jotcsa

Journal of the Turkish Chemical Society Section A: Chemistry

2149-0120

Turkish Chemical Society

Inorganic Chemistry

İnorganik Kimya

Novel lanthanide metallophthalocyanines bearing iodine group and their singlet oxygen generation ability

https://orcid.org/0000-0001-7939-5380

Köksoy

Baybars

Bursa Teknik Üniversitesi

08 31 2022

9 3 741 750 12 16 2021 05 13 2022

2014

Journal of the Turkish Chemical Society Section A: Chemistry

In this study, five novel mono rare earth metallo phthalocyanine derivatives (1a-e) were synthesized by cyclotetramerization of 4-iodophthalonitrile and corresponding metal salts. These novel compounds were characterized by IR, elemental analyses, UV–vis, and MALDI-TOF spectral data. Moreover, the ability of singlet oxygen generation and aggregation behaviour of these phthaloyanines were investigated in dimethyl sulfoxide using UV-Vis spectroscopy. Gadolinium metallo phthalocyanine has the best singlet oxygen quantum yield and it can be a potential candidate for the photodynamic therapy (PDT) of cancer.

Phthalocyanine Iodine Lanthanide Singlet Oxygen

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