Synthesis of Polyaniline / Biochar composite material and modeling with nonlinear model for removal of copper (II) heavy metal ions

Year 2021, Volume: 8 Issue: 1, 289 - 302, 28.02.2021

Halime Yakışık , Uğur Özveren

https://doi.org/10.18596/jotcsa.635073

Cited By: 5

Abstract

Water is one of the most important
compounds for the existence of nature and human life. Nowadays, as a result of
increasing industrialization and industrial production, heavy metals pollute
clean water resources. Copper (II) ions are the leading metals in the industry.
There is a high proportion of copper (II) ions especially in the production of
printed electrical and electronic circuit, paper production, silicon synthesis,
wood preservation, fertilizer production, oil refining enterprises, paint and
pigment production, steel and similar metal industry, motor and motor vehicle
production, aircraft industry and metal industry wastes. When copper (II) ions
are present in trace amounts, they are beneficial to human health, while
excessive amounts show poison effect and cause acute diseases.

In this study, for the
removal of copper (II) ions in waste water; biochar obtained from torrefied
hazelnut shell and was used to synthesize Polyaniline/Biochar composite by comodfification
with polianaline. During the study, optimal temperature, pH, adsorbent amount
and contact time parameters were investigated. Moreover, in this study, a new nonlinear model was also developed
by using temperature, pH, adsorbent dossage and contact time as an input
parameters of the synthesised polymeric Polyaniline/Biochar composite for the
removal of copper (II) ions. 

Keywords

Heavy metal removal, Copper (II)

References

• 1. Rashid N, Rehman MSU, Han J-I. Recycling and reuse of spent microalgal biomass for sustainable biofuels. Biochemical engineering journal. 2013;75:101-7.
• 2. Patra J, Panda S, Dhal N. Biochar as a low-cost adsorbent for heavy metal removal: A review. Int J Res Biosci. 2017;6:1-7.
• 3. Sardar K, Ali S, Hameed S, Afzal S, Fatima S, Shakoor MB, et al. Heavy metals contamination and what are the impacts on living organisms. Greener Journal of Environmental Management and Public Safety. 2013;2(4):172-9.
• 4. Galil N, Rebhun M. Primary chemical treatment minimizing dependence on bioprocess in small treatment plants. Water Sci Technol. 1990;22(3-4):203-10.
• 5. Kurniawan TA, Chan GY, Lo W-H, Babel S. Physico–chemical treatment techniques for wastewater laden with heavy metals. Chem Eng J. 2006;118(1-2):83-98.
• 6. O’Connell DW, Birkinshaw C, O’Dwyer TF. Heavy metal adsorbents prepared from the modification of cellulose: A review. Bioresource technology. 2008;99(15):6709-24.
• 7. Wang Y-H, Lin S-H, Juang R-S. Removal of heavy metal ions from aqueous solutions using various low-cost adsorbents. Journal of Hazardous Materials. 2003;102(2-3):291-302.
• 8. Fu F, Wang Q. Removal of heavy metal ions from wastewaters: a review. Journal of environmental management. 2011;92(3):407-18.
• 9. Khezami L, Capart R. Removal of chromium (VI) from aqueous solution by activated carbons: kinetic and equilibrium studies. Journal of hazardous materials. 2005;123(1-3):223-31.
• 10. Uzun I, Güzel F. Adsorption of some heavy metal ions from aqueous solution by activated carbon and comparison of percent adsorption results of activated carbon with those of some other adsorbents. Turkish Journal of Chemistry. 2000;24(3):291-8.
• 11. Biškup B, Subotić B. Kinetic analysis of the exchange processes between sodium ions from zeolite A and cadmium, copper and nickel ions from solutions. Sep Purif Technol. 2004;37(1):17-31.
• 12. Cincotti A, Mameli A, Locci AM, Orrù R, Cao G. Heavy metals uptake by Sardinian natural zeolites: Experiment and modeling. Ind Eng Chem Res. 2006;45(3):1074-84.
• 13. Gupta VK, Ali I. Removal of lead and chromium from wastewater using bagasse fly ash - a sugar industry waste. J Colloid Interf Sci. 2004;271(2):321-8.
• 14. Haroun AA, El-Halawany NR. Preparation and Evaluation of Novel Interpenetrating Polymer Network-Based on Newspaper Pulp for Removal of Copper Ions. Polym-Plast Technol. 2011;50(3):232-8.
• 15. Haroun AA, Mashaly HM, El-Sayed NH. Novel nanocomposites based on gelatin/HPET/chitosan with high performance acid red 150 dye adsorption. Clean Technol Envir. 2013;15(2):367-74.
• 16. Kardam A, Raj KR, Srivastava S, Srivastava MM. Nanocellulose fibers for biosorption of cadmium, nickel, and lead ions from aqueous solution. Clean Technol Envir. 2014;16(2):385-93.
• 17. Huang Q, Liu MY, Mao LC, Xu DZ, Zeng GJ, Huang HY, et al. Surface functionalized SiO2 nanoparticles with cationic polymers via the combination of mussel inspired chemistry and surface initiated atom transfer radical polymerization: Characterization and enhanced removal of organic dye. J Colloid Interf Sci. 2017;499:170-9.
• 18. Huang QA, Liu MY, Chen JY, Wan Q, Tian JW, Huang L, et al. Facile preparation of MoS2 based polymer composites via mussel inspired chemistry and their high efficiency for removal of organic dyes. Appl Surf Sci. 2017;419:35-44.
• 19. Zhang XY, Huang Q, Liu MY, Tian JW, Zeng GJ, Li Z, et al. Preparation of amine functionalized carbon nanotubes via a bioinspired strategy and their application in Cu2+ removal. Appl Surf Sci. 2015;343:19-27.
• 20. Gier S, Johns WD. Heavy metal-adsorption on micas and clay minerals studied by X-ray photoelectron spectroscopy. Applied Clay Science. 2000;16(5-6):289-99.
• 21. Koppelman M, Dillard J. A study of the adsorption of Ni (II) and Cu (II) by clay minerals. Clays and Clay Minerals. 1977;25(6):457-62.
• 22. Dang V, Doan H, Dang-Vu T, Lohi A. Equilibrium and kinetics of biosorption of cadmium (II) and copper (II) ions by wheat straw. Bioresource technology. 2009;100(1):211-9.
• 23. Hadi B, Margaritis A, Berruti F, Bergougnou M. Kinetics and equilibrium of cadmium biosorption by yeast cells S. cerevisiae and K. fragilis. Int J Chem React Eng. 2003;1(1).
• 24. Sharma YC, Uma, Gode F. Engineering Data for Optimization of Preparation of Activated Carbon from an Economically Viable Material. J Chem Eng Data. 2010;55(9):3991-4.
• 25. Yang T, Lua AC. Textural and chemical properties of zinc chloride activated carbons prepared from pistachio-nut shells. Mater Chem Phys. 2006;100(2-3):438-44.
• 26. Foroushani FT, Tavanai H, Hosseini FA. An investigation on the effect of KMnO4 on the pore characteristics of pistachio nut shell based activated carbon. Microporous and Mesoporous Materials. 2016;230:39-48.
• 27. Zheng W, Guo MX, Chow T, Bennett DN, Rajagopalan N. Sorption properties of greenwaste biochar for two triazine pesticides. Journal of Hazardous Materials. 2010;181(1-3):121-6.
• 28. Anderson N, Jones J, Page-Dumroese D, McCollum D, Baker S, Loeffler D, et al. A comparison of producer gas, biochar, and activated carbon from two distributed scale thermochemical conversion systems used to process forest biomass. Energies. 2013;6(1):164-83.
• 29. Liu W-J, Zeng F-X, Jiang H, Zhang X-S. Preparation of high adsorption capacity bio-chars from waste biomass. Bioresource technology. 2011;102(17):8247-52.
• 30. Nagarale R, Gohil G, Shahi VK. Recent developments on ion-exchange membranes and electro-membrane processes. Advances in colloid and interface science. 2006;119(2-3):97-130.
• 31. Zhou Y, Gao B, Zimmerman AR, Fang J, Sun Y, Cao X. Sorption of heavy metals on chitosan-modified biochars and its biological effects. Chemical Engineering Journal. 2013;231:512-8.
• 32. Zou Y, Wang X, Khan A, Wang P, Liu Y, Alsaedi A, et al. Environmental remediation and application of nanoscale zero-valent iron and its composites for the removal of heavy metal ions: a review. Environmental science & technology. 2016;50(14):7290-304.
• 33. Gao B, Lu J, Zhou H-D, Yin S-H, Hao H. The distribution, accumulation and potential source of seldom monitored trace elements in sediments of Beijiang River, South China. Water Science and Technology. 2012;65(12):2118-24.
• 34. Stern BR. Essentiality and toxicity in copper health risk assessment: overview, update and regulatory considerations. Journal of Toxicology and Environmental Health, Part A. 2010;73(2-3):114-27.
• 35. Bingol H, Coskun A, Akgemci EG, Kaya B, Atalay T. New Copper (II) and Nickel (II) Complexes of 4‐Morpholinoaceto‐phenone Thiosemicarbazone: Structural, Electrochemical and Antimicrobial Studies. Chinese Journal of Chemistry. 2007;25(3):307-11.
• 36. Camakaris J, Voskoboinik I, Mercer J. Molecular mechanisms of copper homeostasis. Biochemical and biophysical research communications. 1999;261(2):225-32.
• 37. Hosokawa M, Nogi K, Naito M, Yokoyama T. Nanoparticle technology handbook: Elsevier; 2012.
• 38. Ahmaruzzaman M, Sharma D. Adsorption of phenols from wastewater. Journal of Colloid and Interface Science. 2005;287(1):14-24.
• 39. Aksu Z, Tatlı Aİ, Tunç Ö. A comparative adsorption/biosorption study of Acid Blue 161: Effect of temperature on equilibrium and kinetic parameters. Chemical Engineering Journal. 2008;142(1):23-39.
• 40. Rahmani A, Mousavi HZ, Fazli M. Effect of nanostructure alumina on adsorption of heavy metals. Desalination. 2010;253(1-3):94-100.