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Synthesis and Characterization of Poly(N-Hydroxymethyl Acrylamide)/Na-Montmorillonite Composites

Year 2017, Volume: 4 Issue: 1, 39 - 50, 13.07.2017
https://doi.org/10.18596/jotcsa.324877

Abstract

In this study, N-hydroxymethyl
acrylamide (
HMAm) monomer was mixed with Na-Montmorillonite (Na-MT) in
different ratio. The mixture was polymerized in the presence of benzoyl
peroxide (Bz2O2) with in-situ radical polymerization to
prepare poly(N-hydroxymethyl acrylamide) (PHMAm)/Na-Montmorillonite (Na-MT) composites.
Purified Na-MT, and also produced composites with different ratio were characterized
with Fourier transform infrared (FTIR)
spectroscopy,
X-ray diffraction (XRD), scanning electron microscopy
(SEM),
thermal analysis (TGA/DTA) techniques. The moisture retention,
water uptake,
adsorptive properties of composites was also researched. The XRD pattern demonstrated that Na-MT layers intercalated into the PHMAm matrix. The composites displayed
much better thermal stability than

the pure polymer.

References

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  • 15. Koksal, E., Afsin, B., Tabak, A., Caglar, B. Structural Characterization of Aniline-Bentonite Composite by FTIR, DTA/TG, and PXRD Analyses and BET Measurement. Spectroscopy Letters. 2011 Feb; 44(2):77-82.
  • 16. Zhang X, Xu R, Wu Z, Zhou C. The Synthesis and Characterization of Polyurethane/clay Nanocomposites. Polymer International. 2003 Apr; 52:790-94.
  • 17. Tiwari RR, Natajaran U. Thermal and Mechanical Properties of Melt Processed Intercalated Poly(methylmethacrylate)–organoclay Nanocompositesover a Wide Range of Filler Loading. Polymer International. 2008 Dec; 57(5):738-43.
  • 18. Peighambardoust SJ, Pourabbas B. Synthesis and Characterization of Conductive Polypyrrole/Montmorillonite Nanocomposites via One-pot Emulsion Polymerization. Macromolecular Symposia. 2007 Feb; 247(1):99-109.
  • 19. Samrana K, Shahzada A, Jiri P, Yogesh MJ. Polyaniline–sodium Montmorillonite Clay Nanocomposites: Effect of Clay Concentration on Thermal, Structural, and Electrical Properties. Journal of Materials Science. 2012 Jan; 47:420-28.
  • 20. Çelik M, Önal M. Synthesis and Characterization of Poly(glycidyl methacrylate)/Na-montmorillonite Nanocomposites. Journal of Applied Polymer Science. 2004 Nov; 94(4):1532-38.
  • 21. Sur GS, Lyu SG, Chang JH. Synthesis and LCST Behavior of Thermosensitive Poly (N-isopropylacrylamide)-Clay Nanocomposites. Journal of Industrial and Engineering Chemistry. 2003 Jan; 9(1):58-62.
  • 22. Boukerma K, Piquemal JY, Chehimi MM, Mravcakova M, Omastova M, Beaunier P. Synthesis and Interfacial Properties of Montmorillonite/polypyrrole Nanocomposites. Polymer. 2006 Jan; 47(2):569-76.
  • 23. Han B, Cheng A, Ji G, Wu S, Shen J. Effect of Organophilic Montmorillonite on Polyurethane/montmorillonite Nanocomposites. Journal of Applied Polymer Science. 2004 Feb; 91(4):2536-42.
  • 24. Low HY, Liu TX, Loh WW. Moisture Sorption and Permeation in Polyamide 6/clay Nanocomposite Films. Polymer International. 2004 Dec; 53(12):1973-78.
Year 2017, Volume: 4 Issue: 1, 39 - 50, 13.07.2017
https://doi.org/10.18596/jotcsa.324877

Abstract

References

  • 1. Akat H, Taşdelen MA, Du Prez F, Yagci Y. Synthesis and Characterization of Polymer/clay Nanocomposites by Intercalated Chain Transfer Agent. European Polymer Journal.2008 Apr; 44:1949–54.
  • 2. Çelik M, Önal M. Preparation and Characterization of Intercalated Polymethacrylamide/Na-Montmorillonite Nanocomposites. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry. 2006 Feb; 43(6):933–43.
  • 3. Choi HJ, Kim JW, Joo J, Kim BH. Synthesis and Electrorheology of Emulsion Intercalated PANI-clay Nanocomposite. Synthetic Metals. 2001 Mar; 121:1325–26.
  • 4. Anbarasan R, Arvind P, Dhanalakshmi V. Synthesis and Characterization of Polymethacrylamide–Clay Nanocomposites. Journal of Applied Polymer Science. 2011 Feb; 121(1):563-73.
  • 5. Koç Z, Çelik M, Önal M, Sarıkaya Y, Öner Y, Açık L. Study on the Synthesis and Properties of Polyacrylamide/Na-montmorillonite Nanocomposites. Journal of Composite Materials. 2014 May; 48(4):439–46.
  • 6. Caglar, B., Afsin, B., Tabak, A., Eren, E. Characterization of the Cation-exchanged Bentonites by XRPD, ATR, DTA/TG Analyses and BET Measurement. Chemical Engineering Journal. 2009 Jul; 149(1-3):242-48.
  • 7. Kumar S, Jog JP, Natarajan U. Preparation and Characterization of Poly(methylmethacrylate)–Clay Nanocomposites via Melt Intercalation: The Effect of Organoclay on the Structure and Thermal Properties. Journal of Applied Polymer Science. 2003 May; 89(5):1186-94.
  • 8. Gao, F. Clay/Polymer Composites: the Story. Materials Today. 2004 Nov; 7(11):50-55.
  • 9. Kraisiri D, Chantarasiri N, Pimpan V. Thermal Behavior of Poly(N-hydroxymethyl acrylamide) Synthesized by Inverse Emulsion Polymerization. Academic Journal of Science. 2012 May; 1(2):183-88.
  • 10. Önal M, Sarıkaya Y, Alemdaroğlu T, Bozdoğan İ. Isolation and Characterization of a Smectite as a Micro-Mesoporous Material from a Bentonite. Turkish Journal of Chemistry. 2003 Jun; 27(6):683-84.
  • 11. Koç Z, Çelik M, Önal M, Sarıkaya Y, Mogulkoç Y. Preparation and characterization of poly(2-hydroxyethyl methacrylate)/Na-montmorillonite Intercalated Nanocomposites. Journal of Polymer Engineering. 2013 Jan; 33(1):27–32.
  • 12. Çelik M, Önal M. Polythiophene/Na-montmorillonite Composites via Intercalative Polymerization. Journal of Thermoplastic Composite Materials. 2014 Feb; 27(2):145–59.
  • 13. Önal M, Çelik M. Polymethacrylamide/Na-montmorillonite Nanocomposites Synthesized by Free-radical Polymerization. Materials Letters. 2006 August; 60(1):48-52.
  • 14. Tong X, Zhao H, Tang T, Feng Z, Huang B. Preparation and Characterization of Poly(ethylacrylate)/Bentonite Nanocomposites by In Situ Emulsion Polymerization. Journal of Polymer Science Part A: Polymer Chemistry. 2002 Apr; 40(11):1706-11.
  • 15. Koksal, E., Afsin, B., Tabak, A., Caglar, B. Structural Characterization of Aniline-Bentonite Composite by FTIR, DTA/TG, and PXRD Analyses and BET Measurement. Spectroscopy Letters. 2011 Feb; 44(2):77-82.
  • 16. Zhang X, Xu R, Wu Z, Zhou C. The Synthesis and Characterization of Polyurethane/clay Nanocomposites. Polymer International. 2003 Apr; 52:790-94.
  • 17. Tiwari RR, Natajaran U. Thermal and Mechanical Properties of Melt Processed Intercalated Poly(methylmethacrylate)–organoclay Nanocompositesover a Wide Range of Filler Loading. Polymer International. 2008 Dec; 57(5):738-43.
  • 18. Peighambardoust SJ, Pourabbas B. Synthesis and Characterization of Conductive Polypyrrole/Montmorillonite Nanocomposites via One-pot Emulsion Polymerization. Macromolecular Symposia. 2007 Feb; 247(1):99-109.
  • 19. Samrana K, Shahzada A, Jiri P, Yogesh MJ. Polyaniline–sodium Montmorillonite Clay Nanocomposites: Effect of Clay Concentration on Thermal, Structural, and Electrical Properties. Journal of Materials Science. 2012 Jan; 47:420-28.
  • 20. Çelik M, Önal M. Synthesis and Characterization of Poly(glycidyl methacrylate)/Na-montmorillonite Nanocomposites. Journal of Applied Polymer Science. 2004 Nov; 94(4):1532-38.
  • 21. Sur GS, Lyu SG, Chang JH. Synthesis and LCST Behavior of Thermosensitive Poly (N-isopropylacrylamide)-Clay Nanocomposites. Journal of Industrial and Engineering Chemistry. 2003 Jan; 9(1):58-62.
  • 22. Boukerma K, Piquemal JY, Chehimi MM, Mravcakova M, Omastova M, Beaunier P. Synthesis and Interfacial Properties of Montmorillonite/polypyrrole Nanocomposites. Polymer. 2006 Jan; 47(2):569-76.
  • 23. Han B, Cheng A, Ji G, Wu S, Shen J. Effect of Organophilic Montmorillonite on Polyurethane/montmorillonite Nanocomposites. Journal of Applied Polymer Science. 2004 Feb; 91(4):2536-42.
  • 24. Low HY, Liu TX, Loh WW. Moisture Sorption and Permeation in Polyamide 6/clay Nanocomposite Films. Polymer International. 2004 Dec; 53(12):1973-78.
There are 24 citations in total.

Details

Subjects Engineering, Chemical Engineering
Journal Section Articles
Authors

Sibel Erol Dağ This is me

Pınar Acar Bozkurt

Meltem Çelik

Publication Date July 13, 2017
Submission Date June 30, 2017
Acceptance Date October 3, 2017
Published in Issue Year 2017 Volume: 4 Issue: 1

Cite

Vancouver Erol Dağ S, Acar Bozkurt P, Çelik M. Synthesis and Characterization of Poly(N-Hydroxymethyl Acrylamide)/Na-Montmorillonite Composites. JOTCSA. 2017;4(1):39-50.