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Adsorptive removal of cationic dye from aqueous solutions using Bardakçı clay

Year 2022, Volume 6, Issue 1, 80 - 90, 15.03.2022
https://doi.org/10.31015/jaefs.2022.1.12

Abstract

This study was investigation employed the batch adsorption method using Bardakçı Clay/Van as an adsorbent to remove crystal violent, a cationic dye from an aqueous solution. The effects of pH, adsorbent amount, interaction time and concentration were investigated to determine the optimal adsorption conditions. The optimal adsorption conditions were determined to be pH=6, 0.6 g adsorbent amount, and the adsorption reached equilibrium at the 25th minute. The equilibrium isotherm was determined using the Langmuir, Freundlich and Dubinin–Radushkevich (D–R) adsorption equations. It was discovered to conform to the Langmuir isotherm. In the Dubinin-Radushkevich (D-R) model, the E value was calculated to E< 8 kJmol-1, indicating that the adsorption process occurs physically. Thermodynamic parameters such as enthalpy (ΔHo), Gibbs' free energy (ΔGo) and entropy (ΔSo) were calculated. The adsorption of crystal violet with Bardakçı clay demonstrated that the process was endothermic, occurring both physically and spontaneously.

References

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Year 2022, Volume 6, Issue 1, 80 - 90, 15.03.2022
https://doi.org/10.31015/jaefs.2022.1.12

Abstract

References

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  • Ahmad, W., Khan, A., Ali, N., Khan, S., Uddin, S., Malik, S., . . . Bilal, M. (2021). Photocatalytic degradation of crystal violet dye under sunlight by chitosan-encapsulated ternary metal selenide microspheres. Environmental Science and Pollution Research, 28(7), 8074-8087. doi:https://doi.org/10.1007/s11356-020-10898-7
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  • Aksakal, O., & Ucun, H. (2010). Equilibrium, kinetic and thermodynamic studies of the biosorption of textile dye (Reactive Red 195) onto Pinus sylvestris L. Journal of hazardous materials, 181(1-3), 666-672. doi:https://doi.org/10.1016/j.jhazmat.2010.05.064
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  • Alacabey, İ., Acet, Ö., Önal, B., Dikici, E., Karakoç, V., Gürbüz, F., . . . Odabaşı, M. (2021). Pumice particle interface: a case study for immunoglobulin G purification. Polymer Bulletin, 78(10), 5593-5607. doi:https://doi.org/10.1007/s00289-020-03392-0
  • Alacabey, İ., Kul, A. R., Şakir, E., & Alkan, H. (2020). Van Gölü Doğal Sediment ve Modifiye Sediment Üzerine Krom (III) Adsorpsiyonu (İzoterm ve Termodinamik Analiz Çalışması). Dicle Üniversitesi Mühendislik Fakültesi Mühendislik Dergisi, 11(3), 1225-1232. doi:https://doi.org/10.24012/dumf.731216
  • Alkan, S., Kul, A. R., Alacabey, İ. h., & Erol, N. (2014). Polifenol Oksidaz Enziminin Aktif Karbonla Adsorpsiyonunun İzoterm ve Kinetik Analizi. Dicle Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 3(1), 69-78. Retrieved from https://dergipark.org.tr/tr/download/article-file/1161435
  • Atasoy, N., Mercan, U., Alacabey, İ., & Kul, A. R. (2011). Levels of heavy metals and certain macro elements in potable and tap water at Van City Center. Hacettepe Journal of Biology and Chemistry, 39(4), 391-396. Retrieved from https://dergipark.org.tr/en/download/article-file/1727656
  • Banat, I. M., Nigam, P., Singh, D., & Marchant, R. (1996). Microbial decolorization of textile-dyecontaining effluents: a review. Bioresource technology, 58(3), 217-227. doi:https://doi.org/10.1016/S0960-8524(96)00113-7
  • Bayramoglu, G., Altintas, B., & Arica, M. Y. (2009). Adsorption kinetics and thermodynamic parameters of cationic dyes from aqueous solutions by using a new strong cation-exchange resin. Chemical Engineering Journal, 152(2-3), 339-346. doi:https://doi.org/10.1016/j.cej.2009.04.051
  • Bhatnagar, A., Jain, A., & Mukul, M. (2005). Removal of congo red dye from water using carbon slurry waste. Environmental Chemistry Letters, 2(4), 199-202. doi:https://doi.org/10.1007/s10311-004-0097-0
  • Bhattacharyya, K. G., & Gupta, S. S. (2008). Kaolinite and montmorillonite as adsorbents for Fe (III), Co (II) and Ni (II) in aqueous medium. Applied Clay Science, 41(1-2), 1-9. doi:https://doi.org/10.1016/j.clay.2007.09.005
  • Biçer, Y. (2019). Bardakçı/Van kilinin bazı fizikokimyasal ve mineralojik özellikleri üzerine ısıl işlemin etkisi. Yüzüncü Yıl University, Graduate School of Natural and Applied Sciences Department of Chemistry, Van, Master thesis.,
  • Caliskan, N., Kul, A. R., Alkan, S., Sogut, E. G., & Alacabey, I. (2011). Adsorption of Zinc (II) on diatomite and manganese-oxide-modified diatomite: A kinetic and equilibrium study. Journal of hazardous materials, 193, 27-36. doi:https://doi.org/10.1016/j.jhazmat.2011.06.058
  • Caliskan, N., Sogut, E. G., Savran, A., Kul, A. R., & Kubilay, S. (2017). Removal of Cu (II) and Cd (II) ions from aqueous solutions using local raw material as adsorbent: a study in binary systems. Desalination and Water Treatment, 75, 132-147. doi:https://doi.org/10.5004/dwt.2017.20728
  • Chakraborty, S., Chowdhury, S., & Saha, P. D. (2011). Adsorption of crystal violet from aqueous solution onto NaOH-modified rice husk. Carbohydrate Polymers, 86(4), 1533-1541. doi:https://doi.org/10.1016/j.carbpol.2011.06.058
  • Choy, K. K., McKay, G., & Porter, J. F. (1999). Sorption of acid dyes from effluents using activated carbon. Resources, Conservation and Recycling, 27(1-2), 57-71. doi:https://doi.org/10.1016/S0921-3449(98)00085-8
  • Collins, O. N., & Elijah, O. C. (2019). ADSORPTION OF A DYE (CRYSTAL VIOLET) ON AN ACID MODIFIED NON-CONVENTIONAL ADSORBENT. Journal of Chemical Technology & Metallurgy, 54(1). Retrieved from https://dl.uctm.edu/journal/node/j2019-1/12_17_197_p_95_110.pdf
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Details

Primary Language English
Subjects Environmental Engineering, Environmental Sciences
Published Date March 2022
Journal Section Research Articles
Authors

İhsan ALACABEY (Primary Author)
MARDİN ARTUKLU ÜNİVERSİTESİ, SAĞLIK HİZMETLERİ MESLEK YÜKSEKOKULU
0000-0002-3080-2296
Türkiye

Publication Date March 15, 2022
Application Date January 11, 2022
Acceptance Date March 5, 2022
Published in Issue Year 2022, Volume 6, Issue 1

Cite

APA Alacabey, İ. (2022). Adsorptive removal of cationic dye from aqueous solutions using Bardakçı clay . International Journal of Agriculture Environment and Food Sciences , 6 (1) , 80-90 . DOI: 10.31015/jaefs.2022.1.12


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