SYNTHESIS OF VARIOUSLY FUNCTIONALIZED MOLECULES AND THEIR CHARACTERIZATION

Year 2016, Volume: 2 Issue: 2, 26 - 33, 01.06.2016

Özgül Haklı Said Nadeem Mehmet Ali Özler

Abstract

Three novel compounds i.e. 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl methyl]-1,10-phenanthrolin1-ium bromide Phen-PHTH , {2-[2-methoxy-4- 3-methoxy-4-{2-[tris propan-2- yl silyl]ethynyl}phenyl phenyl]ethynyl}tris propan-2-yl silane 4SGN-1 and 1- 3- chloropropyl -1,10-phenanthrolin-1-ium chloride SND-Cl2B were synthesized and characterized using NMR, MS, UV, FTIR and CNH analysis. Few reported compounds were also synthesized either with new procedures or modified procedures including 1-methyl-1,10- phenanthrolin-1-ium iodide SN1-OLD ,[25] diethyl [ 1,3-dioxo-2,3-dihydro-1H-isoindol-2- yl methyl]phosphonate SN2-B ,[26] 5H-6,7-dihydro-[1,4]diazepino[1,2,3,4- lmn][1,10]phenanthrolinediium dibromide SN1 ,[27] 2,9-dichloro-1,10-phenanthroline SN3 ,[27,28] 4,4'-diiodo-3,3'-dimethoxy-1,1'-Biphenyl DI ,[29] [2,2'-Bipyridine]-5,5'-diamine 4,4-amin-2,2 ,[30] 1E -1-phenyl-N-[4- 3-{4-[ E - phenylmethylidene amino]phenoxy}phenoxy phenyl]methanimine S11 ,[31] 4- 1Hphenanthro[9,10-d]imidazol-2-yl -phenol PPHOH [32] and octahydroimidazo[4,5- d]imidazolidine-2,5-dione glycoluril .

Keywords

phenanthrolines, N-alylation, organic synthesis, Sonogashira coupling

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