Photochemical Reaction of Metal Carbonyls [M(CO)6 (M=Cr,Mo,W)] with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone

Year 2019, Volume: 2 Issue: 1, 27 - 31, 30.06.2019

Sema Sert

https://doi.org/10.38061/idunas.463196

Abstract

The new complexes, [M(CO)₅(msh4)]
(Cr(1), Mo(2), W(3)), have been synthesized by the photochemical reaction of
metal carbonyls with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone(msh4) .The structure of these complexes
has been investigated by using elemental analyses; FT-IR; EI-MS and ¹H
NMR spectrometric methods. According to all spectroscopic data, msh4 is
monodaentate and coordinate via thiophene ring sulfur.

Keywords

Metal carbonyls; Methanesulfonylhydrazone; Photochemical Reactions.

Photochemical Reaction of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with 2-acetyl-5- chlorothiophenemethanesulfonylhydrazone

Abstract

The new complexes, [M(CO)5(msh4)] (Cr(1), Mo(2), W(3)), have been synthesized by the photochemical reaction of metal carbonyls with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone(msh4) .The structure of these complexes has been investigated by using elemental analyses; FT-IR; EI-MS and 1H NMR spectrometric methods. According to all spectroscopic data, msh4 is monodaentate and coordinate via thiophene ring sulfur.

Keywords

Metal carbonys, Methanesulfonylhydrazone, Photochemical Reactions

References

• G.Domagk, Deut. Med. Wochenschr. 61(1935) 250.
• G.I.Mandell, W.A.Petri, J.G.Hardman, L.E.Limbird, P.B.Molinoff, R.W.Ruddon, A.G.Gilman, Goodman’s the Pharmacological Basis of Therapeutics, 9th ed.,McGraw-Hill, New York, 1996.
• N.R.Lomax , LV.L.Narayanan, Chemical Structures of Interest to the Division of Cancer Treatment, Vol. VI, Developmental Therapeutics Program, National Cancer Institue, Bethesda,MD, p.32(1988).
• P.B.Jensen, B.S.Soerensen, J.F.E.Demant, M.Sehested, P.S.Jensen, L.H.Vindeloey, H.H.Hansen, Cancer Res., 50, 3311(1990).
• G.J.Finlay, B.C.Baguley, K.Snow, W.Judd, J.NATL.Cancer Inst., 82, 662(1990).
• S.Topiol, M.Sabio, P.W.Erhardt, J.Chem.Soc., Perkin Trans., 2, 437(1998).
• H.Rutner, N.Lewin, E.C.Woodbury, T.J.McBride, K.V.Rao. Cancer Chemother.Rep., Part 1,58, 803 (1974).
• A.Lenco, C.Mealli, P.Paoli, N.Dodoff, Z.Kantarcı, N.Karacan, New J. Chem.,23, 1253(1999).
• M.A. Reynolds, A.A. Guzei, B.C. Logsdon, L.M. Thomas, R.A. Jacobson, R.J. Angelici. Organometallics, 18, 4075 (1999).
• G.Orhan, O.S.Şentürk, Ü.Ö.Özmen, S.Sert, E.Subaşı, J.of Coor. Chem., 64, 19 (2014).
• D.D.Perrin, W.F.F.Armarego, D.R.Perrin, Purification of Laboratory Chemicals, Pergamon Press, Oxford (1980).
• N.I.Dodoff, Ü.Özdemir, N.Karacan, M.Georgieva, S.M.Konstantinov, M.E.Stefanova, Z.Naturforsch, 54b, 1553(1999).
• K. Hanai, T. Okuda, T. Uno, K. Machida. Spectrochim. Acta, 31, 1217 (1975).
• A.R. Katritzky, R.A. Jones. J. Chem. Soc., 4497 (1960).
• N. Bacon, A.J. Boulton, R.T.C. Brownlee, A.R. Katritzky, R.D. Topsom. J. Chem. Soc., 5230 (1965).
• Y. Tanaka, Y. Tanaka. Chem. Pharm. Bull., 13, 858 (1965).
• K. Hanai, A. Noguchi, T. Okuda. Spectrochim. Acta, 34, 771 (1978).
• Ü. Özdemir, O.S. Sentürk, S. Sert, N. Karacan, F. Uğur. Transit. Met. Chem., 28, 443 (2003).
• Ü.Ö. Özdemir, N. Akkaya, N. Özbek. Inorg. Chim. Acta, 400, 13 (2013).
• R.J.W. Cremlyn, D.N. Waters. J. Chem Soc., suppl. 2, 6243 (1964).
• R.D. McLachlan, V.B. Carter. Spectrochim. Acta, 26, 1121 (1970).
• T. Uno, K. Machida, K. Hanai. Spectrochim. Acta, 27, 107 (1971).
• G. Geiseler, G. Hanschmann. J. Mol. Struct., 8, 293 (1971).
• G. Chassaing, J. Corset, J. Limouzi. Spectrochim Acta, 37, 721 (1981).
• P. Teyssie, J.J. Charette. Spectrochim. Acta, 19, 1407 (1963).
• J.A. Faniran, K.S. Patel, J.C. Bailar Jr. J. Inorg. Nucl. Chem., 36, 1547 (1974).
• L.I. Kozhevina, E.B. Prokopenko, V.I. Rybachenko, E.V. Titov. Zh. Prikl. Spektrosk., 59, 440 (1993).
• V.I. Tsapkov, N.M. Samus’. Zh. Obshch. Khim., 67, 1422 (1997).
• P. Mills, S. Korlann, M.E. Bussell, M.A. Reynolds, M.V. Ovchinnikov, R.J. Angelici, C. Stinner, T. Weber, R. Prins. J. Phys. Chem. A, 105, 4418 (2001).
• C.Kumar, C.Parlak, H.Fun, M.Tursun, G.Keşan, S.Chandraju, C.K.Quah, Spectrochim.Acta Part A:Molecular and Biomolecular Spectroscopy 127,67 (2014).
• P. Mills, S. Korlann, M.E. Bussell, M.A. Reynolds, M.V. Ovchinnikov, R.J. Angelici, C. Stinner, T. Weber, R. Prins. J. Phys. Chem., 105, 4418 (2001).
• C. Spinu, A. Kriza. Acta Chim. Slov., 47, 179 (2000).
• F. Sarıkahya, O.S. Şentürk. Syn. React. Inorg. Met., 31, 1843 (2001).