jotcsb

Journal of the Turkish Chemical Society Section B: Chemical Engineering

2564-6907

Turkish Chemical Society

Material Production Technologies

Malzeme Üretim Teknolojileri

Modification of safflower oil with triallyletheracrylate dienophile

https://orcid.org/0000-0002-6796-6067

Uğuz

Gediz

ONDOKUZ MAYIS UNIVERSITY Basan

Satilmiş

HITIT UNIVERSITY

05 22 2019

2 1 45 50 03 26 2019 05 19 2019

2016

Journal of the Turkish Chemical Society Section B: Chemical Engineering

Alkydresins and reactive diluents which are among the main components of dye andcoating industries, have properties such as binding and easy application. Inorder to improve the film properties of alkyd resins, a wide variety ofmodification studies are carried out. In this study, safflower oil was modifiedwith triallyletheracrylate dienophile (TAEA) with Diels - Alder reactions andthe product was called as reactive diluent (triallyletheracrylate safflower oil).TAEASO reactive diluent have been characterized by Nuclear Magnetic Resonance(NMR) and Fourier Transform Infrared Spectroscopy (FT-IR) methods. Then, thedifferent dye formulations were prepared with a certain proportions of reactivediluent, wetting and drying agents and a soy oil (SO) based alkyd resin. Dyeformulations were called as SO, TAEASO10-SO, TAEASO20-SO, TAEASO30-SO, TAEASO40-SO.The viscosity reductions of the dye formulations were determined, and then thedye formulations were applied to surface of Aliminium plates as film and the filmproperties such as drying time, film thickness, pencil hardness, brightnesswere evaluated after the curing process. The results show that the viscosityreduction is proportional to the ratio of the reactive diluent. As a result ofthe study, the drying time for the reactive diluents with alkyds were 1.5 timesfaster than alkyd alone.

Alkyd Diels-Alder Safflower

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FBE19004.17.002

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