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Removal of Acıd Yellow 36 Dyestuff Wıth Fenton and Fenton-Lıke Advanced Oxıdatıon Methods

Year 2014, Volume: 4 Issue: 1, 41 - 48, 31.03.2014

Nihal Kocakaplan Neşe Ertugay Emine Malkoç

Abstract









In this study, the decolorization of Acid Yellow 36 (AY36) dyestuff by Fenton and Fenton like
oxidation method was investigated. The effect of pH, iron (Fe0 and Fe+2) hydrogen peroxide (H2O2) and concentration
of dyestuff on oxidation process was determined. The removal of AY36 was determined by means of color, aromatic
and COD. The color was more removed than aromatic in Fenton and Fenton-like oxidation. It was found that
Fenton-like oxidation was more effective than Fenton oxidation process in removal of AY36 dyestuff. 





Keywords

Acid Yellow 36 Fenton Process Fenton-like process COD

References

  • APHA, AWWA and WPCF ,1985. Standart Methods For the Examination of Water and Wastwater. Sixteenth Edition, Washington, DC.
  • Clarke,C.E., Kielar,F., Johnson, K.L., 2013. The oxidation of acid azo dye AY 36 by a manganese oxide containing mine waste. Journal of Hazardous Materials, 246: 310– 318.
  • Dokuzoğlu, Z.,Alkan, U., Yentürk, A., 2008. Reaktif Boyar Madde İçeren Tekstil Atıksularının İleri Oksidasyonu.Uludağ Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 13(2):119-128.
  • Forgacs, E., Cserháti, T., Oros, G., 2004. Removal of synthetic dyes from wastewaters: a review. Environment International, 30: 953– 971.
  • Gül,Ş., Ozcan Yıldırım, Ö., 2009. Degradation of Reactive Red 194 and Reactive Yellow 145 azo dyes by O3 and H2O2/UV-C processes. Chemical Engineering Journal, 155: 684-690.
  • Hanay, Ö., Hasar, H., 2007. Fenton oksidasyon prosesi ile tekstil endüstrisi atıksuyunda renk giderimi. Fırat Üniversitesi Fen ve Mühendislik Bilimler Dergisi, 19(4): 505-509.
  • Liu, X., Qiu, M., Huang, C., 2011. Degradation of the Reactive Black 5 by Fenton and Fenton like system.Procedia Engineering, 15: 4835 – 4840.
  • Malik, P.K., 2003. Use of activated carbons prepared from sawdust and rice-husk for adsorption of acid dyes: a case study of Acid Yellow 36. 56(3): 239–249.
  • Reife, A., Freeman, S., 1996. Environmental Chemistry of Dyes and Pigments, John Wiley&Sons, Inc., Kanada. Sajjad
  • Khezrianjoo and Hosakere Doddarevanna Revanasiddappa,2013. Photocatalytic Degradation of Acid Yellow 36 Using Zinc Oxide Photocatalyst in Aqueous Media. Journal of Catalysts.
  • Song, Y., Li, J., 2009. Degradation of C.I. Direct Black 168 from aqueous solution by y ash/H2O2 combining ultrasound. Ultrasonics Sonochemistry, 16: 440–444.
  • Yıldırım, A.Ö., 2009. Bazı Reaktif Boyar Maddelerin İleri Oksidasyon Yöntemleriyle Parçalanmasının İncelenmesi. Çukurova Üniversitesi, Fen Bilimleri Enstitüsü, Doktora Tezi.
  • Zhou, T., Lu, X., Wang, J., Wong, F.S., Li, Y., 2009. Rapid decolorization and mineralization of simulated textile wastewater in a heterogeneous Fenton like system with/ without external energy. Journal of Hazardous Materials, 165:193-199.

Fenton ve Fenton-Benzeri İleri Oksidasyon Yöntemleri ı̇ le Acid Yellow 36 Boyar Maddesinin Giderimi

Year 2014, Volume: 4 Issue: 1, 41 - 48, 31.03.2014

Nihal Kocakaplan Neşe Ertugay Emine Malkoç

Abstract

Bu çalışmada, Acid Yellow 36 (AY36) boyar maddesinin Fenton ve Fenton-benzeri oksidasyon yöntemi ile giderimi araştırılmıştır. Oksidasyon prosesine pH, demir (Fe0 ve Fe+2), hidrojen peroksit (H2O2) ve boyar madde konsantrasyonunun etkisi incelenmiştir. AY36 giderimi renk, aromatiklik ve KOI üzerinden izlenmiştir. Fenton ve Fenton-benzeri oksidasyonunda renk aromatiklikten daha fazla giderilmiştir. AY36 boyar maddesinin gideriminde, Fenton-benzeri oksidasyonun Fenton oksidasyon prosesinden daha etkili olduğu bulunmuştur.

Keywords

Acid Yellow 36 Fenton Proses Fenton-benzeri proses KOI

References

  • APHA, AWWA and WPCF ,1985. Standart Methods For the Examination of Water and Wastwater. Sixteenth Edition, Washington, DC.
  • Clarke,C.E., Kielar,F., Johnson, K.L., 2013. The oxidation of acid azo dye AY 36 by a manganese oxide containing mine waste. Journal of Hazardous Materials, 246: 310– 318.
  • Dokuzoğlu, Z.,Alkan, U., Yentürk, A., 2008. Reaktif Boyar Madde İçeren Tekstil Atıksularının İleri Oksidasyonu.Uludağ Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 13(2):119-128.
  • Forgacs, E., Cserháti, T., Oros, G., 2004. Removal of synthetic dyes from wastewaters: a review. Environment International, 30: 953– 971.
  • Gül,Ş., Ozcan Yıldırım, Ö., 2009. Degradation of Reactive Red 194 and Reactive Yellow 145 azo dyes by O3 and H2O2/UV-C processes. Chemical Engineering Journal, 155: 684-690.
  • Hanay, Ö., Hasar, H., 2007. Fenton oksidasyon prosesi ile tekstil endüstrisi atıksuyunda renk giderimi. Fırat Üniversitesi Fen ve Mühendislik Bilimler Dergisi, 19(4): 505-509.
  • Liu, X., Qiu, M., Huang, C., 2011. Degradation of the Reactive Black 5 by Fenton and Fenton like system.Procedia Engineering, 15: 4835 – 4840.
  • Malik, P.K., 2003. Use of activated carbons prepared from sawdust and rice-husk for adsorption of acid dyes: a case study of Acid Yellow 36. 56(3): 239–249.
  • Reife, A., Freeman, S., 1996. Environmental Chemistry of Dyes and Pigments, John Wiley&Sons, Inc., Kanada. Sajjad
  • Khezrianjoo and Hosakere Doddarevanna Revanasiddappa,2013. Photocatalytic Degradation of Acid Yellow 36 Using Zinc Oxide Photocatalyst in Aqueous Media. Journal of Catalysts.
  • Song, Y., Li, J., 2009. Degradation of C.I. Direct Black 168 from aqueous solution by y ash/H2O2 combining ultrasound. Ultrasonics Sonochemistry, 16: 440–444.
  • Yıldırım, A.Ö., 2009. Bazı Reaktif Boyar Maddelerin İleri Oksidasyon Yöntemleriyle Parçalanmasının İncelenmesi. Çukurova Üniversitesi, Fen Bilimleri Enstitüsü, Doktora Tezi.
  • Zhou, T., Lu, X., Wang, J., Wong, F.S., Li, Y., 2009. Rapid decolorization and mineralization of simulated textile wastewater in a heterogeneous Fenton like system with/ without external energy. Journal of Hazardous Materials, 165:193-199.
There are 13 citations in total.

Details

Journal Section Çevre Mühendisliği / Environment Engineering
Authors

Nihal Kocakaplan This is me

Neşe Ertugay This is me

Emine Malkoç This is me

Publication Date March 31, 2014
Submission Date September 27, 2013
Acceptance Date November 15, 2013
Published in Issue Year 2014 Volume: 4 Issue: 1

Cite

APA Kocakaplan, N., Ertugay, N., & Malkoç E. (2014). Removal of Acıd Yellow 36 Dyestuff Wıth Fenton and Fenton-Lıke Advanced Oxıdatıon Methods. Journal of the Institute of Science and Technology, 4(1), 41-48.
AMA Kocakaplan N, Ertugay N, Malkoç E. Removal of Acıd Yellow 36 Dyestuff Wıth Fenton and Fenton-Lıke Advanced Oxıdatıon Methods. J. Inst. Sci. and Tech. March 2014;4(1):41-48.
Chicago Kocakaplan, Nihal, Ertugay Neşe, and Malkoç Emine. “Removal of Acıd Yellow 36 Dyestuff Wıth Fenton and Fenton-Lıke Advanced Oxıdatıon Methods”. Journal of the Institute of Science and Technology 4, no. 1 (March 2014): 41-48.
EndNote Kocakaplan N, Ertugay N, Malkoç E (March 1, 2014) Removal of Acıd Yellow 36 Dyestuff Wıth Fenton and Fenton-Lıke Advanced Oxıdatıon Methods. Journal of the Institute of Science and Technology 4 1 41–48.
IEEE N. Kocakaplan, N. Ertugay, and Malkoç E., “Removal of Acıd Yellow 36 Dyestuff Wıth Fenton and Fenton-Lıke Advanced Oxıdatıon Methods”, J. Inst. Sci. and Tech., vol. 4, no. 1, pp. 41–48, 2014.
ISNAD Kocakaplan, Nihal et al. “Removal of Acıd Yellow 36 Dyestuff Wıth Fenton and Fenton-Lıke Advanced Oxıdatıon Methods”. Journal of the Institute of Science and Technology 4/1 (March 2014), 41-48.
JAMA Kocakaplan N, Ertugay N, Malkoç E. Removal of Acıd Yellow 36 Dyestuff Wıth Fenton and Fenton-Lıke Advanced Oxıdatıon Methods. J. Inst. Sci. and Tech. 2014;4:41–48.
MLA Kocakaplan, Nihal et al. “Removal of Acıd Yellow 36 Dyestuff Wıth Fenton and Fenton-Lıke Advanced Oxıdatıon Methods”. Journal of the Institute of Science and Technology, vol. 4, no. 1, 2014, pp. 41-48.
Vancouver Kocakaplan N, Ertugay N, Malkoç E. Removal of Acıd Yellow 36 Dyestuff Wıth Fenton and Fenton-Lıke Advanced Oxıdatıon Methods. J. Inst. Sci. and Tech. 2014;4(1):41-8.