Research Article
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Year 2017, Volume: 1 Issue: 1, 37 - 45, 15.11.2017
https://doi.org/10.32571/ijct.345418

Abstract

References

  • 1. Karaoglu, K.; Baran, T.; Serbest, K.; Er, M.; Degirmencioglu, I. J. Mol. Struct. 2009, 922, 39-45.
  • 2. Ekmekcioglu, P.; Karabocek, N.; Karabocek, S.; Emirik, M. J. Mol. Struct. 2015, 1099, 189-196.
  • 3. Er, M.; Sancak, K.; Değirmencioğlu, I., Serbest, K. J. Mol. Struct. 2008, 882, 35-46.
  • 4. Azadbakht, R.; Khanabadi, J.. Inorg. Chem. Commun. 2013, 30, 21-25.
  • 5. Abbo, H. S.; Titinchi, S. J. J.; Prasad, R.; Chand, S. J. Mol. Catal. A: Chem. 2005, 225, 225¬232.
  • 6. Wang, Y.; Fu, Z.; Wen, X.; Rong, C,; Wu, W.; Zhang, Chao.; Deng, J.; Dai, B.; Kirk S.R.; Yin, D. J. Mol. Catal. A: Chem. 2014, 384, 46-52.
  • 7. Zoubi, W.A.L.; Kandil, F.; Chebani, M.K. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2011, 79(5), 1909-1914.
  • 8. Çolak, M.; Demirel, N. Tetrahedron: Asymmetry 2008, 19(5), 635-639.
  • 9. Temel, H.; Çakır, Ü.; Uğraş, H.İ.; Şekerci, M. J. Coord. Chem. 2003, 56, 943-951.
  • 10. Sönmez, M.; Çelebi, M. and Berber, İ. Eur. J. Med. Chem. 2010, 45, 1935-1940.
  • 11. Sivakumar, R.; Reena, V.; Ananthi N.; Babu, M.; Anandan, S.; Velmathi, S. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2010, 75(3), 1146-1151.
  • 12. Ceyhan, G.; Çelik, C.; Uruş, S.; Demirtaş, İ.; Elmastaş, M.; Tümer, M. Spectrochim Acta Part A: Mol. Biomol. Spectrosc. 2011, 81(1), 184-198. 13. Masih, I.; Fahmi, N. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2011, 79(5), 940-947.
  • 14. Rajsekhar, G.; Rao, C.P.; Saarenketo, P.; Nattinenb, K.; Rissanen, K. New J. Chem. 2004, 28, 75-84.
  • 15. Hailu, S. L,; Nair, B.U.; Redi‐Abshiro, M.; Diaz, I.; Aravindhan, R.; Tessema, M. Chinese J. Catal. 2016, 37(1), 135-145.
  • 16. Zhao, Y.; Tang, Y.; Liu, W.S.; Tang, Ning.; Tan, M.Y. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2006, 65(2), 372-377.
  • 17. Shoair, A.F,; El-Shobaky, A.R,. Azab, E.A. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2015, 151, 322-334.
  • 18. Baran, T.; Karaoglu, K.; Serbest, K.; Ağır, H.; Sandallı, C.; Değirmencioğlu, İ. Monatshefte für Chemie. 2013, 144, 1107-1115.
  • 19. El-Shobaky, A. R. Met-Org. Nano-Met. Chem. 2015, 45, 1481-1488.
  • 20. Yilmaz Obali, .A.; Ucan, H.I. J. Mol. Struct. 2015, 1081, 74-78.
  • 21. Karahan, A.; Yardan, A.; Yahsi, Y.; Kara, H.; Kurtaran, R. SDU J. Sci. (e-Journal). 2013, 8(2), 163-174.
  • 22. Naeimi, H.; Tarazian, R. J. Heterocyclic Chem. 2014, 51, 566.
  • 23. Kaya, İ.; Çulhaoğlu, S. Chinese J. Polym. Sci. 2012, 5, 682−693.
  • 24. Taşkın, O.K.; Öztürk, Ö.F.; Canpolat, E.. BEÜ Fen Bilimleri Dergisi. 2012, 1, 34-39 (in Turkish).
  • 25. Canpolat, E.; Ağlamış, A., Şahal, H.; Kaya, M. Fen Bilimleri Dergisi (CFD), 2016, 37(1), 65-73.
  • 26. Serbest, K.; Karaoğlu, K.; Erman, M.; Er, M.; Değirmencioğlu, İ. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2010, 77(3), 643-651.
  • 27. Rajakumar, P.; Murali, V. Tetrahedron 2004, 60, 2351-2360.
  • 28. Rsmussen, J.C.; Toftlund, H.; Nivorzhkin, A.N.; Bourasse, J.; Ford, P.C. Inorg. Chim. Acta 1996, 251, 291-298.
  • 29. Islam, Sk.M.; Paul, S.; Roy A.S.; Banerjee, S.; Ghosh, K.; Dey, R.C.; Santra, S.C. Trans. Metal. Chem. 2013, 38(6), 675-682.
  • 30. Wang, Y.; Wen, X.; Rong, C.; Tang, S.; Wu, W.; Zhang, C.; Liu, Y.; Fu, Z. J. Mol. Catal. A: Chem. 2016, 411, 103-109.
  • 31. Pramanik, A.K.; Mondal, T.K. Inorg. Chim. Acta 2014, 411, 106-112.
  • 32. Dhara, P. K.; Drew, M. G. B.; Chattopadhyay P. Polyhedron 2006, 25, 1939-1945.
  • 33. Anastasiadis, N.; Bilis, G.; Plakatouras, J.C.; Raptopoulou, C.P.; Psycharis, V.; Beavers, C.; Teat, S.J.; Louloudi, M., Perlepes, S.P. Polyhedron 2013, 64, 189-202.
  • 34. Geary, W J. Coord. Chem. Rev. 1971, 7(1), 81-122.
  • 35. Manonmani, J.; Kandaswamy, M.; Narayanan, V.; Thirumurugan, R.; Shanmuga Sundura Raj, S.; Shanmugam, G., Ponnuswamy, M.N.; Fun, H.K. Polyhedron 2001, 20, 3039-3048.
  • 36. Abdel-Latif, S. A.; Hassib, H. B.; Issa, Y. M. Spectrochim Acta Part A: Mol. Biomol. Spectrosc. 2007, 67(3-4), 950-957.
  • 37. Urus, S.; Keles M.; Serindag, O. J. Inorg. Organometal Polym. 2010, 20, 152-160.
  • 38. Retcher, B.; Costa, J.S.; Tang, J.; Hage, R.; Gamez, P.; Reedijk, J. J. Mol. Catal. A: Chem. 2008, 286, 1-5.
  • 39. Luque R.; Badamali, S.K.; Clark, J.H.; Fleming, M.; Macquarrie, D.J. Appl. Catal. A: Gen. 2008, 341, 154-159.

Synthesis, characterization and catalytic properties of some transition metal complexes of new phenoxy-imine ligand

Year 2017, Volume: 1 Issue: 1, 37 - 45, 15.11.2017
https://doi.org/10.32571/ijct.345418

Abstract

In this study a new
Schiff base ligand was synthesized by the reaction of salicylaldehyde,
1,2-bis(bromomethyl)benzene and 4-nitrobenzenamine. [Cr(L)Cl2]Cl·H2O,
[Fe(L)Cl2]Cl·2H2Oand [Ru(L)Cl2]Cl complexes were synthesized with this ligand and Cr(III), Fe(III) and
Ru(III) chloride salts. The structures of the ligand and the obtained
complexes were characterized using Elemental Analysis, FT-IR, 1H-NMR,
13C-NMR, UV-Vis, Magnetic Susceptibility and Thermogravimetric Analysis.
The synthesized phenoxy-imine ligand is a ligand of the O2N2
type. The resulting metal complexes are mononuclear and have octahedral
geometry. Preliminary studies have also been carried out on the catalytic
effects of complexes in cycloalkane oxidation and in cycloalkene epoxidation.
In the general sense, the catalyst that triggers the highest product formation
in the synthesized catalysts are the Ru(III) complex. It is suggested that
Ru(III) complexes can be used in such catalysis reactions since they exhibit a
high catalytic effect on cyclohexane oxidation.

References

  • 1. Karaoglu, K.; Baran, T.; Serbest, K.; Er, M.; Degirmencioglu, I. J. Mol. Struct. 2009, 922, 39-45.
  • 2. Ekmekcioglu, P.; Karabocek, N.; Karabocek, S.; Emirik, M. J. Mol. Struct. 2015, 1099, 189-196.
  • 3. Er, M.; Sancak, K.; Değirmencioğlu, I., Serbest, K. J. Mol. Struct. 2008, 882, 35-46.
  • 4. Azadbakht, R.; Khanabadi, J.. Inorg. Chem. Commun. 2013, 30, 21-25.
  • 5. Abbo, H. S.; Titinchi, S. J. J.; Prasad, R.; Chand, S. J. Mol. Catal. A: Chem. 2005, 225, 225¬232.
  • 6. Wang, Y.; Fu, Z.; Wen, X.; Rong, C,; Wu, W.; Zhang, Chao.; Deng, J.; Dai, B.; Kirk S.R.; Yin, D. J. Mol. Catal. A: Chem. 2014, 384, 46-52.
  • 7. Zoubi, W.A.L.; Kandil, F.; Chebani, M.K. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2011, 79(5), 1909-1914.
  • 8. Çolak, M.; Demirel, N. Tetrahedron: Asymmetry 2008, 19(5), 635-639.
  • 9. Temel, H.; Çakır, Ü.; Uğraş, H.İ.; Şekerci, M. J. Coord. Chem. 2003, 56, 943-951.
  • 10. Sönmez, M.; Çelebi, M. and Berber, İ. Eur. J. Med. Chem. 2010, 45, 1935-1940.
  • 11. Sivakumar, R.; Reena, V.; Ananthi N.; Babu, M.; Anandan, S.; Velmathi, S. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2010, 75(3), 1146-1151.
  • 12. Ceyhan, G.; Çelik, C.; Uruş, S.; Demirtaş, İ.; Elmastaş, M.; Tümer, M. Spectrochim Acta Part A: Mol. Biomol. Spectrosc. 2011, 81(1), 184-198. 13. Masih, I.; Fahmi, N. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2011, 79(5), 940-947.
  • 14. Rajsekhar, G.; Rao, C.P.; Saarenketo, P.; Nattinenb, K.; Rissanen, K. New J. Chem. 2004, 28, 75-84.
  • 15. Hailu, S. L,; Nair, B.U.; Redi‐Abshiro, M.; Diaz, I.; Aravindhan, R.; Tessema, M. Chinese J. Catal. 2016, 37(1), 135-145.
  • 16. Zhao, Y.; Tang, Y.; Liu, W.S.; Tang, Ning.; Tan, M.Y. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2006, 65(2), 372-377.
  • 17. Shoair, A.F,; El-Shobaky, A.R,. Azab, E.A. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2015, 151, 322-334.
  • 18. Baran, T.; Karaoglu, K.; Serbest, K.; Ağır, H.; Sandallı, C.; Değirmencioğlu, İ. Monatshefte für Chemie. 2013, 144, 1107-1115.
  • 19. El-Shobaky, A. R. Met-Org. Nano-Met. Chem. 2015, 45, 1481-1488.
  • 20. Yilmaz Obali, .A.; Ucan, H.I. J. Mol. Struct. 2015, 1081, 74-78.
  • 21. Karahan, A.; Yardan, A.; Yahsi, Y.; Kara, H.; Kurtaran, R. SDU J. Sci. (e-Journal). 2013, 8(2), 163-174.
  • 22. Naeimi, H.; Tarazian, R. J. Heterocyclic Chem. 2014, 51, 566.
  • 23. Kaya, İ.; Çulhaoğlu, S. Chinese J. Polym. Sci. 2012, 5, 682−693.
  • 24. Taşkın, O.K.; Öztürk, Ö.F.; Canpolat, E.. BEÜ Fen Bilimleri Dergisi. 2012, 1, 34-39 (in Turkish).
  • 25. Canpolat, E.; Ağlamış, A., Şahal, H.; Kaya, M. Fen Bilimleri Dergisi (CFD), 2016, 37(1), 65-73.
  • 26. Serbest, K.; Karaoğlu, K.; Erman, M.; Er, M.; Değirmencioğlu, İ. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 2010, 77(3), 643-651.
  • 27. Rajakumar, P.; Murali, V. Tetrahedron 2004, 60, 2351-2360.
  • 28. Rsmussen, J.C.; Toftlund, H.; Nivorzhkin, A.N.; Bourasse, J.; Ford, P.C. Inorg. Chim. Acta 1996, 251, 291-298.
  • 29. Islam, Sk.M.; Paul, S.; Roy A.S.; Banerjee, S.; Ghosh, K.; Dey, R.C.; Santra, S.C. Trans. Metal. Chem. 2013, 38(6), 675-682.
  • 30. Wang, Y.; Wen, X.; Rong, C.; Tang, S.; Wu, W.; Zhang, C.; Liu, Y.; Fu, Z. J. Mol. Catal. A: Chem. 2016, 411, 103-109.
  • 31. Pramanik, A.K.; Mondal, T.K. Inorg. Chim. Acta 2014, 411, 106-112.
  • 32. Dhara, P. K.; Drew, M. G. B.; Chattopadhyay P. Polyhedron 2006, 25, 1939-1945.
  • 33. Anastasiadis, N.; Bilis, G.; Plakatouras, J.C.; Raptopoulou, C.P.; Psycharis, V.; Beavers, C.; Teat, S.J.; Louloudi, M., Perlepes, S.P. Polyhedron 2013, 64, 189-202.
  • 34. Geary, W J. Coord. Chem. Rev. 1971, 7(1), 81-122.
  • 35. Manonmani, J.; Kandaswamy, M.; Narayanan, V.; Thirumurugan, R.; Shanmuga Sundura Raj, S.; Shanmugam, G., Ponnuswamy, M.N.; Fun, H.K. Polyhedron 2001, 20, 3039-3048.
  • 36. Abdel-Latif, S. A.; Hassib, H. B.; Issa, Y. M. Spectrochim Acta Part A: Mol. Biomol. Spectrosc. 2007, 67(3-4), 950-957.
  • 37. Urus, S.; Keles M.; Serindag, O. J. Inorg. Organometal Polym. 2010, 20, 152-160.
  • 38. Retcher, B.; Costa, J.S.; Tang, J.; Hage, R.; Gamez, P.; Reedijk, J. J. Mol. Catal. A: Chem. 2008, 286, 1-5.
  • 39. Luque R.; Badamali, S.K.; Clark, J.H.; Fleming, M.; Macquarrie, D.J. Appl. Catal. A: Gen. 2008, 341, 154-159.
There are 38 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Articles
Authors

Ali Çapan This is me 0000-0002-6477-6604

Gökhan Ceyhan 0000-0002-9127-2348

Mehmet Sönmez 0000-0003-3127-666X

Publication Date November 15, 2017
Published in Issue Year 2017 Volume: 1 Issue: 1

Cite

APA Çapan, A., Ceyhan, G., & Sönmez, M. (2017). Synthesis, characterization and catalytic properties of some transition metal complexes of new phenoxy-imine ligand. International Journal of Chemistry and Technology, 1(1), 37-45. https://doi.org/10.32571/ijct.345418
AMA Çapan A, Ceyhan G, Sönmez M. Synthesis, characterization and catalytic properties of some transition metal complexes of new phenoxy-imine ligand. Int. J. Chem. Technol. December 2017;1(1):37-45. doi:10.32571/ijct.345418
Chicago Çapan, Ali, Gökhan Ceyhan, and Mehmet Sönmez. “Synthesis, Characterization and Catalytic Properties of Some Transition Metal Complexes of New Phenoxy-Imine Ligand”. International Journal of Chemistry and Technology 1, no. 1 (December 2017): 37-45. https://doi.org/10.32571/ijct.345418.
EndNote Çapan A, Ceyhan G, Sönmez M (December 1, 2017) Synthesis, characterization and catalytic properties of some transition metal complexes of new phenoxy-imine ligand. International Journal of Chemistry and Technology 1 1 37–45.
IEEE A. Çapan, G. Ceyhan, and M. Sönmez, “Synthesis, characterization and catalytic properties of some transition metal complexes of new phenoxy-imine ligand”, Int. J. Chem. Technol., vol. 1, no. 1, pp. 37–45, 2017, doi: 10.32571/ijct.345418.
ISNAD Çapan, Ali et al. “Synthesis, Characterization and Catalytic Properties of Some Transition Metal Complexes of New Phenoxy-Imine Ligand”. International Journal of Chemistry and Technology 1/1 (December 2017), 37-45. https://doi.org/10.32571/ijct.345418.
JAMA Çapan A, Ceyhan G, Sönmez M. Synthesis, characterization and catalytic properties of some transition metal complexes of new phenoxy-imine ligand. Int. J. Chem. Technol. 2017;1:37–45.
MLA Çapan, Ali et al. “Synthesis, Characterization and Catalytic Properties of Some Transition Metal Complexes of New Phenoxy-Imine Ligand”. International Journal of Chemistry and Technology, vol. 1, no. 1, 2017, pp. 37-45, doi:10.32571/ijct.345418.
Vancouver Çapan A, Ceyhan G, Sönmez M. Synthesis, characterization and catalytic properties of some transition metal complexes of new phenoxy-imine ligand. Int. J. Chem. Technol. 2017;1(1):37-45.