Synthesis of Aromatic Structured Di-cationic Surfactants Used as Inhibitors Against Corrosion of Carbon Steel in Acidic Medium

Year 2018, Volume: 5 Issue: 2, 819 - 834, 01.01.2018

Serkan Öztürk , Ayhan Yıldırım

https://doi.org/10.18596/jotcsa.399297

Cited By: 3

Abstract

In this study, three aromatic-structured di-cationic
surfactants with different length carbon chains were synthesized and inhibition
efficiencies against metal corrosion in 1.0 M HCl solution were investigated.
Corrosion inhibition efficiencies of di-cationic surfactants that structurally
illuminated by spectroscopic methods (FT-IR and NMR) were determined in acidic
media by gravimetric method based on weight loss in metal coupons. Corrosion
tests resulted in good inhibition efficiencies (90.40% - 96.85%) against
metallic corrosion at different concentrations of inhibitors. By using the
weight loss values, corrosion rates were also calculated in the inhibited and
uninhibited medium. Finally, images of metal surfaces were obtained using
scanning electron microscopy to support the obtained corrosion inhibition
effect results.

Keywords

Di-cationic surfactants, carbon steel, corrosion inhibitor, acidic medium, SEM.

References

• 1. Görenler A. Al-Si Matrisli Kompozit Malzemelerin Korozyon Davranışlarının İncelenmesi. Yıldız Technical University, Institute of Science, Master of Science Thesis, 2007 İstanbul.
• 2. Üneri S. Corrosion and Prevention. Corrosion Society, 1998, Ankara, 413 s.
• 3. Öztürk S. Design and Synthesis of Some Amide Compounds as Potential Corrosion Inhibitors. Uludag University, Institute of Science and Technology, PhD Thesis, 2013, Bursa.
• 4. Papavinasam, S. Corrosion Inhibitors. In: Uhlig’s Corrosion Handbook, W.R. Revie (Editor), Wiley Interscience, 2000, p.1089-1105.
• 5. Hegazy MA. Novel cationic surfactant based on triazole as a corrosion inhibitor for carbon steel in phosphoric acid produced by dihydrate wet process. J. Mol. Liq. 2015 Aug; 208:227-36.
• 6. Asefi D, Arami M, Sarabi AA, Mahmoodi NM. The chain length influence of cationic surfactant and role of nonionic co-surfactants on controlling the corrosion rate of steel in acidic media. Corros. Sci. 2009 Aug; 51:1817-21.
• 7. El Achouri M, Infante MR, Izquierdo F, Kertit S, Gouttaya HM, Nciri B. Synthesis of some cationic gemini surfactants and their inhibitive effect on iron corrosion in hydrochloric acid medium. Corros. Sci. 2001 Jan; 43:19-35.
• 8. Hegazy MA, Abdallah M, Ahmed H. Novel cationic gemini surfactants as corrosion inhibitors for carbon steel pipelines. Corros. Sci. 2010 Sep; 52:2897-2904.
• 9. Likhanova NV, Dominguez-Aguilar MA, Olivares-Xometl O, Nava-Entzana N, Arce E, Dorantes H. The effect of ionic liquids with imidazolium and pyridinium cations on the corrosion inhibition of mild steel in acidic environment. Corros. Sci. 2010 Jun; 52:2088-97.
• 10. Asefi D, Arami M, Mahmoodi NM. Electrochemical effect of cationic gemini surfactant and halide salts on corrosion inhibition of low carbon steel in acid medium. Corros. Sci. 2010 Mar, 52:794-800.
• 11. Hegazy MA, Badawi AM, Abd El Rehim SS, Kamel WM. Corrosion inhibition of carbon steel using novel N-(2-(2-mercaptoacetoxy)ethyl)-N,N-dimethyl dodecan-1-aminium bromide during acid pickling. Corros. Sci. 2013 Apr; 69:110-22.
• 12. Hegazy MA, El-Tabei AS. Synthesis, surface properties, synergism parameter and inhibitive performance of novel cationic gemini surfactant on carbon steel corrosion in 1 M HCl solution. J. Surf. Deterg. 2013 Mar; 16: 221-32.
• 13. Yıldırım A, Öztürk S, Çetin M. Novel amide-based cationic surfactants as efficient corrosion inhibitors for carbon steel in HCl and H2SO4 media. J. Surf. Deterg. 2013 Jan; 16:13–23.
• 14. Öztürk S, Yıldırım A, Çetin M, Tavaslı M. Synthesis of quaternary, long-chain N-alkyl amides and their corrosion inhibition in acidic media. J. Surfact. Deterg. 2014 May; 17: 471–81.
• 15. Hegazy MA, Abd El-Rehim SS, Badr EA, Kamel WM, Youssif AH. Mono-, Di- and Tetra-Cationic Surfactants as Carbon Steel Corrosion Inhibitors, J. Surfact. Deterg. 2015 Nov; 18:1033–42.
• 16. Abd-Elaal AA, Shaban SM, Tawfik SM. Three Gemini cationic surfactants based on polyethylene glycol as effective corrosion inhibitor for mild steel in acidic environment. Journal of the Association of Arab Universities for Basic and Applied Sciences 2017 Oct; 24:54–65.
• 17. Heakal F. El-Taib, Deyab MA, Osman MM, Nessim MI, Elkholy AE. Synthesis and assessment of new cationic gemini surfactants as inhibitors for carbon steel corrosion in oilfield water. RSC Adv. 2017 Oct; 7:47335-52.
• 18. Hegazy MA, Azam EMS, Kandil NG, Badawi AM, Sami RM. Corrosion inhibition of carbon steel pipelines by some new amphoteric and di-cationic surfactants in acidic solution by chemical and electrochemical methods. J. Surfact. Deterg. 2016 Jul; 19:861–71.
• 19. Hegazy MA, El-Tabei AS, Bedair AH, Sadeq MA. Synthesis and inhibitive performance of novel cationic and gemini surfactants on carbon steel corrosion in 0.5 M H2SO4 solution, RSC Adv., 2015; 5:64633-50.
• 20. Abd El-Lateef HM, Soliman KA, Tantawy AH. Novel synthesized Schiff Base based cationic gemini surfactants: Electrochemical investigation, theoretical modeling and applicability as biodegradable inhibitors for mild steel against acidic corrosion. J. Mol. Liq. 2017 Apr; 232:478–98.
• 21. Kaczerewska O, Leiva-Garcia R, Akid R, Brycki B, Kowalczyk I, Pospieszny T. Effectiveness of O-bridged cationic gemini surfactants as corrosion inhibitors for stainless steel in 3 M HCl: Experimental and theoretical studies, J. Mol. Liq. 2018 Jan; 249:1113–24.
• 22. ASTM NACE / ASTMG31-12a, Standard Guide for Laboratory Immersion Corrosion Testing of Metals, ASTM International, West Conshohocken, PA, 2012 Oct; p.10 www.astm.org DOI: 10.1520/NACEASTMG0031-12A
• 23. Anonymous. Cold rolled low carbon steel flat products for cold forming - Technical delivery conditions; German version EN 10130:2006, DIN Deutsches Institut für Normung e. V., 14s., 2007, Berlin, Germany.
• 24. Abdelrazik H, Mona M, Rehim HA. Surface active hyperbranched polyamide-ester as a corrosion inhibitor for carbon steel in both neutral and acidic media. Anti-Corros. Method M. 2015; 62:95-102.
• 25. Lashgari M, Arshadi MR, Biglar M. Comparative studies of some heterocyclic compounds as corrosion inhibitors of copper in phosphoric acid media. Chem. Eng. Commun. 2010; 197:1303-14.
• 26. Sobhi M, El-sayed R, Abdallah M. The effect of non ionic surfactants containing triazole, thiadiazole and oxadiazole as inhibitors of the corrosion of carbon steel in 1M hydrochloric acid. J. Surfact. Deterg. 2013 Nov; 16:937–46.
• 27. Miller RF, Go TS, Wilson G.R. Method of making corrosion inhibiting polyamine amides, the amides, and use therefor. 1984 Apr; U.S. Patent 4,440,666
• 28. Emregul KC, Hayvali M. Studies on the effect of a newly synthesized Schiff base compound from phenazone and vanillin on the corrosion of steel in 2 M HCl. Corros. Sci. 2006 Apr; 48:797–812.