modelling of single and binary adsorption of cadmium and nickel onto bagasse fly ash, Chem. Eng. J., 117 (2006) 79-91.
  • T. Gotoh, K. Matsushima, K.I. Kikuchi, Adsorption of Cu and Mn on covalently cross-linked alginate gel beads, Chemosphere, 55 (2004) 57–64.
  • N.P. Raval, P.U. Shah, N.K. Shah, Adsorptive removal of nickel(II) ions from aqueous environment: A review, Journal of Environmental Management, 179 (2016) 1-20.
  • M.A. Acheampong, J.P.C. Pereira, R.J.W. Meulepas, P.N.L. Lens, Kinetics modelling of Cu(II) biosorption on to coconut shell and Moringa oleifera seeds from tropical regions, Environ. Technol., 33 (2012) 409-417.
  • M.K. Jha, R.R. Upadhyay, J.C. Lee, V. Kumar, Treatment of rayon waste effluent for the removal of Zn and Ca using Indion BSR resin, Desalination, 228 (2008) 97– 107.
  • A. Denizli, N. Sanli, B. Garipcan, S. Patir, G. Alsancak, Ind. Eng. Chem. Res., 43 (2004) 6095–6101.
  • M. Sciban, M. Klasnja, B. Skrbic, Modified softwood sawdust as adsorbent of heavy metal ions from water, J. Hazard. Mater. B., 136 (2006) 266–271.
  • R.A. Beuvais, S.D. Alexandratos, State-of-the-Art: Selective Ion Complexing Polymers, React. Funct. Polym., 36 (1998) 113–123.
  • K. Tekin, L. Uzun, Ç.A. Sahin, S.Bektas, A.Denizli, Preparation and characterization of composite cryogels containing imidazole group and use in heavy metal removal, React. Functl. Polym., 71 (2011) 985- 993.
  • D.Çimen, D.Türkmen, A.Denizli, Poly-L-Histidine Attached Poly(glycidyl methacrylate) Cryogels for Heavy Metal Removal, J. Macromol. Sci., Part A 52 (2015) 724–731.
  • F. Augusto, E. Carasek, R.G. Silva, S.R. Rivellino, A.D. Batista, E. Martendal, New sorbents for extraction and microextraction techniques, J. Chromatogr. A, 1217 (2010) 2533–2542.
  • B.L. Rivas, M. Jara, E.D. Pereira, Preparation and adsorption properties of the chelating resins containing carboxylic, sulfonic, and imidazole groups, J. Appl. Polym. Sci., 89 (10) (2003) 2852-2856.
  • B.L. Rivas, E. Pereira, M. Jara, C. Esparza, Resins with the ability to bind copper and uranyl ions, J. Appl. Polym. Sci., 99:3 (2006) 706-711.
  • E.Dana, A.Sayari, Preparation and characterization of PEG bis(amine) grafted PMMA/SPION composite nanoparticles, Desal., 285(2012) 62-71.
  • S. Senel, L. Uzun, A. Kara, A. Denizli, Heavy Metal Removal from Synthetic Solutions with Magnetic Beads Under Magnetic Field Sci. Pure Appl. Chem., 45 (2008) 635–642.
  • D.W. O’Connell, C. Birkinshaw, T.F. O’Dwyer, A modified Cellulose Adsorbent for the removal of Ni(II) from aqueous solutions, J. Chem. Technol. Biotechnol., 81(11) (2006) 1820.
  • D.W. O’Connell, C. Birkinshaw, T.F. O’Dwyer, A chelating cellulose adsorbent for the removal of Cu(II) from aqueous solutions, J. Appl. Polym. Sci., 99 (6) (2005) 2888-2897. W.L.Ningmei, L.Zhengkui, Synthesis and characterization of poly(HEMA/MALA) hydrogel and its application in removal of heavy metal ions from water Chem. Eng. J., 894 (2013) 215–216.
  • L. Onnby, C. Giorgi, F.M. Plieva, B. Mattiasson, Removal of heavy metals from water effluents using supermacroporous metal chelating cryogels, Biotechnol. Prog., 26 (2010) 1295–1302.
  • O. Ozay, S. Ekici, Y. Barana, S. Kubilay, N. Aktas, N. Sahiner, Utilization of magnetic hydrogels in the separation of toxic metal ions from aqueous environments, Desalination, 260 (1–3) (2010) 57.
  • H. Kirsebom, B. Mattiasson, I.Y. Galaev, Building Macroporous Materials from Microgels and Microbes via One-Step Cryogelation, Langmuir, 25 (2009) 8462.
  • H. Kirsebom, D. Topgaard, I.Y. Galaev, B. Mattiasson, Modulating the Porosity of Cryogels by Influencing the Nonfrozen Liquid Phase through the Addition of Inert Solutes, Langmuir, 26 (2010) 16129.
  • R.C.Mansal, M.Goyal, Activated Carbon Adsorption, Taylor & Francis Group , LLC, CRC Press, Boca Raton, 2005.
  • T.M. Alslaibi, I. Abustan, M.A. Ahmad, A.A. Foul, Cadmium removal from aqueous solution using microwaved olive stone activated carbon, J. Environ. Chem. Eng., 1 (2013) 589-599.
  • F. Bouhamed, Z. Elouear, J. Bouzid, Adsorptive removal of copper(II) from aqueous solutions on activated carbon prepared from Tunisian date stones: Equilibrium, kinetics and thermodynamics, J. Taiwan Inst. Chem. Eng., 43 (2012) 741-749.
  • A.I. Esmael, M.E. Matta, H.A. Halim, F.M. Abdel Azziz, Adsorption of heavy metals from industrial wastewater using palm date pits as low cost adsorbent, Int. J. Eng. Adv. Technol. (IJEAT), 3 (2014) 71-76.
  • P.O. Ameh, Modeling of the adsorption of Cu (II) and Cd (II) from aqueous solution by Iraqi palm-date activated carbon (IPDAC), Int. J. Modern Chem., 5 (2013) 136-144.
  • F. Bouhamed, Z. Elouear, J. Bouzid, Adsorptive removal of copper(II) from aqueous solutions on activated carbon prepared from Tunisian date stones: Equilibrium, kinetics and thermodynamics, J. Taiwan Inst. Chem. Eng., 43 (2012) 741-749.
  • A. Denizli, E. Pişkin, Dye-ligand Affinity Systems, J. Biochem. Biophys. Methods, 49 (2001) 391–416.
There are 29 citations in total.

Details

Primary Language English
Journal Section Research Article
Authors

Ceren Haktanır This is me

Publication Date March 1, 2017
Published in Issue Year 2017 Volume: 45 Issue: 1

Cite

APA Haktanır, C. (2017). Removal of Heavy Metals From Aqueus Solution Using Activated Carbon Embedded Cryogels. Hacettepe Journal of Biology and Chemistry, 45(1), 135-142.
AMA Haktanır C. Removal of Heavy Metals From Aqueus Solution Using Activated Carbon Embedded Cryogels. HJBC. March 2017;45(1):135-142.
Chicago Haktanır, Ceren. “Removal of Heavy Metals From Aqueus Solution Using Activated Carbon Embedded Cryogels”. Hacettepe Journal of Biology and Chemistry 45, no. 1 (March 2017): 135-42.
EndNote Haktanır C (March 1, 2017) Removal of Heavy Metals From Aqueus Solution Using Activated Carbon Embedded Cryogels. Hacettepe Journal of Biology and Chemistry 45 1 135–142.
IEEE C. Haktanır, “Removal of Heavy Metals From Aqueus Solution Using Activated Carbon Embedded Cryogels”, HJBC, vol. 45, no. 1, pp. 135–142, 2017.
ISNAD Haktanır, Ceren. “Removal of Heavy Metals From Aqueus Solution Using Activated Carbon Embedded Cryogels”. Hacettepe Journal of Biology and Chemistry 45/1 (March 2017), 135-142.
JAMA Haktanır C. Removal of Heavy Metals From Aqueus Solution Using Activated Carbon Embedded Cryogels. HJBC. 2017;45:135–142.
MLA Haktanır, Ceren. “Removal of Heavy Metals From Aqueus Solution Using Activated Carbon Embedded Cryogels”. Hacettepe Journal of Biology and Chemistry, vol. 45, no. 1, 2017, pp. 135-42.
Vancouver Haktanır C. Removal of Heavy Metals From Aqueus Solution Using Activated Carbon Embedded Cryogels. HJBC. 2017;45(1):135-42.

HACETTEPE JOURNAL OF BIOLOGY AND CHEMİSTRY

Copyright © Hacettepe University Faculty of Science

http://www.hjbc.hacettepe.edu.tr/

https://dergipark.org.tr/tr/pub/hjbc