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Thermodynamical Study of Alcoholic Solutions of Poly (ethylene glycol) Diacrylate and Poly (ethylene glycol) Dimethacrylate

Year 2012, Volume: 15 Issue: 2, 111 - 117, 17.05.2012

Abstract

With the aim to study the behaviour of polymer solutions, density and ultrasonic velocity of binary mixtures of pentanol with polyethylene glycol diacrylate and polyethylene glycol dimethacrylate have been investigated at 293.15 K, 303.15 K and 313.15 K, under atmospheric pressure. Thermophysical parameters viz. intermolecular free length, internal pressure and pseudo-Grüneisen parameter have been calculated which infer about the interactions and structural changes on mixing pentanol with these polymers. Enthalpy, entropy and Gibbs free energy of activation for viscous flow at different concentrations of polymer solution have been reported. Excess molar volume, deviation in isentropic compressibility, deviation in ultrasonic velocity, excess acoustic impedance and excess molar enthalpy have been calculated and results have been correlated with Redlich-Kister polynomial equation. Density and ultrasonic velocity data have been fitted by third order polynomial equation.

References

  • Ali, A., Tariq, M. (2006). Thermodynamic and Transport Behaviour of Binary Liquid Mixtures of Benzyl Alcohol with Monocyclic Aromatics at 303.15 K. J. Mol. Liqs. 128, 50-55.
  • Ciocirlan, O., Iuliana, O. (2009). Density, viscosity and refractive index of the dimethyl sulfoxide + o-xylene system . J. Serb. Chem. Soc. 74, 317-329.
  • Dumanian, G.A., Dascombe, W., Hong, C., Labadie, K., Garret, K., Sawhney, A.S., Pathak, C.P., Hubbell, J.A., Johnson, P.C. (1995). A New Photopolymerisable Blood Vessel Glue That Seals Human Vessel Anastomoses without Augmenting Thrombogenicity. Plastic and Reconstructive surgery, Plastic and Reconstructive surgery, 95, 901-907.
  • Fort, R.J., Moore, W.R. (1955). Adiabatic Compressibilities of Binary Liquid. Mixtures.Trans.Faraday Soc. 61, 2102-2111. Viscosities and Ultrasonic Speeds of Binary Mixtures Containing 1,2-Dimethoxyethane and an Alkan-l-ol at 298.15 K. J Solution Chem 35, 1587-1606.
  • Kincaid, J.F., Eyring, H. (1937) J.Phys Chem, 41, 249.
  • Parveen, S., Yasmin, M., Gupta, M., Shukla, J.P. (2010). Thermoacoustical and Excess Properties of Binary Mixtures of Ethyl Butyrate with Methanol and Vinyl Acetate. Int. J. of Thermodynamics. 13, 59-66.
  • Perrin, D.D., Armarego, W.L.F. (1988). Purification of Laboratory Chemicals. (3rd ed.). Oxford: Pergamon Press.
  • Prausnitz, J.M. (1969). Molecular Thermodynamics of Fluid Phase Equilibria. (2nd ed.). New Jersy: Prentice Hall Engle Wood Cliffs.
  • Redlich, O., Kister ,A.T. (1984). Thermodynamics of Nonelectrolytic Solutions. Algebraic Representation of Thermodynamic Properties and the Classification of Solutions. Ind. Eng. Chem., 40, 345-348.
  • Singh, K. P., Agarwal, H., Shukla, V.K., Yasmin, M., Gupta, M., Shukla, J.P. (2009). Thermo-acoustical Properties of Peg with Alkoxy Ethanols. J. Pure Appl. Ultrason. 31, 124-130.
  • Singh, S., Parveen, S., Shukla, D., Yasmin, M., Gupta, M., Shukla, J.P. (2011). Ultrasonic and Volumetric Study of N-H Bond Complexes. J. Solution Chem. 40 889-899.
  • Treszczanowicz, A.J., Kiyohara, O., Benson, G.C. (1981). Excess Molar Volumes for n-Alkanes Binary Mixture of Decan-1-ol + n-Pentane, + n-Hexane, + n-Octane, + n- Decane and + n-Hexadecane. J. Chem. Thermodyn., 13 253-260.
  • Yasmin, M.,Gupta, M. (2011). Thermoacoustical Analysis of Solutions of Poly (Ethylene Glycol) 200 through H- Bond Complex Formation. Thermochimica Acta, 518 89-100.
  • Yasmin, M., Gupta, M., Shukla, J. P. (2011). Experimental and Computational Study on Viscosity and Optical Dielectric Constant of Solutions of Poly (ethylene glycol) 200. J. Mol. Liq, 160, 22-29.
  • Yasmin, M., Singh, K.P., Parveen, S., Gupta, M., Shukla, J.P. (2009). Excess Properties of Binary Liquid Mixtures -A Comparative Experimental and Theoretical Study. Acta Physica Polonica A, 115, 890-900.
  • Zafarani-Moattar, M.T., Tohidifar, N. (2008). Vapour- Liquid Equilibria, Density, Speed of Sound, and Viscosity for the System Poly (ethylene glycol) 400 + Ethanol at Different Temperatures. J. Chem. Eng. Data. 53, 785-793.
Year 2012, Volume: 15 Issue: 2, 111 - 117, 17.05.2012

Abstract

References

  • Ali, A., Tariq, M. (2006). Thermodynamic and Transport Behaviour of Binary Liquid Mixtures of Benzyl Alcohol with Monocyclic Aromatics at 303.15 K. J. Mol. Liqs. 128, 50-55.
  • Ciocirlan, O., Iuliana, O. (2009). Density, viscosity and refractive index of the dimethyl sulfoxide + o-xylene system . J. Serb. Chem. Soc. 74, 317-329.
  • Dumanian, G.A., Dascombe, W., Hong, C., Labadie, K., Garret, K., Sawhney, A.S., Pathak, C.P., Hubbell, J.A., Johnson, P.C. (1995). A New Photopolymerisable Blood Vessel Glue That Seals Human Vessel Anastomoses without Augmenting Thrombogenicity. Plastic and Reconstructive surgery, Plastic and Reconstructive surgery, 95, 901-907.
  • Fort, R.J., Moore, W.R. (1955). Adiabatic Compressibilities of Binary Liquid. Mixtures.Trans.Faraday Soc. 61, 2102-2111. Viscosities and Ultrasonic Speeds of Binary Mixtures Containing 1,2-Dimethoxyethane and an Alkan-l-ol at 298.15 K. J Solution Chem 35, 1587-1606.
  • Kincaid, J.F., Eyring, H. (1937) J.Phys Chem, 41, 249.
  • Parveen, S., Yasmin, M., Gupta, M., Shukla, J.P. (2010). Thermoacoustical and Excess Properties of Binary Mixtures of Ethyl Butyrate with Methanol and Vinyl Acetate. Int. J. of Thermodynamics. 13, 59-66.
  • Perrin, D.D., Armarego, W.L.F. (1988). Purification of Laboratory Chemicals. (3rd ed.). Oxford: Pergamon Press.
  • Prausnitz, J.M. (1969). Molecular Thermodynamics of Fluid Phase Equilibria. (2nd ed.). New Jersy: Prentice Hall Engle Wood Cliffs.
  • Redlich, O., Kister ,A.T. (1984). Thermodynamics of Nonelectrolytic Solutions. Algebraic Representation of Thermodynamic Properties and the Classification of Solutions. Ind. Eng. Chem., 40, 345-348.
  • Singh, K. P., Agarwal, H., Shukla, V.K., Yasmin, M., Gupta, M., Shukla, J.P. (2009). Thermo-acoustical Properties of Peg with Alkoxy Ethanols. J. Pure Appl. Ultrason. 31, 124-130.
  • Singh, S., Parveen, S., Shukla, D., Yasmin, M., Gupta, M., Shukla, J.P. (2011). Ultrasonic and Volumetric Study of N-H Bond Complexes. J. Solution Chem. 40 889-899.
  • Treszczanowicz, A.J., Kiyohara, O., Benson, G.C. (1981). Excess Molar Volumes for n-Alkanes Binary Mixture of Decan-1-ol + n-Pentane, + n-Hexane, + n-Octane, + n- Decane and + n-Hexadecane. J. Chem. Thermodyn., 13 253-260.
  • Yasmin, M.,Gupta, M. (2011). Thermoacoustical Analysis of Solutions of Poly (Ethylene Glycol) 200 through H- Bond Complex Formation. Thermochimica Acta, 518 89-100.
  • Yasmin, M., Gupta, M., Shukla, J. P. (2011). Experimental and Computational Study on Viscosity and Optical Dielectric Constant of Solutions of Poly (ethylene glycol) 200. J. Mol. Liq, 160, 22-29.
  • Yasmin, M., Singh, K.P., Parveen, S., Gupta, M., Shukla, J.P. (2009). Excess Properties of Binary Liquid Mixtures -A Comparative Experimental and Theoretical Study. Acta Physica Polonica A, 115, 890-900.
  • Zafarani-Moattar, M.T., Tohidifar, N. (2008). Vapour- Liquid Equilibria, Density, Speed of Sound, and Viscosity for the System Poly (ethylene glycol) 400 + Ethanol at Different Temperatures. J. Chem. Eng. Data. 53, 785-793.
There are 16 citations in total.

Details

Primary Language English
Journal Section Regular Original Research Article
Authors

Maimoona Yasmin

Manisha Gupta This is me

Publication Date May 17, 2012
Published in Issue Year 2012 Volume: 15 Issue: 2

Cite

APA Yasmin, M., & Gupta, M. (2012). Thermodynamical Study of Alcoholic Solutions of Poly (ethylene glycol) Diacrylate and Poly (ethylene glycol) Dimethacrylate. International Journal of Thermodynamics, 15(2), 111-117.
AMA Yasmin M, Gupta M. Thermodynamical Study of Alcoholic Solutions of Poly (ethylene glycol) Diacrylate and Poly (ethylene glycol) Dimethacrylate. International Journal of Thermodynamics. May 2012;15(2):111-117.
Chicago Yasmin, Maimoona, and Manisha Gupta. “Thermodynamical Study of Alcoholic Solutions of Poly (ethylene Glycol) Diacrylate and Poly (ethylene Glycol) Dimethacrylate”. International Journal of Thermodynamics 15, no. 2 (May 2012): 111-17.
EndNote Yasmin M, Gupta M (May 1, 2012) Thermodynamical Study of Alcoholic Solutions of Poly (ethylene glycol) Diacrylate and Poly (ethylene glycol) Dimethacrylate. International Journal of Thermodynamics 15 2 111–117.
IEEE M. Yasmin and M. Gupta, “Thermodynamical Study of Alcoholic Solutions of Poly (ethylene glycol) Diacrylate and Poly (ethylene glycol) Dimethacrylate”, International Journal of Thermodynamics, vol. 15, no. 2, pp. 111–117, 2012.
ISNAD Yasmin, Maimoona - Gupta, Manisha. “Thermodynamical Study of Alcoholic Solutions of Poly (ethylene Glycol) Diacrylate and Poly (ethylene Glycol) Dimethacrylate”. International Journal of Thermodynamics 15/2 (May 2012), 111-117.
JAMA Yasmin M, Gupta M. Thermodynamical Study of Alcoholic Solutions of Poly (ethylene glycol) Diacrylate and Poly (ethylene glycol) Dimethacrylate. International Journal of Thermodynamics. 2012;15:111–117.
MLA Yasmin, Maimoona and Manisha Gupta. “Thermodynamical Study of Alcoholic Solutions of Poly (ethylene Glycol) Diacrylate and Poly (ethylene Glycol) Dimethacrylate”. International Journal of Thermodynamics, vol. 15, no. 2, 2012, pp. 111-7.
Vancouver Yasmin M, Gupta M. Thermodynamical Study of Alcoholic Solutions of Poly (ethylene glycol) Diacrylate and Poly (ethylene glycol) Dimethacrylate. International Journal of Thermodynamics. 2012;15(2):111-7.