Removal of Lead and Cadmium Ions from Aqueous Solutions by Olive Pomace as a Low-Cost Biosorbent

Year 2019, Volume: 2 Issue: 2, 121 - 132, 15.11.2019

Onur Uzunkavak Günseli Özdemir

Abstract

In this study, the adsorptive performance of olive
pomace on lead and cadmium removal from aqueous solutions was investigated.
Process parameters such as particle size, solution pH, contact time, initial
ion concentration, and incubation temperature were evaluated by batch experiments.
It was found that lead and cadmium adsorption follows a pseudo second order
kinetics. Maximum sorption for lead and cadmium ions was obtained at pH 5.5 and
6 as 33 and 8 mg/g, respectively, with 1 g/L olive pomace loading. Adsorption isotherms
were best fitted with Redlich-Peterson and Langmuir-Freundlich models for lead
and cadmium adsorption, respectively. Thermodynamic calculations revealed that the
adsorption process is feasible and spontaneous in nature. Point of zero charge
(pH_PZC) and BET surface area measurements were performed in
adsorbent characterization.

Keywords

Wastewater treatment, Biosorption, olive pomace, lead, cadmium

Supporting Institution

Ege University Research Fund

Project Number

14-MUH-052

Thanks

Van Yüzüncü Yıl University, 13th National Chemical Engineering Congress

References

• 1. Yakub A, Mughal MS, Mukhtar H, Spirogyra as an efficient biosorbent of cadmium: A mechanistic approach. Pakistan Journal of Botany. 2016; 48(6): 2563-70.
• 2. Lawal OS, Ayanda OS, Rabiu OO, Adebowale KO, Application of black walnut (Juglannigra) husk for the removal of lead (II) ion from aqueous solution. IWA Publishing. 2017; 1-10.
• 3. Verma A, Kumar S, Kumar S, Biosorption of lead ions from the aqueous solution by Sargassumfilipendula: Equilibrium and kinetic studies. Journal of Environmental Chemical Engineering. 2016; 4: 4587-99.
• 4. Husein DZ, Aazam E, Battia M, Adsorption of cadmium (II) onto watermelon rind under microwave radiation and application into surface water from Jeddah, Saudi Arabia. Arabian Journal for Science and Engineering. 2017; 42: 2403-15.
• 5. Mohammed A, Biosorption of lead, cadmium, and zinc onto sunflower shell: Equilibrium, kinetic, and thermodynamic studies. Iraqi Journal of Chemical and Petroleum Engineering. 2015; 16(1); 91-105.
• 6. Liu X, Chen ZQ, Han B, Su CL, Han Q, Chen, WZ, Biosorption of copper ions from aqueous solution using rape straw powders: Optimization, equilibrium and kinetic studies. Ecotoxicology and Environmental Safety. 2018; 150: 251-9.
• 7. Morosanu I, Teodosiu C, Paduraru C, Ibanescu D, Tofan, L, Biosorption of lead ions from aqueous effluents by rapeseed biomass. New Biotechnology. 2017; 39: 110-24.
• 8. Nishikawa E, da Silva MGC, Vieira MGA, Cadmium biosorption by alginate extraction waste and process overview in life cycle assessment context. Journal of Cleaner Production. 2018; 178: 166-75.
• 9. Tchounwou PB, Yedjou CG, Patlolla AK, Sutton DJ, Heavy Metals Toxicity and the Environment. EXS. 2012; 101: 133-64.
• 10. Martin-Lara MA, Pagnanelli F, Mainelli S, Calero M, Toro L, Chemical treatment of olive pomace: Effect on acid-basic properties and metal biosorption capacity. Journal of Hazardous Materials. 2008; 156(1-3): 448-57.
• 11. Martin-Lara MA, Blazquez G, Ronda A, Perez A, Calero M, Development and characterization of biosorbents to remove heavy metals from aqueous solutions by chemical treatment of olive stone. Industrial & Engineering Chemistry Research. 2013; 52: 10809-19.
• 12. Shouman MA, Fathy NA, Khedr SA, Attia AA, Comparative biosorption studies of hexavalent chromium ion onto raw and modified palm branches. Advances in Physical Chemistry. 2013; 1-9.
• 13. Lagergren S, About the Theory of so Called Adsorption of Soluble Substances. Kungliga Svenska Vetenskapsakademiens Handlingar. 1898; 24: 1-39.
• 14. Febrianto J, Kosasih AN, Sunarso J, Ju YH, Indraswati N, Ismadji S, Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: A summary of recent studies. Journal of Hazardous Materials. 2009; 162: 616-45.
• 15. Weber JW, Morris JC, Kinetics of adsorption on carbon from solution. Journal of the Sanitary Engineering Division. 1963; 89: 31-60.
• 16. Hashem A, Adam E, Hussein HA, Sanousy MA, Ayoub A, Bioadsorption of Cd (II) from contaminated water on treated sawdust: Adsorption mechanism and optimization. Journal of Water Resource and Protection. 2013; 5: 82-90.
• 17. Chakrapani C, Babu CS, Vani KNK, Rao KS, Adsorption kinetics for the removal of fluoride from aqueous solution by activated carbon adsorbents derived from the peels of selected citrus fruits. E-Journal of Chemistry. 2010; 7(1): 419-27.
• 18. Qiu H, Pan B-C, Zhang Q-J, Zhang W-M, Zhang Q-X, Critical review in adsorption kinetic models. Journal of Zhejiang University SCIENCE A. 2009; 10(5): 716-24.
• 19. Foo KY, Hameed BH, Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal. 2010; 156: 2-10.
• 20. Montazer-Rahmati MM, Rabbani P, Abdolali, A, Keshtkar AR, Kinetics and equilibrium studies on biosorption of cadmium, lead, and nickel ions from aqueous solutions by intact and chemically modified brown algae. Journal of Hazardous Materials. 2011; 185: 401-407.
• 21. Saadi R, Saadi Z, Fazaeli R, Fard NE, Monolayer and multilayer adsorption isotherm models for sorption from aqueous media. Korean Journal of Chemical Engineering. 2015; 32(5): 787-799.
• 22. Ghaffari HR, Pasalari H, Tajvar A, Dindarloo K, Goudarzi B, Alipour V, Ghanbarneajd A, Linear and nonlinear two-parameter adsorption isotherm modeling: A case-study. The International Journal of Engineering and Science. 2017; 6(9): 1-11.
• 23. Tran HN, You SJ, Hosseini-Bandegharaei A, Chao HP, Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: A critical review. Water Research. 2017; 120: 88-116.
• 24. Almasi A, Omidi M, Khodadadian M, Khamutian R, Gholivand MB, Lead(II) and cadmium(II) removal from aqueous solution using processed walnut shell: Kinetic and equilibrium study. Toxicological & Environmental Chemistry. 2012; 94(4): 660-671.
• 25. Feng N, Guo X, Liang S, Adsorption study of copper (II) by chemically modified orange peel. Journal of Hazardous Materials. 2009; 164(2-3): 1286-1292.
• 26. Moyo M, Pakade VE, Modise SJ, Biosorption of lead(II) by chemically modified Mangiferaindica seed shells: Adsorbent preparation, characterization and performance assessment. Process Safety and Environmental Protection. 2017; 111: 40-51.
• 27. Pehlivan E, Yanik BH, Ahmetli G, Pehlivan M, Equilibrium isotherm studies for the uptake of cadmium and lead ions onto sugar beet pulp. Bioresource Technology. 2008; 99(9): 3520-3527.
• 28. Tadashi M, editor. Thermodynamics. Chapter 16: Insight Into Adsorption Thermodynamics, InTech; 2011.