Thermodynamics of Ethanol + Water + 2-Propanol mixture at the range of temperature 288.15-323.15 K

Year 2018, Volume: 21 Issue: 2, 82 - 92, 30.05.2018

Safira Barros Rebecca S. Andrade Miguel Iglesias

https://doi.org/10.5541/ijot.303999

Cited By: 2

Abstract

The packing
properties of hydroxylic chemicals is very unusual, however these substances
find extensive application in food and alcoholic beverage industry. When short
alcohols are mixed with water, the entropy of the final system increases far
less than we could expected for an ideal solution of ramdomly interacting
molecules. Experimental works on thermodynamics helps to understand how
hydrophobic headgroups of alcohol molecules in aqueous media cluster together.
To this aim, the densities and ultrasonic velocity of the ternary mixtures
ethanol + water + 2-propanol at 288.15-323.15 K and atmospheric pressure, have
been measured over the whole concentration range, due to the importance of the
2-propanol among the flavor compounds contained into spirit beverages. The
experimental data have been analyzed in terms of different theoretical models,
an adequate agreement between the experimental and predicted values both in
magnitude and sign being obtained, despite the high non-ideal trend. The
obtained experimental values indicate varying extent of interstitial
accommodation among unlike molecules with strong influence of steric hindrance
among aliphatic ends.

Keywords

Densities, ultrasonic velocities, derived properties, mixture, estimation procedure

References

• M. Gaiser, G. M. Bell, A. W. Lim, N. A. Roberts, D. B. F. Faraday, R. A. Schultz, R. Grob, “Computer simulation of a continuous whisky still,” J. Food Eng., 51, 27-31, 2002.
• C. A. Faúndez, J. O. Valderrama, V. H. Alvarez, “Phase equilibrium in binary aqueous mixtures of interest in alcoholic distillation using a modified PSRK equation of state,” J. Phase Eq. and Diffusion, 25, 230-236, 2004.
• C. A. Faúndez, J. O. Valderrama, “Phase equilibrium modeling in binary mistures found in wine and must distillation,”J. Food Eng., 63, 577-583, 2004.
• O. Perez, L. Zumalacarregui, O. Gozá, “Simplificaciones en el Cálculo de Columnas de Destilación Alcohólica,” Inf. Tecnol., 21, 103-112, 2010.
• J. Sacher, L. García-Llobodanin, F. López, H. Segura, J. R. Pérez-Correa, “Dynamic modeling and simulation of an alembic pear wine distillation,” Food Bioprod. Process., 91, 447-456, 2013.
• C. A. Faúndez, G. A. Ramírez, J. O. Valderrama, “Thermodynamic consistency of low pressure equilibrium data of water+ congener mixtures using a versatile equation of state,” J. Taiwan Inst. Chem. Eng., 68, 15-22, 2016.
• J. M. Resa, C. Gonzalez, J. M. Goenaga, M. Iglesias, “Density, Refractive Index, and Speed of Sound at 298.15 K and Vapor-Liquid Equilibria at 101.3 kPa for Binary Mixtures of Ethyl Acetate + 1-Pentanol,” J. Chem. Eng. Data, 49, 804-808, 2004a.
• J. M. Resa, C. Gonzalez, J. M. Goenaga, M. Iglesias, “Influence of temperature on the volumetric properties of ethanol + water + 1–pentanol,” J. Serbian Chem. Soc., 69, 1073-1097, 2004b.
• J. M. Resa, C. Gonzalez, J. M. Goenaga, M. Iglesias, “Temperature Dependence of Excess Molar Volumes of Ethanol + Water + Ethyl Acetate,” J. Sol. Chem. 33, 169-198, 2004c.
• J. M. Goenaga, R. Gonzalez-Olmos, M. Iglesias J. M. Resa, “Measurement and modelling of phase equilibria for ethanol+water+1-pentanol at isobaric condition,” Korean J. Chem. Eng., 23, 631-637, 2006.
• J. M. Resa, J. M. Goenaga, M. Iglesias, R. Gonzalez-Olmos, D. Pozuelo, “Liquid-liquid equilibrium diagrams of ethanol + water + (ethyl acetate or 1-pentanol) at several temperatures,”,J. Chem. Eng. Data, 51, 1300-1305, 2006a.
• J. M. Resa, J. M. Goenaga, J. Lanz, M. Iglesias, “ Vapor-liquid equilibrium of binary mixtures containing Ethyl acetate + 2-methyl-1-propanol and Ethyl acetate + 2-methyl-1-butanol at 101.3 kPa.,”, J. Chem. Eng. Data, 51, 595-598, 2006b.
• M. Iglesias, B. Orge, M. Dominguez, J. Tojo, “Mixing properties of the binary mixtures of acetone, methanol, ethanol, and 2-butanone at 298.15 K,” Phys. Chem. Liq., 37, 9-29, 1998.
• W. Schaaffs, Molekularakustic; eine Einfuehrung in die Zusammenhaenge zwischen Ultraschall und Molekuelstruktur in Fluessigkeiten und Gasen, ed. by Springer Verlag, Bonn, 1963.
• TRC Thermodynamic Tables, Thermodynamic Research Center, Texas A&M University, College Station, TX, 1994.
• J. A. Riddick, W. B. Bunger, T. K. Sakano, Organic Solvents, Techniques of Chemistry, 4th ed., Vol. 2, ed. by Wiley-Interscience, New York, 1986.
• M. Iglesias, A. Torres, R. Gonzalez-Olmos, D. Salvatierra, “Effect of temperature on mixing thermodynamics of a new ionic liquid: 2-hydroxy ethylammonium formate (2-HEAF) + short hydroxylic solvents,” J. Chem. Thermodyn., 40, 119-133, 2008.
• H. Iloukhani, B. Samiey, M. A. Moghaddasi, “Speeds of sound, isentropic compressibilities, viscosities and excess molar volumes of binary mixtures of methylcyclohexane + 2-alkanols or ethanol at T = 298.15 K,” J. Chem. Thermodyn., 38, 190-200, 2006.
• V. A. Del Grosso, C. W. Mader, “Speed of Sound in Pure Water,” J. Acous. Soc. Am., 52, 1442, 1972.
• C. Gonzalez, J. M. Resa, J. Lanz, M. Iglesias, “Intermolecular interactions in soybean oil + different organic solvents by ultrasonic velocity measurements,” J. Food Eng., 77, 152-161, 2006.
• T. M. Aminabhavi, M. I. Aralaguppi, Sh. B. Harogoppad, R. H. Balundgri, “Densities, Viscosities, Refractive Indices, and Speeds of Sound for Methyl Acetoacetate + Aliphatic Alcohols (C1–C8),” J. Chem. Eng. Data, 38, 31-39, 1993.
• M. Sovilj, “Densities of Ternary Liquid Systems Containing Aliphatic Alcohols at Various Temperatures,” Bull. Chem. Technol. Macedonia, 18, 41-45, 1999.
• P. Navarro, M. Larriba, S. Garcia, J. Garcia, F. Rodriguez, “Physical properties of binary and ternary mixtures of 2-propanol, water, and 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid,” J. Chem. Eng. Data, 57, 1165-1173, 2012.
• A. Sikorska, N. Ponikwicki, A. Koniecko, B. B. Linde, “Comparative Studies of the Mixing Effect on the Thermal Effusivity, Compressibility, and Molar Volume for Aqueous Solutions of Alcohols,” Int. J. Thermophys., 31, 131-142, 2010.
• J. M. Goenaga, PhD Thesis, Facultad de Farmacia, Universidad del Pais Vasco, 2007.
• H. A. Zarei, F. Jalili, S. Assadi, “Temperature Dependence of the Volumetric Properties of Binary and Ternary Mixtures of Water (1) + Methanol (2) + Ethanol (3) at Ambient Pressure (81.5 kPa),” J. Chem. Eng. Data, 52, 2517-2526, 2007.
• N. Radojkovic, A. Tasic, B. Grozdanic, M. Malic, “Excess volumes of acetone + benzene, acetone + cyclohexane, and acetone + benzene + cyclohexane at 298.15 K,” J. Chem. Thermodyn., 9, 349-352, 1977.
• B. E. Poling, J. M. Prausnitz, J. P. O´Connell, The Properties of Gases and Liquids, 5th ed. McGraw-Hill, New York, 2001.
• G. Soave, “Equilibrium constants from a modified Redlich-Kwong equation of state,” Chem Eng. Sci., 27, 1197-1203, 1972.
• D. Y. Peng, D. B. Robinson, “A New Two-Constant Equation of State,” Ind. Eng. Chem. Fundamentals, 15, 59-64, 1976.
• J. F. Kincaid, H. Eyring, “Free Volumes and Free Angle Ratios of Molecules in Liquids,” J. Chem. Phys., 10, 620-629, 1938.
• M. V. Kaulgud, “Ultrasonic velocity and compressibility in Binary liquid mixtures,” Z. Phys. Chem., 36. 365-375, 1963.
• J. D. Pandey, S. N. Srivastav, “Temperature dependence of some acoustical and thermodynamical properties of letrafluoromethane and methane,” Acoustica, 51, 66, 1982.