Year 2020, Volume 10 , Issue 1, Pages 63 - 72 2020-03-01

Use of Kaolin-supported Nano-scale Zero-valent Iron for Removal of Remazol Brilliant Blue R from Aqueous Solution
Sulu Çözeltiden Remazol Brilliant Blue R Gideriminde Kaolin Destekli Nano Boyutlu Sıfır Değerlikli Demir Kullanımı

Müslün Sara TUNÇ [1]


In this study, kaolin supported nano-sized zero-valent iron (K-nZVI) particles were synthesized by borohydride reduction method in presence of kaolin and used for removal of Remazol Brilliant Blue R (RBBR) from aqueous solution. The effects of solution initial pH, K-nZVI dosage, contact time and initial dye concentration for removal of RBBR were evaluated. The removal efficiency was determined to be pH dependent and the maximum removal efficiency of RBBR was obtained at pH 3. RBBR removal efficiency increased with increasing K-nZVI dosage in the dosage range of 0.3 and 1.0 g L-1. The equilibrium was reached at the contact time of 60 minutes. The removal efficiency decreased with the increase of the initial dye concentration. In this study, the suitability of experimental data to Langmuir and Freundlich isotherm models was also investigated and the parameters of these models were calculated. It was found that RBBR adsorption by K-nZVI was suitable for both Langmuir and Freundlich isotherm. The maximum adsorption capacity was determined as 200 mg g-1.

Bu çalışmada, kaolin destekli nano boyutlu sıfır değerlikli demir (K-nZVI) partikülleri kaolin varlığında borhidrür indirgeme metodu ile sentezlenmiş ve sulu çözeltiden Remazol Brilliant Blue R (RBBR) gideriminde kullanılmıştır. RBBR gideriminde çözelti başlangıç pH’ı, K-nZVI dozajı, temas süresi ve başlangıç boyar madde konsantrasyonunun etkisi değerlendirilmiştir. Giderim veriminin pH’a bağlı olduğu tespit edilmiş ve RBBR’nin maksimum giderim verimi pH 3’te gerçekleşmiştir. 0.3-1.0 g L-1 dozaj aralığında K-nZVI dozajının artışı ile RBBR giderim verimi artmıştır. 60 dakikalık temas süresinde dengeye ulaşılmıştır. Başlangıç boyar madde konsantrasyonun artışı ile giderim verimi azalmıştır. Çalışmada, deneysel verilerin Langmuir ve Freundlich izoterm modellere uygunluğu da araştırılmış ve bu modellere ait parametreler hesaplanmıştır. K-nZVI ile RBBR adsorpsiyonun hem Langmuir hem de Freundlich izoterme uygun olduğu tespit edilmiştir. Maksimum adsorpsiyon kapasitesi 200 mg g-1 olarak belirlenmiştir.

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Primary Language tr
Subjects Environmental Engineering
Published Date Mart-2020
Journal Section Çevre Mühendisliği / Environment Engineering
Authors

Orcid: 0000-0001-9907-0428
Author: Müslün Sara TUNÇ (Primary Author)
Institution: FIRAT ÜNİVERSİTESİ, MÜHENDİSLİK FAKÜLTESİ, ÇEVRE MÜHENDİSLİĞİ BÖLÜMÜ
Country: Turkey


Dates

Application Date : September 20, 2019
Acceptance Date : October 23, 2019
Publication Date : March 1, 2020

Bibtex @research article { jist622811, journal = {Journal of the Institute of Science and Technology}, issn = {2146-0574}, eissn = {2536-4618}, address = {}, publisher = {Igdir University}, year = {2020}, volume = {10}, pages = {63 - 72}, doi = {10.21597/jist.622811}, title = {Sulu Çözeltiden Remazol Brilliant Blue R Gideriminde Kaolin Destekli Nano Boyutlu Sıfır Değerlikli Demir Kullanımı}, key = {cite}, author = {TUNÇ, Müslün Sara} }
APA TUNÇ, M . (2020). Sulu Çözeltiden Remazol Brilliant Blue R Gideriminde Kaolin Destekli Nano Boyutlu Sıfır Değerlikli Demir Kullanımı. Journal of the Institute of Science and Technology , 10 (1) , 63-72 . DOI: 10.21597/jist.622811
MLA TUNÇ, M . "Sulu Çözeltiden Remazol Brilliant Blue R Gideriminde Kaolin Destekli Nano Boyutlu Sıfır Değerlikli Demir Kullanımı". Journal of the Institute of Science and Technology 10 (2020 ): 63-72 <https://dergipark.org.tr/en/pub/jist/issue/52503/622811>
Chicago TUNÇ, M . "Sulu Çözeltiden Remazol Brilliant Blue R Gideriminde Kaolin Destekli Nano Boyutlu Sıfır Değerlikli Demir Kullanımı". Journal of the Institute of Science and Technology 10 (2020 ): 63-72
RIS TY - JOUR T1 - Sulu Çözeltiden Remazol Brilliant Blue R Gideriminde Kaolin Destekli Nano Boyutlu Sıfır Değerlikli Demir Kullanımı AU - Müslün Sara TUNÇ Y1 - 2020 PY - 2020 N1 - doi: 10.21597/jist.622811 DO - 10.21597/jist.622811 T2 - Journal of the Institute of Science and Technology JF - Journal JO - JOR SP - 63 EP - 72 VL - 10 IS - 1 SN - 2146-0574-2536-4618 M3 - doi: 10.21597/jist.622811 UR - https://doi.org/10.21597/jist.622811 Y2 - 2019 ER -
EndNote %0 Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi Sulu Çözeltiden Remazol Brilliant Blue R Gideriminde Kaolin Destekli Nano Boyutlu Sıfır Değerlikli Demir Kullanımı %A Müslün Sara TUNÇ %T Sulu Çözeltiden Remazol Brilliant Blue R Gideriminde Kaolin Destekli Nano Boyutlu Sıfır Değerlikli Demir Kullanımı %D 2020 %J Journal of the Institute of Science and Technology %P 2146-0574-2536-4618 %V 10 %N 1 %R doi: 10.21597/jist.622811 %U 10.21597/jist.622811
ISNAD TUNÇ, Müslün Sara . "Sulu Çözeltiden Remazol Brilliant Blue R Gideriminde Kaolin Destekli Nano Boyutlu Sıfır Değerlikli Demir Kullanımı". Journal of the Institute of Science and Technology 10 / 1 (March 2020): 63-72 . https://doi.org/10.21597/jist.622811
AMA TUNÇ M . Sulu Çözeltiden Remazol Brilliant Blue R Gideriminde Kaolin Destekli Nano Boyutlu Sıfır Değerlikli Demir Kullanımı. Iğdır Üniv. Fen Bil Enst. Der.. 2020; 10(1): 63-72.
Vancouver TUNÇ M . Sulu Çözeltiden Remazol Brilliant Blue R Gideriminde Kaolin Destekli Nano Boyutlu Sıfır Değerlikli Demir Kullanımı. Journal of the Institute of Science and Technology. 2020; 10(1): 72-63.