Research Article
BibTex RIS Cite
Year 2023, Volume: 26 Issue: 1, 1 - 10, 14.03.2023
https://doi.org/10.5541/ijot.1136209

Abstract

References

  • O. Owoyomi, J. Ige, and O.J.C.S.J. Soriyan, "Thermodynamics of micellization of n-alkyltriphenylphosphonium bromides: a conductometric study," Chem Sci J, 25, 1-13. 2011.
  • A. Mehrdad and M.J.T.J.o.C.T. Hajikarimi, "Conductometric investigation of ceftriaxone disodium in aqueous solutions of 1-propanol and 2-propanol," J Chem Thermodyn, 142, 105972. 2020.
  • Y. O Al-Allaf, M. Y Al-Tamer, and M.J.R.J.o.S. N Abdulfattah, "Conductometric studies for association reaction of some amino acid complexes in water," Raf. J. Sci., 24, 45-60. 2013.
  • V. Sokol, R. Tomaš, M. Višić, and I.J.J.o.s.c. Tominić, "Conductometric study of potassium bromide in 2-butanol+ water mixtures," J Solution Chem, 35, 1687-1698. 2006.
  • F.M.J.T.E.P.O.S.T.E. Al-Healy and Mathematics, "Electrical Conductance Study of Glutamic Acid Complex with [Mn (ΙΙ)] in Different Solvents and Temperatures," EPSTEM, 11, 20-28. 2020.
  • D.M. Murad, A.Z. Al-Rubaie, and A.A. Al-Najar. (2019). Conductametric studies of some organotellurium (IV) trihalides. in J Phys: Conference Series. IOP Publishing.
  • R. Thakur, R. Sharma, and A. Sharma. (2020). Molecular interactions analysis of some aluminium salts in binary aqueous solutions of tetrahydrofuran (THF): Acoustic and Conductometric approach. in J Phys: Conference Series. IOP Publishing.
  • R.T.Morrison and R.N. BoYd, (2002). Organic Chemistry, Asoke K. Ghosh, Prentice-Hall of India Private Limited, M-97, Connaught Circus, New DelhF110001 and Printed by Jay Print Pack Private Limited, New Delhi-10015, India
  • R.M. Fuoss and K.-L.J.P.o.t.N.A.o.S. Hsia, "Association of 1-1 salts in water," Pnas, 57, 1550-1557. 1967.
  • M. Haisa, S. Kashino, F. Ikejiri, T. Ohno, and K. Teranishi, "Topochemical studies. VIII. The crystal and molecular sturtures of two polymorphs of 4-formylbenzoic acid," Acta. Crystallogr. B. Struct. Sci. Cryst. Eng. Mater., 32, 857-860. 1976.
  • M. Nandi, J. Mondal, K. Sarkar, Y. Yamauchi, and A. Bhaumik, "Highly ordered acid functionalized SBA-15: a novel organocatalyst for the preparation of xanthenes," Chem comm, 47, 6677-6679. 2011.
  • N. Sunsandee, M. Hronec, M. Štolcová, N. Leepipatpiboon, and U. Pancharoen, "Thermodynamics of the solubility of 4-acetylbenzoic acid in different solvents from 303.15 to 473.15 K," J. Mol. Liq., 180, 252-259. 2013.
  • W. Sun, W. Qu, and L. Zhao, "Solubilities of 4-Formylbenzoic Acid in Ethanoic Acid, Water, and Ethanoic Acid/Water Mixtures with Different Compositions from (303.2 to 473.2) K," J. Chem. Eng. Data., 55, 4476-4478. 2010.
  • N. Sunsandee, S. Suren, N. Leepipatpiboon, M. Hronec, and U. Pancharoen, "Determination and modeling of aqueous solubility of 4-position substituted benzoic acid compounds in a high-temperature solution," Fluid Ph. Equilibria, 338, 217-223. 2013.
  • H. Kabir, R.K. Nath, K. Hossain, and M.M.Z. Hyder, "Conductimetric Properties of Benzoic Acid in Water and 1-Propanol Mixtures at the Temperatures from 298.15 to 313.15 K," Orient. J. Chem., 34, 196-202. 2018.
  • N. Raghavendra, "Conductometric study on the benzoic acid in water+ methanol systems at different solution temperatures," Asian J. Nanosci. Mater, 2, 350-355. 2019.
  • G. Franchini, E. Ori, C. Preti, L. Tassi, and G. Tosi, "A conductometric study of dissociation of picric acid in 2-methoxyethanol and 1, 2-ethanediol from− 10 to 80° C," Can. J. Chem., 65, 722-726. 1987.
  • M.W. Farrar and R. Levine, "The oxidation of certain ketones to acids by alkaline hypochlorite solution," J. Am. Chem. Soc. 71, 1496-1496. 1949.
  • N.K.R. Shekhani, "Dissociation constants of Proline and Valine in solvent mixture," Indian J. Chem, 80-82. , 2000.
  • R.M. Fuoss and K.-L. Hsia, "Association of 1-1 salts in water," PNAS, 57, 1550. 1967.
  • R. Fernandez-Prini, "Conductance of electrolyte solutions. A modified expression for its concentration dependence," J. Chem. Soc. Faraday Trans., 65, 3311-3313. 1969.
  • K.N. Kaka, A.A. Al-Najar, and W.M. Hamad, "The Audio Frequency Conductance Study of Some Metal Succinate Salts in Aqueous Medium at Different Temperatures (Part Ii: Zinc, Nickel and Cobalt Succinates)," Sjuoz, 1, 780-790. 2013.
  • K.N.K. Baban, (2008). AFC study of some metal succinate salts in aqueous medium at different temperature, Koya Universuty. Ph.D. thesis, College of Science, Chemistry department
  • V. Sokol, I. Tominić, R. Tomaš, and M. Višić, "Thermodynamics of the Association Reaction of Li+ and Br–Ions in 2 Butanol+ Water Mixtures from Conductivity Measurements," Croatica chemica acta, 78, 43-47. 2005.
  • A. Sepsey, É. Horváth, M. Catani, and A.J.J.o.C.A. Felinger, "The correctness of van’t Hoff plots in chiral and achiral chromatography," 1611, 460594. 2020.
  • M.F. Bakr, "Investigation of magnesium (II), calcium (II) and barium (II) complexes in Aqueous solution." 2005.

Dissociation Constant Studies of 2-Substituted 4-Formylbenzoic Acid based on Conductometric Parameters using Fuoss-Hsia Theories

Year 2023, Volume: 26 Issue: 1, 1 - 10, 14.03.2023
https://doi.org/10.5541/ijot.1136209

Abstract

The dissociation constant is a quantitative measure of the strength of an acid in solution. This study examines dissociation constant for the series substituted acids like Ortho-alkoxy-4-formylbenzoic acid. The use of (2-methoxy ethanol) as a solvent contributed to the study expected to form free ions or solvent separated ion pair which has been studied with the use conductometric method at different temperatures ranged from 293.15 to 318.15K. The study aims at figuring out dissociation constant, equivalent conductance at infinity dilution, and Walden product by minimization technique using Fuoss-Hsia for both (Modified and Complete) equations. It has been found in the results that the calculated values based on statistical sum square (different between practical and theoretical values) is equivalent conductance at infinity dilution and dissociation constant. It has also been observed that increase the temperature leads to the increase of the molar conductance at infinity dilution, and the increase in association. Moreover, the substituted alkoxy group also affected dissociation of compounds. In this study, the thermodynamic parameters (Ho, Go and So) have also been evaluated and discussed. Finally, the effect of substituent groups on rate of dissociation was studied and explained with agreement to the principles of mesomeric(M) and Inductive effect(I) of substituent groups on dissociation constant.

References

  • O. Owoyomi, J. Ige, and O.J.C.S.J. Soriyan, "Thermodynamics of micellization of n-alkyltriphenylphosphonium bromides: a conductometric study," Chem Sci J, 25, 1-13. 2011.
  • A. Mehrdad and M.J.T.J.o.C.T. Hajikarimi, "Conductometric investigation of ceftriaxone disodium in aqueous solutions of 1-propanol and 2-propanol," J Chem Thermodyn, 142, 105972. 2020.
  • Y. O Al-Allaf, M. Y Al-Tamer, and M.J.R.J.o.S. N Abdulfattah, "Conductometric studies for association reaction of some amino acid complexes in water," Raf. J. Sci., 24, 45-60. 2013.
  • V. Sokol, R. Tomaš, M. Višić, and I.J.J.o.s.c. Tominić, "Conductometric study of potassium bromide in 2-butanol+ water mixtures," J Solution Chem, 35, 1687-1698. 2006.
  • F.M.J.T.E.P.O.S.T.E. Al-Healy and Mathematics, "Electrical Conductance Study of Glutamic Acid Complex with [Mn (ΙΙ)] in Different Solvents and Temperatures," EPSTEM, 11, 20-28. 2020.
  • D.M. Murad, A.Z. Al-Rubaie, and A.A. Al-Najar. (2019). Conductametric studies of some organotellurium (IV) trihalides. in J Phys: Conference Series. IOP Publishing.
  • R. Thakur, R. Sharma, and A. Sharma. (2020). Molecular interactions analysis of some aluminium salts in binary aqueous solutions of tetrahydrofuran (THF): Acoustic and Conductometric approach. in J Phys: Conference Series. IOP Publishing.
  • R.T.Morrison and R.N. BoYd, (2002). Organic Chemistry, Asoke K. Ghosh, Prentice-Hall of India Private Limited, M-97, Connaught Circus, New DelhF110001 and Printed by Jay Print Pack Private Limited, New Delhi-10015, India
  • R.M. Fuoss and K.-L.J.P.o.t.N.A.o.S. Hsia, "Association of 1-1 salts in water," Pnas, 57, 1550-1557. 1967.
  • M. Haisa, S. Kashino, F. Ikejiri, T. Ohno, and K. Teranishi, "Topochemical studies. VIII. The crystal and molecular sturtures of two polymorphs of 4-formylbenzoic acid," Acta. Crystallogr. B. Struct. Sci. Cryst. Eng. Mater., 32, 857-860. 1976.
  • M. Nandi, J. Mondal, K. Sarkar, Y. Yamauchi, and A. Bhaumik, "Highly ordered acid functionalized SBA-15: a novel organocatalyst for the preparation of xanthenes," Chem comm, 47, 6677-6679. 2011.
  • N. Sunsandee, M. Hronec, M. Štolcová, N. Leepipatpiboon, and U. Pancharoen, "Thermodynamics of the solubility of 4-acetylbenzoic acid in different solvents from 303.15 to 473.15 K," J. Mol. Liq., 180, 252-259. 2013.
  • W. Sun, W. Qu, and L. Zhao, "Solubilities of 4-Formylbenzoic Acid in Ethanoic Acid, Water, and Ethanoic Acid/Water Mixtures with Different Compositions from (303.2 to 473.2) K," J. Chem. Eng. Data., 55, 4476-4478. 2010.
  • N. Sunsandee, S. Suren, N. Leepipatpiboon, M. Hronec, and U. Pancharoen, "Determination and modeling of aqueous solubility of 4-position substituted benzoic acid compounds in a high-temperature solution," Fluid Ph. Equilibria, 338, 217-223. 2013.
  • H. Kabir, R.K. Nath, K. Hossain, and M.M.Z. Hyder, "Conductimetric Properties of Benzoic Acid in Water and 1-Propanol Mixtures at the Temperatures from 298.15 to 313.15 K," Orient. J. Chem., 34, 196-202. 2018.
  • N. Raghavendra, "Conductometric study on the benzoic acid in water+ methanol systems at different solution temperatures," Asian J. Nanosci. Mater, 2, 350-355. 2019.
  • G. Franchini, E. Ori, C. Preti, L. Tassi, and G. Tosi, "A conductometric study of dissociation of picric acid in 2-methoxyethanol and 1, 2-ethanediol from− 10 to 80° C," Can. J. Chem., 65, 722-726. 1987.
  • M.W. Farrar and R. Levine, "The oxidation of certain ketones to acids by alkaline hypochlorite solution," J. Am. Chem. Soc. 71, 1496-1496. 1949.
  • N.K.R. Shekhani, "Dissociation constants of Proline and Valine in solvent mixture," Indian J. Chem, 80-82. , 2000.
  • R.M. Fuoss and K.-L. Hsia, "Association of 1-1 salts in water," PNAS, 57, 1550. 1967.
  • R. Fernandez-Prini, "Conductance of electrolyte solutions. A modified expression for its concentration dependence," J. Chem. Soc. Faraday Trans., 65, 3311-3313. 1969.
  • K.N. Kaka, A.A. Al-Najar, and W.M. Hamad, "The Audio Frequency Conductance Study of Some Metal Succinate Salts in Aqueous Medium at Different Temperatures (Part Ii: Zinc, Nickel and Cobalt Succinates)," Sjuoz, 1, 780-790. 2013.
  • K.N.K. Baban, (2008). AFC study of some metal succinate salts in aqueous medium at different temperature, Koya Universuty. Ph.D. thesis, College of Science, Chemistry department
  • V. Sokol, I. Tominić, R. Tomaš, and M. Višić, "Thermodynamics of the Association Reaction of Li+ and Br–Ions in 2 Butanol+ Water Mixtures from Conductivity Measurements," Croatica chemica acta, 78, 43-47. 2005.
  • A. Sepsey, É. Horváth, M. Catani, and A.J.J.o.C.A. Felinger, "The correctness of van’t Hoff plots in chiral and achiral chromatography," 1611, 460594. 2020.
  • M.F. Bakr, "Investigation of magnesium (II), calcium (II) and barium (II) complexes in Aqueous solution." 2005.
There are 26 citations in total.

Details

Primary Language English
Subjects Physical Chemistry
Journal Section Research Articles
Authors

Kosrat Kaka 0000-0002-6379-9775

Rebaz Omer

Salam Taher This is me 0000-0001-9583-3432

Wali M. Hamad Hamad This is me

Publication Date March 14, 2023
Published in Issue Year 2023 Volume: 26 Issue: 1

Cite

APA Kaka, K., Omer, R., Taher, S., Hamad, W. M. H. (2023). Dissociation Constant Studies of 2-Substituted 4-Formylbenzoic Acid based on Conductometric Parameters using Fuoss-Hsia Theories. International Journal of Thermodynamics, 26(1), 1-10. https://doi.org/10.5541/ijot.1136209
AMA Kaka K, Omer R, Taher S, Hamad WMH. Dissociation Constant Studies of 2-Substituted 4-Formylbenzoic Acid based on Conductometric Parameters using Fuoss-Hsia Theories. International Journal of Thermodynamics. March 2023;26(1):1-10. doi:10.5541/ijot.1136209
Chicago Kaka, Kosrat, Rebaz Omer, Salam Taher, and Wali M. Hamad Hamad. “Dissociation Constant Studies of 2-Substituted 4-Formylbenzoic Acid Based on Conductometric Parameters Using Fuoss-Hsia Theories”. International Journal of Thermodynamics 26, no. 1 (March 2023): 1-10. https://doi.org/10.5541/ijot.1136209.
EndNote Kaka K, Omer R, Taher S, Hamad WMH (March 1, 2023) Dissociation Constant Studies of 2-Substituted 4-Formylbenzoic Acid based on Conductometric Parameters using Fuoss-Hsia Theories. International Journal of Thermodynamics 26 1 1–10.
IEEE K. Kaka, R. Omer, S. Taher, and W. M. H. Hamad, “Dissociation Constant Studies of 2-Substituted 4-Formylbenzoic Acid based on Conductometric Parameters using Fuoss-Hsia Theories”, International Journal of Thermodynamics, vol. 26, no. 1, pp. 1–10, 2023, doi: 10.5541/ijot.1136209.
ISNAD Kaka, Kosrat et al. “Dissociation Constant Studies of 2-Substituted 4-Formylbenzoic Acid Based on Conductometric Parameters Using Fuoss-Hsia Theories”. International Journal of Thermodynamics 26/1 (March 2023), 1-10. https://doi.org/10.5541/ijot.1136209.
JAMA Kaka K, Omer R, Taher S, Hamad WMH. Dissociation Constant Studies of 2-Substituted 4-Formylbenzoic Acid based on Conductometric Parameters using Fuoss-Hsia Theories. International Journal of Thermodynamics. 2023;26:1–10.
MLA Kaka, Kosrat et al. “Dissociation Constant Studies of 2-Substituted 4-Formylbenzoic Acid Based on Conductometric Parameters Using Fuoss-Hsia Theories”. International Journal of Thermodynamics, vol. 26, no. 1, 2023, pp. 1-10, doi:10.5541/ijot.1136209.
Vancouver Kaka K, Omer R, Taher S, Hamad WMH. Dissociation Constant Studies of 2-Substituted 4-Formylbenzoic Acid based on Conductometric Parameters using Fuoss-Hsia Theories. International Journal of Thermodynamics. 2023;26(1):1-10.