Photovoltaic, thermal, fluorescence and aggregation properties of non-peripherally metallophthalocyanines bearing four 3,4-dimethoxyphenethoxy substituents

Derya Güngördü Solğun; Mehmet Salih Ağırtaş; Sabit Horoz

doi:10.32571/ijct.687373

Research Article

3,4-dimetoksifentoksi sübstitüenti taĢıyan periferik olmayan metaloftalosiyaninlerin fotovoltaik, termal, floresans ve agregasyon özellikleri

Year 2020, Volume: 4 Issue: 1, 8 - 15, 30.06.2020

Derya Güngördü Solğun Mehmet Salih Ağırtaş Sabit Horoz

https://doi.org/10.32571/ijct.687373

Abstract

Bu çalıĢmada, baĢlangıç materyali olarak non periferik bir ftalonitril bileĢiği hazırlanmıĢtır. Daha sonra bu 3,4- dimetoksifentoksi sübstitüentli non periferal ftalonitril bileĢiği, Co, Zn ve Cu tuzları ile reaksiyona sokuldu. Kolay ve pratik bir metot kullanılarak non periferal ftalosiyanin bileĢikleri hazırlandı. Çinko ftalosiyanin bileĢiğinin floresan spektrumları tetrahidrofuran içinde ölçüldü. Agregasyon çalıĢmaları, non periferal ftalosiyanin bileĢikleri için incelenen konsantrasyon aralığında lambert-beer yasasına uyum göstermiĢtir. Termogravimetrik (TG) analizler bileĢiklerin kararlı olduğunu gösterdi. Bu ftalosiyanin bileĢiklerinin fotovoltaik performansı akım yoğunluk voltajı (J-V) olarak ölçüldü. Hesaplanan güç dönüĢüm etkileri, bu bileĢiklerin, boyaya duyarlı güneĢ pili (DSSC) yapıları için kullanılma potansiyeline sahip olduğunu göstermiĢtir.

Keywords

Fotovoltaik, ftalosiyanin, termal, periferik olmayan, floresan

References

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Photovoltaic, thermal, fluorescence and aggregation properties of non-peripherally metallophthalocyanines bearing four 3,4-dimethoxyphenethoxy substituents

Year 2020, Volume: 4 Issue: 1, 8 - 15, 30.06.2020

Derya Güngördü Solğun Mehmet Salih Ağırtaş Sabit Horoz

https://doi.org/10.32571/ijct.687373

Abstract

In this study, a non-peripheral phthalonitrile compound was prepared as a starting material. Then this 3,4-dimethoxymethoxy substituted non-peripheral phthalonitrile compound was reacted with Co, Zn and Cu salts. Non-peripheral phthalocyanine compounds were prepared using an easy and practical method. The fluorescence spectra of the zinc phthalocyanine compound were measured in tetrahydrofuran. Aggregation studies showed the compliance with the lambert-beer law in the concentration range studied for non-peripheral phthalocyanine compounds. Thermogravimetric (TG) analyses showed that the compounds were stable. The photovoltaic performance of these phthalocyanine compounds was measured as current density-voltage (J-V). The calculated power conversion effects showed that these compounds had the potential to be used for dye-sensitized solar cell (DSSC) structures.

Keywords

Photovoltaic, phthalocyanine, thermal, non-peripheral, fluorescence

References

1. Martín-Gomis, L.; Parejo, C.; Álvarez, J. C.; Fernández-Lázaro, F.; Sastre-Santos, Á. Inorg. Chim. Acta 2017, 468, 327-333.
2. Haroun, A.A.; Diab, H.A.; Hakeim, O.A. Carbohydr. Polym. 2016, 146, 102-108.
3. Xiao, Y.; Zhang, M. R.; Li, J. J.; Pan, G.B. Chem. Phys. Lett. 2017, 687, 317-321.
4. Ağırtaş, M. S.; Güven, M. E.; Gümüş, S.; Özdemir, S.; Dündar, A. Synthetic Met. 2014, 195, 177-184.
5. Torabi, N.; Rahnamanic, A.; Amrollahi, H.; Mirjalili, F.; Sadeghzade, M. A.; Behjat, A. Org. Electron. 2017, 48, 211-216.
6. Zhao, P.; Wang, Z.; Chen, J.; Zhou, Y.; Zhang, F.; Opt. Mater. 2017, 66, 98-105.
7. Huang, W.; Ahlfield, J. M.; Kohl, P. A.; Zhang, X. Electrochim. Acta. 2017,257, 224-232.
8. Klyamera, D. D.; Sukhikha, A. S.; Krasnov, P. O.; Gromilov, S. A.; Morozova, N. B.; Basova, T. V. Appl. Surf. Sci. 2016, 372, 79-86.
9. Fujishiro, R.; Sonoyama, H.; Ide, Y.; Fujimura, T.; Sasai, R.; Nagai, A.; Mori, S.; Kaufman, N. E.M.; Zhou, Z.; Vicente, M. G. H.; Ikeue, T. J. Inorg. Biochem. 2019, 192, 7-16.
10. Yang, H.; Pan, S.; Ma, D.; He, D.; Wang, Y.; Xie, S.; Peng, Y. J. Lumin. 2016, 179, 588-594.
11. Ağırtaş, M. S.; Karatas, C.; Gümüş, S.; Okumuş, V. Z. Anorg. Allg. Chem. 2015, 641, 442-447.
12. Ağırtaş, M. S. Dyes Pigments 2008, 79, 247-251.
13. Sodeifian, G.; Ardestani, N.S.; Sajadian, S. A. Fluid Phase Equilibr. 2019, 494, 61-73.
14. Fukuda, T.; Ishikawa, N. Dyes Pigments 2014, 109, 151-154.
15. Vittal, R.; Ho, K.C. Renew. Sust. Energ. Rev. 2017, 70, 920-935.
16. Güngördü Solğun, D.; Horoz, S.; Ağırtas, M. S. Inorg. Nano-Metal Chem. 2019, 48 (10), 508-514.
17. Huang, H.; Cao, Z.; Li, X.; Zhang, L.; Liu, X.; Zhao, H.; Tan, S. Synthetic Met. 2012, 162, 2316-2321.
18. Osifeko, O.; Nyokong, T. Dyes Pigments 2016, 131, 186-200.
19. Armarego, W. L. F.; Chai, C. L. L. Purification of laboratory chemicals, 7nd ed., Butterwordh Heinemann, Oxford, 2013.
20. Ağırtaş, M. S.; Güngördü Solğun, D.; Özdemir, S.; İzgi, M. S. Chem. Select 2018, 3, 3523-3528.
21. Güzel, E.; Günsel, A.; Tüzün, B.; Yaşa Atmaca, G.; Bilgiçli, A.T.; Erdoğmus, A.; Yarasir, M.N. Polyhedron 2019, 158, 316-324.
22. Yanik, H.; Aydin, D.; Durmuş, M.; Ahsen, V. J. Photochem. Photobiol. A. 2009, 206 (1), 18-26.
23. Erdoğmuş, A.; Durmuş, M.; Uğur, A. L.; Avciata, O.; Avciata, U.; Nyokong, T. Synthetic Met. 2010, 160,1868-1876.
24. Cabir, B.; Yildiko, U.; Agirtas, M. S. J. Coord. Chem. 2019, 72 (17), 2997-3011.
25. Gui, L.; Zhang, Q.; Wang, Y.; Fang, K.; Wang, A.; You, X.; Zhou, L.; Zhou, J.; Wei, S. Inorg. Chem. Commun. 2017, 75, 1-4.
26. Ağırtaş, M. S.; Gümüs, İ.; Okumus, V.; Dundar. A. Z. Anorg. Allg. Chem. 2012, 638 (11), 1868-1872.
27. Urbani, M.; Ragoussi, M. E.; Nazeeruddin, M. K.; Torres, T. Coordin Chem. Rev. 2019, 381, 1-64.
28. Sun, Z.; Fang, S.; Li, F.; Xu, L.; Hu, Y.; Ren, J. J. Photochem. Photobioli. A. 2013, 252, 25-30.
29. Suzuki, A.; Okumura, H.; Yamasaki, Y.; Oku, T. Appl. Surf. Sci. 2019, 488, 586-592.

There are 44 citations in total.

Details

Primary Language	English
Subjects	Chemical Engineering
Journal Section	Research Articles
Authors	Derya Güngördü Solğun This is me 0000-0001-9492-5669 Mehmet Salih Ağırtaş 0000-0003-1296-2066 Sabit Horoz 0000-0002-3238-8789
Publication Date	June 30, 2020
Published in Issue	Year 2020 Volume: 4 Issue: 1

Cite

APA	Güngördü Solğun, D., Ağırtaş, M. S., & Horoz, S. (2020). Photovoltaic, thermal, fluorescence and aggregation properties of non-peripherally metallophthalocyanines bearing four 3,4-dimethoxyphenethoxy substituents. International Journal of Chemistry and Technology, 4(1), 8-15. https://doi.org/10.32571/ijct.687373
AMA	Güngördü Solğun D, Ağırtaş MS, Horoz S. Photovoltaic, thermal, fluorescence and aggregation properties of non-peripherally metallophthalocyanines bearing four 3,4-dimethoxyphenethoxy substituents. Int. J. Chem. Technol. June 2020;4(1):8-15. doi:10.32571/ijct.687373
Chicago	Güngördü Solğun, Derya, Mehmet Salih Ağırtaş, and Sabit Horoz. “Photovoltaic, Thermal, Fluorescence and Aggregation Properties of Non-Peripherally Metallophthalocyanines Bearing Four 3,4-Dimethoxyphenethoxy Substituents”. International Journal of Chemistry and Technology 4, no. 1 (June 2020): 8-15. https://doi.org/10.32571/ijct.687373.
EndNote	Güngördü Solğun D, Ağırtaş MS, Horoz S (June 1, 2020) Photovoltaic, thermal, fluorescence and aggregation properties of non-peripherally metallophthalocyanines bearing four 3,4-dimethoxyphenethoxy substituents. International Journal of Chemistry and Technology 4 1 8–15.
IEEE	D. Güngördü Solğun, M. S. Ağırtaş, and S. Horoz, “Photovoltaic, thermal, fluorescence and aggregation properties of non-peripherally metallophthalocyanines bearing four 3,4-dimethoxyphenethoxy substituents”, Int. J. Chem. Technol., vol. 4, no. 1, pp. 8–15, 2020, doi: 10.32571/ijct.687373.
ISNAD	Güngördü Solğun, Derya et al. “Photovoltaic, Thermal, Fluorescence and Aggregation Properties of Non-Peripherally Metallophthalocyanines Bearing Four 3,4-Dimethoxyphenethoxy Substituents”. International Journal of Chemistry and Technology 4/1 (June 2020), 8-15. https://doi.org/10.32571/ijct.687373.
JAMA	Güngördü Solğun D, Ağırtaş MS, Horoz S. Photovoltaic, thermal, fluorescence and aggregation properties of non-peripherally metallophthalocyanines bearing four 3,4-dimethoxyphenethoxy substituents. Int. J. Chem. Technol. 2020;4:8–15.
MLA	Güngördü Solğun, Derya et al. “Photovoltaic, Thermal, Fluorescence and Aggregation Properties of Non-Peripherally Metallophthalocyanines Bearing Four 3,4-Dimethoxyphenethoxy Substituents”. International Journal of Chemistry and Technology, vol. 4, no. 1, 2020, pp. 8-15, doi:10.32571/ijct.687373.
Vancouver	Güngördü Solğun D, Ağırtaş MS, Horoz S. Photovoltaic, thermal, fluorescence and aggregation properties of non-peripherally metallophthalocyanines bearing four 3,4-dimethoxyphenethoxy substituents. Int. J. Chem. Technol. 2020;4(1):8-15.

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