Nonlinear Fitting for Estimation of Adsorption Equilibrium, Kinetic and Thermodynamic Parameters of Methylene Blue onto Activated Carbon

Year 2022, Volume: 9 Issue: 1, 67 - 84, 28.02.2022

Ibrahim Yaagoub Erwa , Omer Ishag , Omar Alrefaei , Issa Hassan

https://doi.org/10.18596/jotcsa.904311

Cited By: 4

Abstract

Adsorption equilibrium, kinetics, and thermodynamics of methylene blue dye (MB) from aqueous solutions onto activated carbon (AC) synthesized from pomegranate peel was conducted in controlled batch systems. The effects of initial MB concentration, AC particle size, contact time, and temperature on adsorption were evaluated. Under the optimized conditions (i.e., contact time 120 min, pH ∼ 5, particle size 125 µm, dye concentration 20 mg/L, temperature 333 K, and 0.5 g AC/50 mL MB solution), the removal percentages can achieve ∼ 98.28%. The nonlinear method was conducted for estimating the equilibrium and kinetic parameters, where the equilibrium data were fitted to the Langmuir isotherm model. The Langmuir isotherm suggested a maximum monolayer adsorption capacity of 5.03 mg/g at 60 °C. The pseudo-second-order kinetic model provided the best fit to the experimental data compared with the pseudo-first-order. Kinetic studies showed that the adsorption equilibrium was rapidly established, with low activation energy entailed for adsorption (Ea; 15.60 kJ/mol). Thermodynamic parameters showed that the adsorption was spontaneous (−∆G° and +∆S°), exothermic (+∆H°), and favorable at ambient conditions.

Keywords

Methylene blue, Adsorption isotherms, Kinetics, Thermodynamic parameters, Nonlinear fitting

Supporting Institution

International University of Africa

Thanks

The authors express their sincere gratitude to the Department of Applied Chemistry, International University of Africa, in Sudan, for financially supporting this study.

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