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            <front>

                <journal-meta>
                                                                <journal-id>jiens</journal-id>
            <journal-title-group>
                                                                                    <journal-title>Journal of Innovative Engineering and Natural Science</journal-title>
            </journal-title-group>
                                        <issn pub-type="epub">2791-7630</issn>
                                                                                            <publisher>
                    <publisher-name>İdris Karagöz</publisher-name>
                </publisher>
                    </journal-meta>
                <article-meta>
                                        <article-id pub-id-type="doi">10.29228/JIENS.51666</article-id>
                                                                <article-categories>
                                            <subj-group  xml:lang="en">
                                                            <subject>Polymer Science and Technologies</subject>
                                                    </subj-group>
                                            <subj-group  xml:lang="tr">
                                                            <subject>Polimer Bilimi ve Teknolojileri</subject>
                                                    </subj-group>
                                    </article-categories>
                                                                                                                                                        <title-group>
                                                                                                                        <article-title>Preparation of poly(lactic acid) based biocomposites with poly(ethylene glycol) and montmorillonite clay by solvent casting method</article-title>
                                                                                                                                        </title-group>
            
                                                    <contrib-group content-type="authors">
                                                                        <contrib contrib-type="author">
                                                                    <contrib-id contrib-id-type="orcid">
                                        https://orcid.org/0000-0003-0600-5913</contrib-id>
                                                                <name>
                                    <surname>Özdoğan</surname>
                                    <given-names>Reyhan</given-names>
                                </name>
                                                                    <aff>YALOVA ÜNİVERSİTESİ</aff>
                                                            </contrib>
                                                    <contrib contrib-type="author">
                                                                    <contrib-id contrib-id-type="orcid">
                                        https://orcid.org/0000-0002-2013-5354</contrib-id>
                                                                <name>
                                    <surname>Çelebi</surname>
                                    <given-names>Mithat</given-names>
                                </name>
                                                                    <aff>YALOVA ÜNİVERSİTESİ</aff>
                                                            </contrib>
                                                                                </contrib-group>
                        
                                        <pub-date pub-type="pub" iso-8601-date="20210730">
                    <day>07</day>
                    <month>30</month>
                    <year>2021</year>
                </pub-date>
                                        <volume>1</volume>
                                        <issue>1</issue>
                                        <fpage>33</fpage>
                                        <lpage>40</lpage>
                        
                        <history>
                                    <date date-type="received" iso-8601-date="20210606">
                        <day>06</day>
                        <month>06</month>
                        <year>2021</year>
                    </date>
                                                    <date date-type="accepted" iso-8601-date="20210625">
                        <day>06</day>
                        <month>25</month>
                        <year>2021</year>
                    </date>
                            </history>
                                        <permissions>
                    <copyright-statement>Copyright © 2021, Journal of Innovative Engineering and Natural Science</copyright-statement>
                    <copyright-year>2021</copyright-year>
                    <copyright-holder>Journal of Innovative Engineering and Natural Science</copyright-holder>
                </permissions>
            
                                                                                                <abstract><p>Poly(lactic acid) is one of the most widely used bioplastics. PLA is derived from lactic acid monomer which is produced by fermentation using microorganisms. It is renewable, biodegradable, biocompatible, and low-cost aliphatic thermoplastic bioplastic. However, it displays low barrier properties to use packaging applications compared with conventional polymers. PLA has brittle, low toughness, and low thermal resistance properties. To improve the weak properties of PLA, copolymers of lactic acid are synthesized or blends of PLA with other synthetic and biodegradable polymers are prepared. PLA has been used as mulching films, biomedical devices, packaging, and membrane materials. In this study, PLA films were prepared by solution casting method using a high shear mixer for 90 sec. PLA films were blended with different concentrations of poly(ethylene glycol) (PEG) and Montmorillonite (MMT). Properties of mechanical, thermal, and optic of biodegradable films were determined using mechanical testing machine Zwick Z 1.0 kN, thermogravimetric analysis, differential scanning calorimetry (DSC), and optical microscopy, respectively.</p></abstract>
                                                                                    
            
                                                            <kwd-group>
                                                    <kwd>Biodegradable</kwd>
                                                    <kwd>  Montmorillonite</kwd>
                                                    <kwd>  Poly(lactic acid</kwd>
                                                    <kwd>  Solution casting</kwd>
                                                    <kwd>  Poly(ethylene glycol)</kwd>
                                            </kwd-group>
                                                        
                                                                                                                                                    </article-meta>
    </front>
    <back>
                            <ref-list>
                                    <ref id="ref1">
                        <label>1</label>
                        <mixed-citation publication-type="journal">Holmberg AL, Reno KH, Wool RP, Epps TH (2015). Biobased building blocks for the rational design of renewable block polymers. Soft Matter,  00:1–20. https://doi.org/10.1039/c4sm01220h</mixed-citation>
                    </ref>
                                    <ref id="ref2">
                        <label>2</label>
                        <mixed-citation publication-type="journal">Ashter SA (2016) Introduction to Bioplastics Engineering. William Andrew Publishing, Norwich NY</mixed-citation>
                    </ref>
                                    <ref id="ref3">
                        <label>3</label>
                        <mixed-citation publication-type="journal">Ray SS (2012) Polylactide-based bionanocomposites: A promising class of hybrid materials. Acc Chem  Res 45(10):1710–1720. https://doi.org/10.1021/ar3000376</mixed-citation>
                    </ref>
                                    <ref id="ref4">
                        <label>4</label>
                        <mixed-citation publication-type="journal">Nampoothiri KM, Nair NR, John RP (2010) An overview of the recent developments in polylactide (PLA) research. Bioresour Technol 101(22):8493–8501. https://doi.org/10.1016/j.biortech.2010.05.092</mixed-citation>
                    </ref>
                                    <ref id="ref5">
                        <label>5</label>
                        <mixed-citation publication-type="journal">Auras R, Harte B, Selke S (2004) An overview of polylactides as packaging materials. Macromolecular Bioscience 4(9):835–864. https://doi.org/10.1002/mabi.200400043</mixed-citation>
                    </ref>
                                    <ref id="ref6">
                        <label>6</label>
                        <mixed-citation publication-type="journal">Lasprilla AJR, Martinez AGR, Lunelli BH, Figueroa JEJ, Jardini AL, Filho RM (2010) Synthesis and Characterization of Poly (Lactic Acid) for Use in Biomedical Field. Chem Eng Trans 24:85–990. https://doi.org/10.3303/CET1124165</mixed-citation>
                    </ref>
                                    <ref id="ref7">
                        <label>7</label>
                        <mixed-citation publication-type="journal">Xiong Z, Lin H, Liu F, Yu X, Wang Y, Wang Y (2016). A new strategy to simultaneously improve the permeability, heat-deformation resistance and antifouling properties of polylactide membrane via bio-based ??-cyclodextrin and surface crosslinking. Journal of Membrane Science 513:166–176. https://doi.org/10.1016/j.memsci.2016.04.036</mixed-citation>
                    </ref>
                                    <ref id="ref8">
                        <label>8</label>
                        <mixed-citation publication-type="journal">Abd Alsaheb RA et al. (2015) Recent applications of polylactic acid in pharmaceutical and medical industries. J Chem Pharm Res 7(12):51–63</mixed-citation>
                    </ref>
                                    <ref id="ref9">
                        <label>9</label>
                        <mixed-citation publication-type="journal">Pawar RP, Tekale SU, Shisodia SU, Totre JT, Domb AJ (2014) Biomedical Applications of Poly ( Lactic Acid ). https://doi.org/10.2174/2210296504666140402235024</mixed-citation>
                    </ref>
                                    <ref id="ref10">
                        <label>10</label>
                        <mixed-citation publication-type="journal">Sim KJ, Han SO, Seo YB (2010) Dynamic mechanical and thermal properties of red algae fiber reinforced poly(lactic acid) biocomposites. Macromol Res 18(5):489–495. https://doi.org/10.1007/s13233-010-0503-3</mixed-citation>
                    </ref>
                                    <ref id="ref11">
                        <label>11</label>
                        <mixed-citation publication-type="journal">Tokoro R, Vu DM, Okubo K, Tanaka T, Fujii T, Fujiura T (2008) How to improve mechanical properties of polylactic acid with bamboo fibers. J Mater Sci 43(2):775–787. https://doi.org/10.1007/s10853-007-1994-y</mixed-citation>
                    </ref>
                                    <ref id="ref12">
                        <label>12</label>
                        <mixed-citation publication-type="journal">Matta AK, Rao RU, Suman KNS, Rambabu V (2014) Preparation and Characterization of Biodegradable PLA/PCL Polymeric Blends. Procedia Mater Sci 6:1266–1270. https://doi.org/10.1016/j.mspro.2014.07.201</mixed-citation>
                    </ref>
                                    <ref id="ref13">
                        <label>13</label>
                        <mixed-citation publication-type="journal">Shuttleworth PS, Díez-Pascual AM, Marco C, Ellis G (2017) Flexible Bionanocomposites from Epoxidized Hemp Seed Oil Thermosetting Resin Reinforced with Halloysite Nanotubes. J Phys Chem B 121(11):2454–2467. https://doi.org/10.1021/acs.jpcb.7b00103</mixed-citation>
                    </ref>
                                    <ref id="ref14">
                        <label>14</label>
                        <mixed-citation publication-type="journal">Miteluț AC, Tănase E, Popa VI, Popa ME (2015) Sustainable Alternative for Food Packaging: Chitosan Biopolymer-a Review  4(2):52-61</mixed-citation>
                    </ref>
                                    <ref id="ref15">
                        <label>15</label>
                        <mixed-citation publication-type="journal">Erpek CEY, Ozkoc G, Yilmazer U (2015) Comparison of Natural Halloysite with Synthetic Carbon Nanotubes in Poly(lactic acid) Based Composites. Polym Compos. https://doi.org/10.1002/pc.23816</mixed-citation>
                    </ref>
                                    <ref id="ref16">
                        <label>16</label>
                        <mixed-citation publication-type="journal">Wu TM, Wu CY (2006) Biodegradable poly(lactic acid)/chitosan-modified montmorillonite nanocomposites: Preparation and characterization. Polym Degrad Stab 91(9):2198–2204. https://doi.org/10.1016/j.polymdegradstab.2006.01.004</mixed-citation>
                    </ref>
                                    <ref id="ref17">
                        <label>17</label>
                        <mixed-citation publication-type="journal">Sébastien F, Stéphane G, Copinet A, Coma V (2006) Novel biodegradable films made from chitosan and poly(lactic acid) with antifungal properties against mycotoxinogen strains. Carbohydr Polym 65(2):185–193. https://doi.org/10.1016/j.carbpol.2006.01.006</mixed-citation>
                    </ref>
                                    <ref id="ref18">
                        <label>18</label>
                        <mixed-citation publication-type="journal">Labrecque LV, Kumar R, Dave V, Gross R, McCarthy SP (1997) Citrate esters as plasticizers for poly(lactic acid). J Appl Polym Sci 66(8):1507–1513. https://doi.org/10.1002/(sici)1097-4628(19971121)66:8&lt;1507::aid-app11&gt;3.0.co;2-0</mixed-citation>
                    </ref>
                                    <ref id="ref19">
                        <label>19</label>
                        <mixed-citation publication-type="journal">Oksman K, Skrifvars M, Selin JF (2003) Natural fibres as reinforcement in polylactic acid (PLA) composites. Compos Sci Technol. https://doi.org/10.1016/S0266-3538(03)00103-9</mixed-citation>
                    </ref>
                                    <ref id="ref20">
                        <label>20</label>
                        <mixed-citation publication-type="journal">Grande R, Pessan LA, Carvalho AJF (2015) Ternary melt blends of poly(lactic acid)/poly(vinyl alcohol)-chitosan. Ind Crops Prod 72:159–165. https://doi.org/10.1016/j.indcrop.2014.12.041</mixed-citation>
                    </ref>
                                    <ref id="ref21">
                        <label>21</label>
                        <mixed-citation publication-type="journal">Huneault MA, Li H (2007) Morphology and properties of compatibilized polylactide/thermoplastic starch blends. Polymer (Guildf) 48(1):270–280. https://doi.org/10.1016/j.polymer.2006.11.023</mixed-citation>
                    </ref>
                                    <ref id="ref22">
                        <label>22</label>
                        <mixed-citation publication-type="journal">Shirai MA, Grossmann MVE, Mali S, Yamashita F, Garcia PS, Müller CMO (2013) Development of biodegradable flexible films of starch and poly(lactic acid) plasticized with adipate or citrate esters. Carbohydr Polym 92(1):19–22. https://doi.org/10.1016/j.carbpol.2012.09.038</mixed-citation>
                    </ref>
                                    <ref id="ref23">
                        <label>23</label>
                        <mixed-citation publication-type="journal">Li H, Huneault MA (2011) Comparison of sorbitol and glycerol as plasticizers for thermoplastic starch in TPS/PLA blends. J Appl Polym Sci 119(4):2439–2448. 2011, https://doi.org/10.1002/app.32956</mixed-citation>
                    </ref>
                                    <ref id="ref24">
                        <label>24</label>
                        <mixed-citation publication-type="journal">Ke TT, Sun XX (2001) Thermal and mechanical properties of poly(lactic acid) and starch blends with various lasticizers. Trans ASAE 44(4):945. https://doi.org/10.13031/2013.6228</mixed-citation>
                    </ref>
                                    <ref id="ref25">
                        <label>25</label>
                        <mixed-citation publication-type="journal">Maiza M, Benaniba MT, Quintard G, Massardier-Nageotte V (2015) Biobased additive plasticizing Polylactic acid (PLA). Polimeros 25(6):581–590. https://doi.org/10.1590/0104-1428.1986</mixed-citation>
                    </ref>
                                    <ref id="ref26">
                        <label>26</label>
                        <mixed-citation publication-type="journal">Johnson W (2002) Final report on the safety assessment of acetyl triethyl citrate, acetyl tributyl citrate, acetyl trihexyl citrate, and acetyl trioctyl citrate. Int J Toxicol 21(2):1–17. https://doi.org/10.1080/10915810290096504</mixed-citation>
                    </ref>
                                    <ref id="ref27">
                        <label>27</label>
                        <mixed-citation publication-type="journal">Zhang JF, X. Sun X (2004) Physical characterization of coupled poly(lactic acid)/ starch/maleic anhydride blends plasticized by acetyl triethyl citrate. Macromol Biosci 4(11):1053–1060. https://doi.org/10.1002/mabi.200400076</mixed-citation>
                    </ref>
                                    <ref id="ref28">
                        <label>28</label>
                        <mixed-citation publication-type="journal">Arrieta MP, Fortunati E, Dominici F, López J, Kenny JM (2015) Bionanocomposite films based on plasticized PLA-PHB/cellulose nanocrystal blends. Carbohydr Polym 121:265–275. https://doi.org/10.1016/j.carbpol.2014.12.056</mixed-citation>
                    </ref>
                                    <ref id="ref29">
                        <label>29</label>
                        <mixed-citation publication-type="journal">Arrieta MP, López J, López D, Kenny JM, Peponi L (2016) Biodegradable electrospun bionanocomposite fibers based on plasticized PLA???PHB blends reinforced with cellulose nanocrystals. Ind Crops Prod 93:290–301. 2016, https://doi.org/10.1016/j.indcrop.2015.12.058</mixed-citation>
                    </ref>
                                    <ref id="ref30">
                        <label>30</label>
                        <mixed-citation publication-type="journal">Cui L, Zhu CL, Zhu P, Tsou CH, Yang WJ, Yeh JT (2012) Preparation and physical properties of melt-blown nonwovens of biodegradable PLA/acetyl tributyl citrate/FePol copolyester blends. J Appl Polym Sci. https://doi.org/10.1002/app.36429</mixed-citation>
                    </ref>
                                    <ref id="ref31">
                        <label>31</label>
                        <mixed-citation publication-type="journal">Mainardes RM, Khalil NM, Gremio MPD (2010) Intranasal delivery of zidovudine by PLA and PLA-PEG blend nanoparticles. Int J Pharm 395(1–2):266–271. https://doi.org/10.1016/j.ijpharm.2010.05.020</mixed-citation>
                    </ref>
                                    <ref id="ref32">
                        <label>32</label>
                        <mixed-citation publication-type="journal">Zaaba NF, Jaafar M, Ismail H (2021) Tensile and morphological properties of nanocrystalline cellulose and nanofibrillated cellulose reinforced PLA bionanocomposites: A review. Polym Eng Sci 61(1):22–38. https://doi.org/10.1002/pen.25560</mixed-citation>
                    </ref>
                                    <ref id="ref33">
                        <label>33</label>
                        <mixed-citation publication-type="journal">Shen P, Moriya A, Rajabzadeh S, Maruyama T, Matsuyama H (2013) Improvement of the antifouling properties of poly (lactic acid) hollow fiber membranes with poly (lactic acid)-polyethylene glycol-poly (lactic acid) copolymers. Desalination 325:37–39. https://doi.org/10.1016/j.desal.2013.06.012</mixed-citation>
                    </ref>
                                    <ref id="ref34">
                        <label>34</label>
                        <mixed-citation publication-type="journal">Li FJ, Liang JZ, Zhang SD, Zhu B (2015) Tensile Properties of Polylactide/Poly(ethylene glycol) Blends. J Polym Environ 23(3):407–415. https://doi.org/10.1007/s10924-015-0718-7</mixed-citation>
                    </ref>
                                    <ref id="ref35">
                        <label>35</label>
                        <mixed-citation publication-type="journal">Chieng BW, Ibrahim NA, Yunus WMZW, Hussein MZ (2013) Plasticized poly(lactic acid) with low molecular weight poly(ethylene glycol): Mechanical, thermal, and morphology properties. J Appl Polym Sci 130(6):4576–4580. https://doi.org/10.1002/app.39742</mixed-citation>
                    </ref>
                                    <ref id="ref36">
                        <label>36</label>
                        <mixed-citation publication-type="journal">Avérous L (2004) Biodegradable Multiphase Systems Based on Plasticized Starch: A Review. J Macromol Sci Part C Polym Rev 44(3):231–274. https://doi.org/10.1081/MC-200029326</mixed-citation>
                    </ref>
                                    <ref id="ref37">
                        <label>37</label>
                        <mixed-citation publication-type="journal">Tsui A, Wright ZC, Frank CW (2013) Biodegradable polyesters from renewable resources. Annu Rev Chem Biomol Eng 4:143–70. https://doi.org/10.1146/annurev-chembioeng-061312-103323</mixed-citation>
                    </ref>
                                    <ref id="ref38">
                        <label>38</label>
                        <mixed-citation publication-type="journal">Garlotta D (2002) A Literature Review of Poly ( Lactic Acid ). J Polym Environ 9(2):63–84. https://doi.org/10.1023/A:1020200822435</mixed-citation>
                    </ref>
                            </ref-list>
                    </back>
    </article>
