Year 2021, Volume 11 , Issue 2, Pages 1362 - 1373 2021-06-01

Su Ortamından Ultrasonik Koşullar Altında GO Malzemesine Yüklenen Bimetalik Pt / Co ile Maxilon Blue 5G Kaldırma
Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium

Mehmet Harbi ÇALIMLI [1]


Bimetalik Pt/Co’nin GO üzerine yüklenmiş adsorbent bir seri hidrotermal metod ile sentezlendi. Elde edilen adsorbance maxilon blue 5G (MB 5G)’inin giderilmesinde kullanıldı ve adsorbsiyon çalışmaları incelendi. MB 5G’inin Pt/Co yüklü GO material ile yapılan adsorbsiyon çalışmaları farklı deneysel durumlarda olan ultrasonic ışıma zamanı (1-120 min), sıcaklık (24-55 oC), başlangıç MB 5G konstrasyonu (0.7.10-5- 1.5.10-5 M), ve pH (4- 10) gibi deneysel koşullar altında yapıldı. Kinetik reaksiyonlar birinci dereceden, ikinci dereceden ve intrapartikül düfüzyonu metodları ile incelendi. Buna ilaveten, entalpi, entropi, Gibbs serbest enerjisi ve termodinamik aktivasyon fonksiyoları aktivasyon mekanizmasını tespit etmek için incelendi. Elde edilen sonuçlar ile bimetallik Pt/Co’nin GO üzerine yüklenmiş adsorbent MB 5G organik boyasının giderilmesinde etkin bir şekilde kullanılabileceği sonucuna varıldı.
Bimetallic Pt/Co loaded on GO adsorbance was produced following a series of simple hydrothermal methods. The produced bimetallic Pt/Co loaded GO material was used in the maxilon blue 5G removal (MB 5G) and investigated its adsorption studies. The adsorption studies on removal of MB 5G using the bimetallic Pt/Co loaded on GO material were carried out performing different experimental conditions like ultrasonic irradiation time (1-120 min), temperature (24-55 oC), initial MB 5G concentration (0.7.10-5- 1.5.10-5 M), and pH (4- 10) to detect optimum removal conditions. The reaction kinetics were investigated by pairing the so-called first-order pseudo-second-order and intraparticle diffusion in the adsorption process study. In addition, enthalpy, entropy and Gibbs free energy, and thermodynamic activation functions were investigated in order to understand the adsorption mechanism. These data showed that the bimetallic Pt/Co loaded on GO material can be used as an effective nano adsorbent for the removal of MB 5G as an organic pollutant in an aquatic medium.
  • Akova, A, Ustun, G, 2000. Activity and adsorption of lipase from Nigella sativa seeds on Celite at different pH values. Biotechnology Letters, 22(5), 355–359.
  • Aksu Z, Tezer, S, 2000. Equilibrium and kinetic modelling of biosorption of Remazol black B by Rhizopus arrhizus in a batch system: Effect of temperature. Process Biochemistry, 36(5), 431–439.
  • Alkan M, Doǧan M, Turhan Y, Demirbaş Ö, Turan P, 2008. Adsorption kinetics and mechanism of maxilon blue 5G dye on sepiolite from aqueous solutions. Chemical Engineering Journal, 139(2), 213–223.
  • Alkan M, Çelikçcapa S, Demirbaş Ö, Dogan M, 2005. Removal of reactive blue 221 and acid blue 62 anionic dyes from aqueous solutions by sepiolite. Dyes and Pigments, 65(3), 251–259.
  • Bae S, Kim D, Lee W, 2013. Degradation of diclofenac by pyrite catalyzed Fenton oxidation. Applied Catalysis B: Environmental, 134–135, 93–102.
  • Bagal MV, Lele BJ, Gogate PR, 2013. Removal of 2,4-dinitrophenol using hybrid methods based on ultrasound at an operating capacity of 7 L. Ultrasonics Sonochemistry, 20(5), 1217–1225.
  • Banat IM, Nigam P, Singh D, Marchant R. 1996. Microbial decolorization of textile-dye-containing effluents: A review. In Bioresource Technology 58(3), 217–227.
  • Batra, K, Nayak S, Behura SK, Jani O, 2015. Optimizing performance parameters of chemically-derived graphene/ p -Si heterojunction solar cell. Journal of Nanoscience and Nanotechnology, 15(7), 4877–4882.
  • Çalımlı M. H, 2020. Magnetic nanocomposite cobalt-multiwalled carbon nanotube and adsorption kinetics of methylene blue using an ultrasonic batch. International Journal of Environmental Science and Technology, 18(3), 723–740.
  • Çalımlı MH, Demirbaş, Ö, Aygün A, Alma MH, Nas MS, Şen F, 2018. Immobilization kinetics and mechanism of bovine serum albumin on diatomite clay from aqueous solutions. Applied Water Science, 8(7), 209.
  • Chen Z, Fu J, Wang M, Wang X, Zhang J, Xu Q, 2014. Adsorption of cationic dye (methylene blue) from aqueous solution using poly(cyclotriphosphazene-co-4,4′-sulfonyldiphenol) nanospheres. Applied Surface Science, 289, 495–501.
  • Chiou MS, Ho PY, Li HY, 2004. Adsorption of anionic dyes in acid solutions using chemically cross-linked chitosan beads. Dyes and Pigments, 60(1), 69–84.
  • Choy KKH, McKay G, Porter JF, 1999. Sorption of acid dyes from effluents using activated carbon. Resources, Conservation and Recycling, 27(1–2), 57–71.
  • Çiçek F, Özer D, Özer A, Özer A, 2007. Low cost removal of reactive dyes using wheat bran. Journal of Hazardous Materials, 146(1–2), 408–416.
  • Crini G, 2006. Non-conventional low-cost adsorbents for dye removal: A review. In Bioresource Technology, 97(9), 1061–1085.
  • Demirbaş Ö, Çalımlı MH, Demirkan B, Alma MH, Nas MS, Khan A, Asiri AM, Şen F, 2019. Thermodynamics, Kinetics, and Adsorption Properties of Biomolecules onto Carbon-Based Materials Obtained from Food Wastes. BioNanoScience, 9(3), 672–682.
  • Demirbaş Ö, Nas M, 2016. Kinetics and Mechanism of the Adsorption of Methylene Blue from Aqueous Solution onto Turkish Green Clay. Archives of Current Research International, 6(3), 1–10.
  • Dindarsafa M, Khataee A, Kaymak B, Vahid B, Karimi A, Rahmani A, 2017. Heterogeneous sono-Fenton-like process using martite nanocatalyst prepared by high energy planetary ball milling for treatment of a textile dye. Ultrasonics Sonochemistry, 34, 389–399.
  • Doǧan M, Alkan M, 2003. Adsorption kinetics of methyl violet onto perlite. Chemosphere, 50(4), 517–528.
  • Feng X, Zhang Y, Zhou J, Li Y, Chen S, Zhang L, Ma Y, Wang L, Yan X, 2015. Three-dimensional nitrogen-doped graphene as an ultrasensitive electrochemical sensor for the detection of dopamine. Nanoscale, 7(6), 2427–2432.
  • Fonseca AF, Zhang H, Cho K, 2015. Formation energy of graphene oxide structures: A molecular dynamics study on distortion and thermal effects. Carbon, 84(1), 365–374.
  • Ghorai S, Sarkar A, Raoufi M, Panda A. B, Schönherr H, Pal S, 2014. Enhanced removal of methylene blue and methyl violet dyes from aqueous solution using a nanocomposite of hydrolyzed polyacrylamide grafted xanthan gum and incorporated nanosilica. ACS Applied Materials and Interfaces, 6(7), 4766–4777.
  • Haldorai Y, Kim BK, Jo Y. L, Shi, JJ, 2014. Ag@graphene oxide nanocomposite as an efficient visible-light plasmonic photocatalyst for the degradation of organic pollutants: A facile green synthetic approach. Materials Chemistry and Physics, 143(3), 1452–1461.
  • Hassani A, Soltani RDC, Karaca S, Khataee A, 2015. Preparation of montmorillonite-alginate nanobiocomposite for adsorption of a textile dye in aqueous phase: Isotherm, kinetic and experimental design approaches. Journal of Industrial and Engineering Chemistry, 21, 1197–1207.
  • Hernández FP, Rojas S, Ocón P, de la Fuente JLG, Terreros P, Peña MA, García-Fierro J L, 2007. An opening route to the design of cathode materials for fuel cells based on PtCo nanoparticles. Applied Catalysis B: Environmental, 77(1–2), 19–28. doi: 10.1016/j.apcatb.2007.07.002
  • Huang R, Fang Z, Fang X, Tsang EP, 2014. Ultrasonic Fenton-like catalytic degradation of bisphenol A by ferroferric oxide (Fe3O4) nanoparticles prepared from steel pickling waste liquor. Journal of Colloid and Interface Science, 436, 258–266.
  • Iram M, Guo C, Guan Y, Ishfaq A, Liu H, 2010. Adsorption and magnetic removal of neutral red dye from aqueous solution using Fe3O4 hollow nanospheres. Journal of Hazardous Materials, 181(1–3), 1039–1050.
  • Kannan N, Sundaram MM, 2001. Kinetics and mechanism of removal of methylene blue by adsorption on various carbons - A comparative study. Dyes and Pigments, 51(1), 25–40.
  • Khataee A, Kayan B, Kalderis D, Karimi A, Akay S, Konsolakis M, 2017. Ultrasound-assisted removal of Acid Red 17 using nanosized Fe3O4-loaded coffee waste hydrochar. Ultrasonics Sonochemistry, 35, 72–80.
  • Khataee A, Rad TS, Vahid B, Khorram S, 2016. Preparation of zeolite nanorods by corona discharge plasma for degradation of phenazopyridine by heterogeneous sono-Fenton-like process. Ultrasonics Sonochemistry, 33, 37–46.
  • Khataee A, Saadi S, Safarpour M, Joo S. W, 2015. Sonocatalytic performance of Er-doped ZnO for degradation of a textile dye. Ultrasonics Sonochemistry, 27, 379–388.
  • Koffi RC, Coutanceau C, Garnier E, Léger JM, Lamy C, 2005. Synthesis, characterization and electrocatalytic behaviour of non-alloyed PtCr methanol tolerant nanoelectrocatalysts for the oxygen reduction reaction (ORR). Electrochimica Acta, 50(20), 4117–4127.
  • Lai FJ, Su WN, Sarma LS, Liu, DG, Hsieh CA, Lee JF, Hwang BJ, 2010. Chemical Dealloying Mechanism of Bimetallic Pt-Co Nanoparticles and Enhancement of Catalytic Activity toward Oxygen Reduction. Chemistry - A European Journal, 16(15), 4602–4611.
  • Liu SH, Zheng FS, Wu JR, 2011. Preparation of ordered mesoporous carbons containing well-dispersed and highly alloying Pt-Co bimetallic nanoparticles toward methanol-resistant oxygen reduction reaction. Applied Catalysis B: Environmental, 108–109, 81–89.
  • Liu T, Li Y, Du Q, Sun J, Jiao Y, Yang G, Wang Z, Xia Y, Zhang W, Wang K, Zhu H, Wu D, 2012. Adsorption of methylene blue from aqueous solution by graphene. Colloids and Surfaces B: Biointerfaces, 90(1), 197–203.
  • Liu Y, Liu C. Y, Liu Y, 2011. Investigation on fluorescence quenching of dyes by graphite oxide and graphene. Applied Surface Science, 257(13), 5513–5518.
  • Liu Z, Liu, Q, Huang Y, Ma Y, Yin S, Zhang X, Sun W, ChenY, 2008. Organic Photovoltaic Devices Based on a Novel Acceptor Material: Graphene. Advanced Materials, 20(20), 3924–3930.
  • Ma J, Yu F, Zhou L, Jin L, Yang M, Luan J, Tang Y, Fan H, Yuan Z, Chen J, 2012. Enhanced adsorptive removal of methyl orange and methylene blue from aqueous solution by alkali-activated multiwalled carbon nanotubes. ACS Applied Materials and Interfaces, 4(11), 5749–5760.
  • Mittal H, Ballav N, Mishra S. B, 2014. Gum ghatti and Fe3O4 magnetic nanoparticles based nanocomposites for the effective adsorption of methylene blue from aqueous solution. Journal of Industrial and Engineering Chemistry, 20(4), 2184–2192.
  • Nas MS, Gür A, Gür T, Yönten V, 2017. Exploring thermodynamics and kinetic parameters of immobilized catalase enzyme via adsorption on krill clay. Desalination and Water Treatment, 67, 178–186.
  • Nasuha N, Hameed BH, Din ATM, 2010. Rejected tea as a potential low-cost adsorbent for the removal of methylene blue. Journal of Hazardous Materials, 175(1–3), 126–132.
  • Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA, 2004. Electric field in atomically thin carbon films. Science, 306(5696), 666–669.
  • Qin J, Qiu F, Rong X, Yan J, Zhao H, Yang D, 2015. Adsorption behavior of crystal violet from aqueous solutions with chitosan-graphite oxide modified polyurethane as an adsorbent. Journal of Applied Polymer Science, 132(17), 41828.
  • Roy-Mayhew J D, Aksay IA, 2014. Graphene materials and their use in dye-sensitized solar cells. In Chemical Reviews. 114,12, 6323–6348).
  • Savk A, Özdil B, Demirkan B, Nas MS, Calimli MH, Alma MH, Inamuddin, Asiri AM, Şen, F. 2019. Multiwalled carbon nanotube-based nanosensor for ultrasensitive detection of uric acid, dopamine, and ascorbic acid. Materials Science and Engineering C, 99, 248–254.
  • Sen B, Şavk A, Sen F, 2018. Highly efficient monodisperse Pt nanoparticles confined in the carbon black hybrid material for hydrogen liberation. Journal of Colloid and Interface Science, 520, 112–118.
  • Şen F, Demirbaş Ö, Çalımlı MH, Aygün A, Alma MH, Nas MS, 2018. The dye removal from aqueous solution using polymer composite films. Applied Water Science, 8(7), 206.
  • Shen J, Shi M, Li N, Yan B, Ma H, Hu Y, Ye M, 2010. Facile Synthesis and Application of Ag-Chemically Converted Graphene Nanocomposite. Nano Res, 3, 339–349.
  • Singh KP, Mohan D, Sinha S, Tondon GS, Gosh D, 2003. Color removal from wastewater using low-cost activated carbon derived from agricultural waste material. Industrial and Engineering Chemistry Research, 42(9), 1965–1976.
  • Song Z, Liu W, Wei W, Quan C, Sun N, Zhou Q, Liu G, Wen X, 2016. Preparation and electrochemical properties of Fe2O3/reduced graphene oxide aerogel (Fe2O3/rGOA) composites for supercapacitors. Journal of Alloys and Compounds, 685, 355–363.
  • Teixeira SR, Lloyd C, Yao S, Andrea SG, Whitaker IS, Francis L, Conlan, RS, Azzopardi E, 2016. Polyaniline-graphene based α-amylase biosensor with a linear dynamic range in excess of 6 orders of magnitude. Biosensors and Bioelectronics, 85, 395–402.
  • Vadivelan V, Vasanth, KK, 2005. Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk. Journal of Colloid and Interface Science, 286(1), 90–100.
  • Wu Q, Zhang H, Zhou, L, Bao C, Zhu H, Zhang Y, 2016. Synthesis and application of rGO/CoFe2O4 composite for catalytic degradation of methylene blue on heterogeneous Fenton-like oxidation. Journal of the Taiwan Institute of Chemical Engineers, 67, 484–494.
  • Wu R, Liu JH, Zhao L, Zhang X, Xie J, Yu B, Ma X, Yang ST, Wang H, Liu Y, 2014. Hydrothermal preparation of magnetic Fe3O4@C nanoparticles for dye adsorption. Journal of Environmental Chemical Engineering, 2(2), 907–913.
  • Xu L, Wang J, 2012. Fenton-like degradation of 2,4-dichlorophenol using Fe 3O 4 magnetic nanoparticles. Applied Catalysis B: Environmental, 123–124, 117–126.
  • Yagub MT, Sen TK, Afroze S, Ang HM, 2014. Dye and its removal from aqueous solution by adsorption: A review. In Advances in Colloid and Interface Science. 209, 172–184.
  • Yener J, Kopac T, Dogu G, Dogu T, 2006. Adsorption of Basic Yellow 28 from aqueous solutions with clinoptilolite and amberlite. Journal of Colloid and Interface Science, 294(2), 255–264.
  • Yenisoy KS, Aygün A, Güneş M, Tahtasakal E, 2004. Physical and chemical characteristics of polymer-based spherical activated carbon and its ability to adsorb organics. Carbon, 42(3), 477–484.
  • Yönten V, Özgüven A, Ahmed AA, Akçay ME, 2020. Effect of some medium parameters on Brilliant Blue G biosorption by Amberlite resin/Agaricus campestris. International Journal of Environmental Science and Technology, 1–10.
  • Yönten, Vahap, Sanyürek NK, Kivanç MR, 2020. A thermodynamic and kinetic approach to adsorption of methyl orange from aqueous solution using a low cost activated carbon prepared from Vitis vinifera L. Surfaces and Interfaces, 20, 100529.
  • Zhang X, Zhang P, Wu Z, Zhang L, Zeng G, Zhou C, 2013. Adsorption of methylene blue onto humic acid-coated Fe3O4 nanoparticles. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 435, 85–90.
  • Zhao J, Manthiram A, 2011. Preleached Pd-Pt-Ni and binary Pd-Pt electrocatalysts for oxygen reduction reaction in proton exchange membrane fuel cells. Applied Catalysis B: Environmental, 101(3–4), 660–668.
  • Zhao W, Tang Y, Xi J, Kong J, 2015. Functionalized graphene sheets with poly(ionic liquid)s and high adsorption capacity of anionic dyes. Applied Surface Science, 326, 276–284.
  • Zolgharnein J, Bagtash M, Shariatmanesh T, 2015. Simultaneous removal of binary mixture of Brilliant Green and Crystal Violet using derivative spectrophotometric determination, multivariate optimization and adsorption characterization of dyes on surfactant modified nano-γ-alumina. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 137, 1016–1028.
Primary Language en
Subjects Engineering, Chemical
Published Date Haziran-2021
Journal Section Kimya / Chemistry, Kimya Mühendisliği / Chemical Engineering
Authors

Orcid: 0000-0001-9756-191X
Author: Mehmet Harbi ÇALIMLI (Primary Author)
Institution: Igdir University
Country: Turkey


Dates

Application Date : March 8, 2021
Acceptance Date : March 18, 2021
Publication Date : June 1, 2021

Bibtex @research article { jist893416, journal = {Journal of the Institute of Science and Technology}, issn = {2146-0574}, eissn = {2536-4618}, address = {}, publisher = {Igdir University}, year = {2021}, volume = {11}, pages = {1362 - 1373}, doi = {10.21597/jist.893416}, title = {Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium}, key = {cite}, author = {Çalımlı, Mehmet Harbi} }
APA Çalımlı, M . (2021). Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium . Journal of the Institute of Science and Technology , 11 (2) , 1362-1373 . DOI: 10.21597/jist.893416
MLA Çalımlı, M . "Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium" . Journal of the Institute of Science and Technology 11 (2021 ): 1362-1373 <https://dergipark.org.tr/en/pub/jist/issue/61423/893416>
Chicago Çalımlı, M . "Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium". Journal of the Institute of Science and Technology 11 (2021 ): 1362-1373
RIS TY - JOUR T1 - Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium AU - Mehmet Harbi Çalımlı Y1 - 2021 PY - 2021 N1 - doi: 10.21597/jist.893416 DO - 10.21597/jist.893416 T2 - Journal of the Institute of Science and Technology JF - Journal JO - JOR SP - 1362 EP - 1373 VL - 11 IS - 2 SN - 2146-0574-2536-4618 M3 - doi: 10.21597/jist.893416 UR - https://doi.org/10.21597/jist.893416 Y2 - 2021 ER -
EndNote %0 Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium %A Mehmet Harbi Çalımlı %T Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium %D 2021 %J Journal of the Institute of Science and Technology %P 2146-0574-2536-4618 %V 11 %N 2 %R doi: 10.21597/jist.893416 %U 10.21597/jist.893416
ISNAD Çalımlı, Mehmet Harbi . "Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium". Journal of the Institute of Science and Technology 11 / 2 (June 2021): 1362-1373 . https://doi.org/10.21597/jist.893416
AMA Çalımlı M . Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium. Iğdır Üniv. Fen Bil Enst. Der.. 2021; 11(2): 1362-1373.
Vancouver Çalımlı M . Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium. Journal of the Institute of Science and Technology. 2021; 11(2): 1362-1373.
IEEE M. Çalımlı , "Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium", Journal of the Institute of Science and Technology, vol. 11, no. 2, pp. 1362-1373, Jun. 2021, doi:10.21597/jist.893416