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A systematic study on adsorptive removal of arsenic using low cost adsorbents with or without the presence of NOM

Year 2023, , 117 - 130, 23.06.2023
https://doi.org/10.58559/ijes.1205280

Abstract

Arsenic is a toxic and bio-accumulating element in water bodies, especially in drinking water sources.One of the methods used to remove arsenic from drinking water is adsorption. NOM (natural organic matter), which is ubiquitous in natural aquatic environments, can inhibit arsenic adsorption by competing with arsenic for adsorbent surface sites. The main objectives of this study were to investigate the competitive adsorption between NOM and arsenic using low-cost adsorbents. For this purpose, batch adsorption experiments were carried out in synthetic and natural water using pumice, steel slag and red mud as low cost adsorbents.The highest arsenic removal efficiencies obtained with steel slag, pumice and red mud were 95, 95 and 50 %, respectively without the presence of NOM. The results showed that the presence of NOM caused a significant reduction in arsenic adsorption for all tested adsorbents and 20-30% less arsenic removal efficiency was obtained in natural water compared to the removal efficiencies obtained in synthetic water. The maximum adsorption capacities obtained in synthetic water with all tested adsorbents vary between 1.6 -3.05 mgAs/g, while the maximum adsorption capacities obtained in natural water vary between 0.9-1.2 mgAs/g. All these findings indicate that NOM can hinder the uptake of arsenic by all tested adsorbents. Moreover, the arsenic adsorption in natural water were modelled by Langmuir, Freundlich and modified Freundlich. The results showed that the arsenic adsorption data were well fitted by modified Freundlich isotherm with R2 values between 0.87 and 0.90.

Supporting Institution

TUBITAK

Thanks

This work was supported by The Scientific and Technological Research Council of Turkey (TUBITAK). The authors would like to thank TUBITAK 2209 Programme.

References

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  • [9] Bingül Z. The use of waste green tea leaves for crystal viyole adsorption: kinetic, equilibrium and thermodynamics studies. Journal of the Institute of Science and Technology 2021; 11(4): 2645-2659.
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  • [18] Aykut Senel B, Ozgur C, Kaplan Bekaroglu SS, Ates N. Removal of Natural Organic Matter by Using Original and Chemically Modified Adsorbents. The 2nd International Conference on Environmental Science and Applications, Seoul, 2021.
  • [19] Yigit NO, Tozum S. Removal of Selenium Species from Waters Using Various Surface-Modified Natural Particles and WasteMaterials. Clean – Soil, Air, Water 2012; 40 (7): 735–745.
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  • [23] Redman AD, Macalady DL, Ahmann D. Natural Organic Matter Affects Arsenic Speciation and Sorption onto Hematite. Environmental Science Technology 2002; 36: 2889-2896.
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  • [26] Öztel MD, Akbal F, Altaş L. Arsenite removal by adsorption onto iron oxide-coated pumice and sepiolite. Environmental Earth Science 2015; 73: 4461–447.
  • [27] Liu G, Zhang X, Talley JW, Neal CR, Wang H. Effect of NOM on arsenic adsorption by TiO2 in simulated As(III)- contaminated raw waters. Water Research 2008;42: 2309-2319.
  • [28] Mahoutian M, Chaallal O, Shao Y. Pilot production of steel slag masonry blocks. Canadian Journal of Civil Engineerng 2018; 45(7): 537–546.
  • [29] Nikolić I, Đurović D, Tadić M, Radmilović VV. Radmilović VR. Adsorption kinetics, equilibrium, and thermodynamics of Cu2+ on pristine and alkali activated steel slag. Chemical Engineering Communications 2020; 207 (9): 1278–1297.
  • [30] Pereira PAL, Dutra AJB, Martins AH. Adsorptive removal of arsenic from river waters using pisolite. Minerals Engineering 2007; 20: 52–59.
  • [31] Arıkan S. Investigation of Arsenic Adsorption Performance of the Modified Natural Materials, Ph. D. Thesis, Dokuz Eylul University, 2016.
  • [32] Velazquez-Jimenez LH, Arcibar-Orozco JA, Rangel-Mendez JR. Overview of As(V) adsorption on Zr- functionalized activated carbon for aqueous streams remediation. Journal of Environmental Managament 2018; 212: 121–130.
Year 2023, , 117 - 130, 23.06.2023
https://doi.org/10.58559/ijes.1205280

Abstract

References

  • [1] Hao L, Liu M, Wang N, Li G. A critical review on arsenic removal from water using iron-based adsorbents. RSC Advances 2018; 8: 39545–39560.
  • [2] Elizalde-González M. P, Mattusch J, Einicke WD, Wennrich R. Sorption on natural solids for arsenic removal. Chemical Engineering Journal 2001; 81: 187-195.
  • [3] World Health Organization (WHO) 1993. Guidelines for drinking water quality, vol 1, 2nd edn. WHO, Geneva.
  • [4] United States Environmental Protection Agency (USEPA) 2013. Arsenic in drinking water. http://water.epa.gov/lawsregs/rulesregs/sdwa/arsenic/index.cfm. Accessed 14 November 2022.
  • [5] Turkish Ministry of Health, Regulation Concerning Water Intended for Human Consumption, Official News Paper, No. 25730, Ankara, Turkey, 2005.
  • [6] Tözüm Akgül S, Kaplan Bekaroğlu ŞŞ. Removal of Arsenic from water with Low Cost and Environmentally- benign Adsorbents. Journal of the Institute of Science and Technology 2022; 12(3): 1395-1404.
  • [7] Kumar R, Patel M, Singh P, Bundschuh J, Pittman CU, Trakal L, Mohan D. Emerging technologies for arsenic removal from drinking water in rural and peri-urban areas: Methods, experience from, and options for Latin America. Science of the Total Environment 2019; 694, 133427.
  • [8] Mohan D, Pittman CU. Arsenic removal from water/wastewater using adsorbents-Ac critical review. Journal of Hazardous Materials 2007; 142, 1-53.
  • [9] Bingül Z. The use of waste green tea leaves for crystal viyole adsorption: kinetic, equilibrium and thermodynamics studies. Journal of the Institute of Science and Technology 2021; 11(4): 2645-2659.
  • [10] Foroutan R, Mohammadi R, Adeleye AS, Farjadfard S, Esvandi Z, Arfaeinia H, Sorial GA, Ramavandi B, Sahebi S. Efficient arsenic(V) removal from con-taminated water using natural clay and clay composite adsorbents. Environmental Science and Pollution Research 2019; 2: 29748–29762.
  • [11] Kırkan B, Bekaroğlu M. 2019. Removal of Arsenate (V) by Adsorption Process from Aqueous Media Using Modified Pumice. Süleyman Demirel University Journal of Natural and Applied Sciences 2019; 23(2): 356-366.
  • [12] Balsamo M, Di Natale F, Erto A, Lancia A, Montagnaro F, Santoro L. Arsenate removal from synthetic wastewater by adsorption onto fly ash. Desalination 2010; 263: 58-63.
  • [13] Genc-Fuhrman H, Bergnhoj H, McConchie D. Arsenate removal from water using sand-red mud columns. Water Research 2005; 39: 2944–2954.
  • [14] Chiban M, Zerbet M, Carja G, Sinan F. Application of low-cost adsorbents for arsenic removal: A review. Journal of Environmental Chemistry and Ecotoxicology 2012; 4(5): 91-102.
  • [15] Zhang S, Liu C, Luan Z, Peng X, Ren H, Wang J. Arsenate removal from aqueous solutions using modified red mud. Journal of Hazardous Materials 2008; 152: 486–492.
  • [16] Far LB, Souri B, Heidari M, Khoshnavazi R. Evaluation of iron and manganese-coated pumice application fort he removal of As(V) from aqueous solutions. Iranian Journal of Environmental Health Sciences and Engineering 2012; 9.
  • [17] Lekić BM, Marković DD, Rajaković-Ognjanović VN, Ɖukić AR, Rajaković LV. Arsenic Removal from Water Using Industrial By-Products. Hindawi Publishing Corporation Journal of Chemistry 2013.
  • [18] Aykut Senel B, Ozgur C, Kaplan Bekaroglu SS, Ates N. Removal of Natural Organic Matter by Using Original and Chemically Modified Adsorbents. The 2nd International Conference on Environmental Science and Applications, Seoul, 2021.
  • [19] Yigit NO, Tozum S. Removal of Selenium Species from Waters Using Various Surface-Modified Natural Particles and WasteMaterials. Clean – Soil, Air, Water 2012; 40 (7): 735–745.
  • [20] Mouelhi M, Giraudet S, Amrane A, Hamrouni B. Competitive adsorption between fluoride and natural organic matter onto activated alümina. Environmental Technology 2016; 1-11.
  • [21] Otero-Fariña A, Fiol S, Arce F, Antelo J. Effects of natural organic matter on the binding of arsenate and copper onto goethite. Chemical Geology 2017; 459: 119–128.
  • [22] Weng L, Van Riemsdijk WH, Hiemstra T. Effects of Fulvic and Humic Acids on Arsenate Adsorption to Goethite: Experiments and Modeling. Environmental Science Technology 2009;43: 7198-7204.
  • [23] Redman AD, Macalady DL, Ahmann D. Natural Organic Matter Affects Arsenic Speciation and Sorption onto Hematite. Environmental Science Technology 2002; 36: 2889-2896.
  • [24] Öztürk M. Arsenic Treatment in Drinking Water Supplies. Ministry of Environment and Urbanization, 2017 Ankara. http://www.cevresehirkutuphanesi.com/assets/files/slider_pdf/nsUI8wIeDbPq.pdf
  • [25] APHA (American Public Health Association),Standard Methods for the Examination of Water and Wastewater, 20th ed., American Public Health Association, Washington, D.C., 1998.
  • [26] Öztel MD, Akbal F, Altaş L. Arsenite removal by adsorption onto iron oxide-coated pumice and sepiolite. Environmental Earth Science 2015; 73: 4461–447.
  • [27] Liu G, Zhang X, Talley JW, Neal CR, Wang H. Effect of NOM on arsenic adsorption by TiO2 in simulated As(III)- contaminated raw waters. Water Research 2008;42: 2309-2319.
  • [28] Mahoutian M, Chaallal O, Shao Y. Pilot production of steel slag masonry blocks. Canadian Journal of Civil Engineerng 2018; 45(7): 537–546.
  • [29] Nikolić I, Đurović D, Tadić M, Radmilović VV. Radmilović VR. Adsorption kinetics, equilibrium, and thermodynamics of Cu2+ on pristine and alkali activated steel slag. Chemical Engineering Communications 2020; 207 (9): 1278–1297.
  • [30] Pereira PAL, Dutra AJB, Martins AH. Adsorptive removal of arsenic from river waters using pisolite. Minerals Engineering 2007; 20: 52–59.
  • [31] Arıkan S. Investigation of Arsenic Adsorption Performance of the Modified Natural Materials, Ph. D. Thesis, Dokuz Eylul University, 2016.
  • [32] Velazquez-Jimenez LH, Arcibar-Orozco JA, Rangel-Mendez JR. Overview of As(V) adsorption on Zr- functionalized activated carbon for aqueous streams remediation. Journal of Environmental Managament 2018; 212: 121–130.
There are 32 citations in total.

Details

Primary Language English
Subjects Environmental Engineering
Journal Section Research Article
Authors

Seda Tözüm Akgül 0000-0002-4150-6046

İbrahim Yıldıran 0000-0003-2291-4578

Turgut Erdem 0000-0002-2524-7005

Nuray Ateş 0000-0002-8923-4852

Şehnaz Şule Bekaroğlu 0000-0003-0917-7219

Publication Date June 23, 2023
Submission Date November 18, 2022
Acceptance Date April 6, 2023
Published in Issue Year 2023

Cite

APA Tözüm Akgül, S., Yıldıran, İ., Erdem, T., Ateş, N., et al. (2023). A systematic study on adsorptive removal of arsenic using low cost adsorbents with or without the presence of NOM. International Journal of Energy Studies, 8(2), 117-130. https://doi.org/10.58559/ijes.1205280
AMA Tözüm Akgül S, Yıldıran İ, Erdem T, Ateş N, Bekaroğlu ŞŞ. A systematic study on adsorptive removal of arsenic using low cost adsorbents with or without the presence of NOM. Int J Energy Studies. June 2023;8(2):117-130. doi:10.58559/ijes.1205280
Chicago Tözüm Akgül, Seda, İbrahim Yıldıran, Turgut Erdem, Nuray Ateş, and Şehnaz Şule Bekaroğlu. “A Systematic Study on Adsorptive Removal of Arsenic Using Low Cost Adsorbents With or Without the Presence of NOM”. International Journal of Energy Studies 8, no. 2 (June 2023): 117-30. https://doi.org/10.58559/ijes.1205280.
EndNote Tözüm Akgül S, Yıldıran İ, Erdem T, Ateş N, Bekaroğlu ŞŞ (June 1, 2023) A systematic study on adsorptive removal of arsenic using low cost adsorbents with or without the presence of NOM. International Journal of Energy Studies 8 2 117–130.
IEEE S. Tözüm Akgül, İ. Yıldıran, T. Erdem, N. Ateş, and Ş. Ş. Bekaroğlu, “A systematic study on adsorptive removal of arsenic using low cost adsorbents with or without the presence of NOM”, Int J Energy Studies, vol. 8, no. 2, pp. 117–130, 2023, doi: 10.58559/ijes.1205280.
ISNAD Tözüm Akgül, Seda et al. “A Systematic Study on Adsorptive Removal of Arsenic Using Low Cost Adsorbents With or Without the Presence of NOM”. International Journal of Energy Studies 8/2 (June 2023), 117-130. https://doi.org/10.58559/ijes.1205280.
JAMA Tözüm Akgül S, Yıldıran İ, Erdem T, Ateş N, Bekaroğlu ŞŞ. A systematic study on adsorptive removal of arsenic using low cost adsorbents with or without the presence of NOM. Int J Energy Studies. 2023;8:117–130.
MLA Tözüm Akgül, Seda et al. “A Systematic Study on Adsorptive Removal of Arsenic Using Low Cost Adsorbents With or Without the Presence of NOM”. International Journal of Energy Studies, vol. 8, no. 2, 2023, pp. 117-30, doi:10.58559/ijes.1205280.
Vancouver Tözüm Akgül S, Yıldıran İ, Erdem T, Ateş N, Bekaroğlu ŞŞ. A systematic study on adsorptive removal of arsenic using low cost adsorbents with or without the presence of NOM. Int J Energy Studies. 2023;8(2):117-30.