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DETERMINATION OF THE CHEMICAL EFFECT IN THE LANTHANIDE GROUP OF ELEMENTS USING WAVE DISPERSIVE X-RAY SPECTROMETRY

Year 2018, Volume: 1 Issue: 2, 1 - 11, 30.11.2018

Abstract

In this study,
chemical effect  changes on the lines
of 
Lα1, Lα2, Lβ1, Lβ2, Lβ3, Lβ4, Lβ6, Lγ1, Lγ2 and Lγ3 were examined by using a Rigaku single-crystal
(LiF) ZSX 100e wavelength dispersive X-Ray spectrometer (WDXRF). In our
research, proportional counter (PC) was used for wavelengths less than 0,336 nm
and scintillation counter (SC) was used for wavelengths more than 0,154 nm.
X-rays could be counted simultaneously both PC and SC in LiF crystal of our
device. Depending on the chemical state of the mater, chemical effect may bring
about some modifications in values of energy of X-Ray line, full width at half
maximum (FWHM), asymmetry index (AI). These effects are different for each main
group elements have been investigated to what or what could be caused these
differences. Also chemical effects researched depend on status of the chemical
bonds and number of valence electrons. Results of the measurements evaluated by
Orjin 8.0 program and in order to prevent from faults may occur during the
measurements, best experimental geometry conditions determined.

References

  • 1- P. Glatzel,U. Bergmann, High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes-electronic and structural information, Coordination Chemistry Reviews, 2005, 249, 65-95.
  • 2- J.H. Guo, S.M. Butorin, N. Wassdahl, P. Skytt, J. Nordgren and Y. Ma, Electronic structure of La2−xSrxCuO4 studied by soft-x-ray-fluorescence spectroscopy with tunable excitation, Phys. Rev. B, 1994, 49, 1376.
  • 3- S.M. Butorin, D.C. Mancini, J.H. Guo, N. Wassdahl, J. Nordgren, M. Nakazawa, S. Tanaka, T. Uozumi, A. Kotani, Y. Ma, K. E. Myano, B.A. Karlin and D.K. Shuh, Resonant X-Ray Fluorescence Spectroscopy of Correlated Systems: A Probe of Charge-Transfer Excitations, Phys. Rev. Lett., 1996, 77, 574.
  • 4- T.Yoshimuraa, Y. Tamenori, A. Suzuki, R. Nakashima, N. Iwasaki, H. Hasegawae, H. Kawahataa, Element profile and chemical environment of sulfur in a giant clam shell: Insights from μ-XRF and X-ray absorption near-edge structure, Chemical Geology, 2013, 352, 170-175.
  • 5- D.B. Hunter, P.M. Bertsch, K.M. Kemner and S.B. Clark, Distribution and Chemical Speciation of Metals and Metalloids in Biota Collected from Contaminated Environments by Spatially Resolved XRF, XANES, and EXAFS, Proceedings of the 9th International Conference on X-Ray Absorption Fine Structure, J. Phys. IV, France 1997, C2-767-771.
  • 6- E. Boydaş, E. Orhan, M.G. Boydaş, E. Cömert, Chemical shifts of Ka and Kb1,3 X-ray emission spectra for oxygen compounds of Ti, Cr, Fe, Co, Cu with WDXRF, Procedia - Social and Behavioral Sciences 195 ( 2015 ) 1757 –1761.
  • 7- S. Porikli, D. Demir and Y. Kurucu, Variation of Kβ/Kα X-ray intensity ratio and lineshape with the effects of external magnetic field and chemical combination, 2008, Eur. Phys. J. D 47, 315–323.
  • 8- S. Nishibu, S. Yonezawa, M. Takashima, J. Fluorine Chem. 2005, 126, 1048.
  • 9- H.S. Kainth, R.Singh, J.S. Shahi, T. Singh, Study of chemical shift in Ll and Lƞ X‐ray emission lines in different chemical forms of 48Cd and 50Sn compounds using WDXRF technique, X-Ray Spectrometry, 2018, 47(2), 116-126.
  • 10- S. Raj, H.C. Padhi, M. Polasik, Influence of chemical effect on the Kβ-to-Kα x-ray intensity ratios of Cr, Mn and Co in CrSe, MnSe, MnS and CoS, Nuclear Instruments and Methods in Physics Research Section B, 160(4), 443-448.
  • 11- S. Porikli, Y. Kurucu, Effect of an External Magnetic Field on the Kα and Kβ X-Ray Emission Lines of the 3d Transition Metals, Instrumentation Science&Technology, 2008, 36(4), 341-354.
  • 12- H. Baltas, B. Ertugral, C. Kantar, S. Sasmaz, E. Yılmaz and U. Cevik, Kβ/Kα X-Ray Intensity Ratios for Co, Ni, Cu, and Zn in Phthalocyanines Complexes, Acta Physica Polonica, 2011, 119(6), 764-768.
Year 2018, Volume: 1 Issue: 2, 1 - 11, 30.11.2018

Abstract

References

  • 1- P. Glatzel,U. Bergmann, High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes-electronic and structural information, Coordination Chemistry Reviews, 2005, 249, 65-95.
  • 2- J.H. Guo, S.M. Butorin, N. Wassdahl, P. Skytt, J. Nordgren and Y. Ma, Electronic structure of La2−xSrxCuO4 studied by soft-x-ray-fluorescence spectroscopy with tunable excitation, Phys. Rev. B, 1994, 49, 1376.
  • 3- S.M. Butorin, D.C. Mancini, J.H. Guo, N. Wassdahl, J. Nordgren, M. Nakazawa, S. Tanaka, T. Uozumi, A. Kotani, Y. Ma, K. E. Myano, B.A. Karlin and D.K. Shuh, Resonant X-Ray Fluorescence Spectroscopy of Correlated Systems: A Probe of Charge-Transfer Excitations, Phys. Rev. Lett., 1996, 77, 574.
  • 4- T.Yoshimuraa, Y. Tamenori, A. Suzuki, R. Nakashima, N. Iwasaki, H. Hasegawae, H. Kawahataa, Element profile and chemical environment of sulfur in a giant clam shell: Insights from μ-XRF and X-ray absorption near-edge structure, Chemical Geology, 2013, 352, 170-175.
  • 5- D.B. Hunter, P.M. Bertsch, K.M. Kemner and S.B. Clark, Distribution and Chemical Speciation of Metals and Metalloids in Biota Collected from Contaminated Environments by Spatially Resolved XRF, XANES, and EXAFS, Proceedings of the 9th International Conference on X-Ray Absorption Fine Structure, J. Phys. IV, France 1997, C2-767-771.
  • 6- E. Boydaş, E. Orhan, M.G. Boydaş, E. Cömert, Chemical shifts of Ka and Kb1,3 X-ray emission spectra for oxygen compounds of Ti, Cr, Fe, Co, Cu with WDXRF, Procedia - Social and Behavioral Sciences 195 ( 2015 ) 1757 –1761.
  • 7- S. Porikli, D. Demir and Y. Kurucu, Variation of Kβ/Kα X-ray intensity ratio and lineshape with the effects of external magnetic field and chemical combination, 2008, Eur. Phys. J. D 47, 315–323.
  • 8- S. Nishibu, S. Yonezawa, M. Takashima, J. Fluorine Chem. 2005, 126, 1048.
  • 9- H.S. Kainth, R.Singh, J.S. Shahi, T. Singh, Study of chemical shift in Ll and Lƞ X‐ray emission lines in different chemical forms of 48Cd and 50Sn compounds using WDXRF technique, X-Ray Spectrometry, 2018, 47(2), 116-126.
  • 10- S. Raj, H.C. Padhi, M. Polasik, Influence of chemical effect on the Kβ-to-Kα x-ray intensity ratios of Cr, Mn and Co in CrSe, MnSe, MnS and CoS, Nuclear Instruments and Methods in Physics Research Section B, 160(4), 443-448.
  • 11- S. Porikli, Y. Kurucu, Effect of an External Magnetic Field on the Kα and Kβ X-Ray Emission Lines of the 3d Transition Metals, Instrumentation Science&Technology, 2008, 36(4), 341-354.
  • 12- H. Baltas, B. Ertugral, C. Kantar, S. Sasmaz, E. Yılmaz and U. Cevik, Kβ/Kα X-Ray Intensity Ratios for Co, Ni, Cu, and Zn in Phthalocyanines Complexes, Acta Physica Polonica, 2011, 119(6), 764-768.
There are 12 citations in total.

Details

Primary Language English
Subjects Metrology, Applied and Industrial Physics
Journal Section Articles
Authors

Sevil Porikli Durdağı

Aslıhan Taşpolat This is me

Publication Date November 30, 2018
Submission Date August 5, 2018
Acceptance Date October 25, 2018
Published in Issue Year 2018 Volume: 1 Issue: 2

Cite

APA Porikli Durdağı, S., & Taşpolat, A. (2018). DETERMINATION OF THE CHEMICAL EFFECT IN THE LANTHANIDE GROUP OF ELEMENTS USING WAVE DISPERSIVE X-RAY SPECTROMETRY. Journal of Physical Chemistry and Functional Materials, 1(2), 1-11.
AMA Porikli Durdağı S, Taşpolat A. DETERMINATION OF THE CHEMICAL EFFECT IN THE LANTHANIDE GROUP OF ELEMENTS USING WAVE DISPERSIVE X-RAY SPECTROMETRY. Journal of Physical Chemistry and Functional Materials. November 2018;1(2):1-11.
Chicago Porikli Durdağı, Sevil, and Aslıhan Taşpolat. “DETERMINATION OF THE CHEMICAL EFFECT IN THE LANTHANIDE GROUP OF ELEMENTS USING WAVE DISPERSIVE X-RAY SPECTROMETRY”. Journal of Physical Chemistry and Functional Materials 1, no. 2 (November 2018): 1-11.
EndNote Porikli Durdağı S, Taşpolat A (November 1, 2018) DETERMINATION OF THE CHEMICAL EFFECT IN THE LANTHANIDE GROUP OF ELEMENTS USING WAVE DISPERSIVE X-RAY SPECTROMETRY. Journal of Physical Chemistry and Functional Materials 1 2 1–11.
IEEE S. Porikli Durdağı and A. Taşpolat, “DETERMINATION OF THE CHEMICAL EFFECT IN THE LANTHANIDE GROUP OF ELEMENTS USING WAVE DISPERSIVE X-RAY SPECTROMETRY”, Journal of Physical Chemistry and Functional Materials, vol. 1, no. 2, pp. 1–11, 2018.
ISNAD Porikli Durdağı, Sevil - Taşpolat, Aslıhan. “DETERMINATION OF THE CHEMICAL EFFECT IN THE LANTHANIDE GROUP OF ELEMENTS USING WAVE DISPERSIVE X-RAY SPECTROMETRY”. Journal of Physical Chemistry and Functional Materials 1/2 (November 2018), 1-11.
JAMA Porikli Durdağı S, Taşpolat A. DETERMINATION OF THE CHEMICAL EFFECT IN THE LANTHANIDE GROUP OF ELEMENTS USING WAVE DISPERSIVE X-RAY SPECTROMETRY. Journal of Physical Chemistry and Functional Materials. 2018;1:1–11.
MLA Porikli Durdağı, Sevil and Aslıhan Taşpolat. “DETERMINATION OF THE CHEMICAL EFFECT IN THE LANTHANIDE GROUP OF ELEMENTS USING WAVE DISPERSIVE X-RAY SPECTROMETRY”. Journal of Physical Chemistry and Functional Materials, vol. 1, no. 2, 2018, pp. 1-11.
Vancouver Porikli Durdağı S, Taşpolat A. DETERMINATION OF THE CHEMICAL EFFECT IN THE LANTHANIDE GROUP OF ELEMENTS USING WAVE DISPERSIVE X-RAY SPECTROMETRY. Journal of Physical Chemistry and Functional Materials. 2018;1(2):1-11.